• Title/Summary/Keyword: Dip

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Synthesis and Microstructure Analysis of NiO Catalysts Coated on the FeCrAl Metal Alloy Foam for Hydrogen Production (수소제조를 위한 다공성 FeCrAl 금속 합금 Foam의 NiO 촉매 담지 및 미세구조 분석)

  • Lee, Yu-Jin;An, Geon-Hyoung;Park, Man-Ho;Lee, Chang-Woo;Choi, Sang-Hyun;Jung, Ju-Yong;Jo, Sung-Jong;Lee, Kun-Jae;Ahn, Hyo-Jin
    • Korean Journal of Materials Research
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    • v.24 no.8
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    • pp.393-400
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    • 2014
  • NiO catalysts were successfully coated onto FeCrAl metal alloy foam as a catalyst support via a dip-coating method. To demonstrate the optimum amount of NiO catalyst on the FeCrAl metal alloy foam, the molar concentration of the Ni precursor in a coating solution was controlled, with five different amounts of 0.4 M, 0.6 M, 0.8 M, 1.0 M, and 1.2 M for a dip-coating process. The structural, morphological, and chemical bonding properties of the NiO-catalyst-coated FeCrAl metal alloy foam samples were assessed by means of field-emission scanning electron microscopy(FESEM), scanning electron microscopy-energy dispersive spectroscopy(SEM-EDS), X-ray diffraction(XRD), and X-ray photoelectron spectroscopy(XPS). In particular, when the FeCrAl metal alloy foam samples were coated using a coating solution with a 0.8 M Ni precursor, well-dispersed NiO catalysts on the FeCrAl metal alloy foam compared to the other samples were confirmed. Also, the XPS results exhibited the chemical bonding states of the NiO phases and the FeCrAl metal alloy foam. The results showed that a dip-coating method is one of best ways to coat well-dispersed NiO catalysts onto FeCrAl metal alloy foam.

Impact of rock microstructures on failure processes - Numerical study based on DIP technique

  • Yu, Qinglei;Zhu, Wancheng;Tang, Chun'an;Yang, Tianhong
    • Geomechanics and Engineering
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    • v.7 no.4
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    • pp.375-401
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    • 2014
  • It is generally accepted that material heterogeneity has a great influence on the deformation, strength, damage and failure modes of rock. This paper presents numerical simulation on rock failure process based on the characterization of rock heterogeneity by using a digital image processing (DIP) technique. The actual heterogeneity of rock at mesoscopic scale (characterized as minerals) is retrieved by using a vectorization transformation method based on the digital image of rock surface, and it is imported into a well-established numerical code Rock Failure Process Analysis (RFPA), in order to examine the effect of rock heterogeneity on the rock failure process. In this regard, the numerical model of rock could be built based on the actual characterization of the heterogeneity of rock at the meso-scale. Then, the images of granite are taken as an example to illustrate the implementation of DIP technique in simulating the rock failure process. Three numerical examples are presented to demonstrate the impact of actual rock heterogeneity due to spatial distribution of constituent mineral grains (e.g., feldspar, quartz and mica) on the macro-scale mechanical response, and the associated rock failure mechanism at the meso-scale level is clarified. The numerical results indicate that the shape and distribution of constituent mineral grains have a pronounced impact on stress distribution and concentration, which may further control the failure process of granite. The proposed method provides an efficient tool for studying the mechanical behaviors of heterogeneous rock and rock-like materials whose failure processes are strongly influenced by material heterogeneity.

Fabrication Of Thin Electrolyte Layer For Solid Oxide Fuel Cell by Vacuum Slurry Dip-coating Process (진공 슬러리 담금 코팅 공정에 의한 고체 산화물 연료전지용 박막 전해질막 제조에 관한 연구)

  • Son, Hui-Jeong;Lim, Tak-Hyoung;Lee, Seung-Bok;Shin, Dong-Tyul;Song, Rak-Hyun;Kim, Sung-Hyun
    • Transactions of the Korean hydrogen and new energy society
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    • v.17 no.2
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    • pp.204-211
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    • 2006
  • The electrolyte in the solid oxide fuel cell must be dense enough to avoid gas leakage and thin enough to reduce the ohmic resistance. In order to manufacture the thin and dense electrolyte layer, 8 mol% $Y_2O_3$ stabilized-$ZrO_2$ (8YSZ) electrolyte layers were coated on the porous tubular substrate by the novel vacuum slurry dip-coating process. The effects of the slurry concentration, presintering temperature, and vacuum pressure on the thickness and the gas permeability of the coated electrolyte layers have been examined in the vacuum slurry coating process. The vacuum-coated electrolyte layers showed very low gas permeabilities and had thin thicknesses. The single cell with the vacuum-coated electrolyte layer indicated a good performance of $495\;mW/cm^2$, 0.7 V at $700^{\circ}C$. The experimental results show that the vacuum dip-coating process is an effective method to fabricate dense thin film on the porous tubular substrate.

A Study on the Process of Hybrid Welding Using Pulsed Nd:YAG Laser and Dip-transfer DC GMA Heat Sources (펄스형 Nd:YAG 레이저와 단락이행모드의 직류 GMA 열원을 이용한 하이브리드 용접 공정에 대한 연구)

  • Cho, Won-Ik;Na, Suck-Joo
    • Journal of Welding and Joining
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    • v.25 no.6
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    • pp.71-77
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    • 2007
  • Until now, many researches on laser-arc hybrid welding processes have been conducted mainly for high power CW laser and high direct current arc to weld the thick steel plates for shipbuilding. Recently, however the usage of thin steel plates, which tend to be deformed easily by thermal energy, is been increasing because of demand of light structure such as car body in the automobile industry. Accordingly, heat sources having relatively low heat input such as pulsed laser, dip-transfer DC GMA and pulsed GMA seem to be applied more increasingly and the study about those heat sources is needed more intensively. Any heat source mentioned above can not stand alone without weld defects at a relatively high welding speed for increasing the welding productivity. This is main reason to apply the hybrid welding process which uses pulsed laser and low-heat-input GMA heat sources simultaneously to weld the thin steel plate. In this study, parameters of pulsed laser and dip-transfer DC GMA welding are studied firstly through preliminary experiments, and then analyzed in the viewpoint of their physical phenomena. Before conducting the hybrid welding, a pulse control technique is developed based on the parallel port communication and Visual C++ 6.0. Owing to development of this technique, interactions of laser and arc pulses can be controlled consistently. Using the pulse control technique, the hybrid welding is conducted and then its interactive welding phenomenon is analyzed.

A Model Study on Deformability of A Transversely Isotropic Rock (평면이방성 암석의 변형특성 모델연구)

  • Park, Chul-Whan;Park, Eui-Seob;Park, Chan
    • Tunnel and Underground Space
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    • v.18 no.4
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    • pp.252-262
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    • 2008
  • In the uniaxial compressive test of a single specimen of transversely isotropic rock, its 5 independent elastic constants can not be defined since maximum 4 independent strain measurements are available theoretically. In order to solve this problem, one equation proposed by Saint Venant in 19C and confirmed by Lekhnitskii through the test experiences has been used for long time. Accordign to authors' experiences, however, this equation turned out to give erroneous elastic constants in some cases. Three new equations are suggested and their compatibilities are discussed in this paper. As the results of the analyses of the models, Lekhnitskii's suggested equation is effective for the specimen with the high dip angle whereas it results in the large erred output for that with dip angle less than $25{\sim}30$. It was found that the effectivenesses of three suggested equations and their compatibilities are subject to the dip angle and not to the amounts of elastic constants. Guide map to the selection of the compatible one of those suggested equations is presented as a result of the study.

The Thickness of Shear Zone in Granular Materials Using Digital Image Processing (DIP 기법을 이용한 조립토의 전단영역 크기 분석)

  • Min, Tuk-Ki;Kim, Chi-Young
    • Journal of the Korean Geotechnical Society
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    • v.22 no.8
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    • pp.89-97
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    • 2006
  • This study investigated the effect of relative density on the thickness of shear zone. Digital image processing was used to measure the thickness of shear zone under plane strain conditions. A suitable epoxy resin was injected into the sample and the thickness of the shear zone was investigated. Four independent condition samples were prepared and the thickness of the shear zone was measured. The results indicated that the thickness of shear zone increases as the initial density of sample increases, and during the shear, the void ratios of the shear zone were changed, but the thickness of shear zone was not changed. In addition, the result of measurement of the thickness showed that the thickness of shear zone was almost fixed before critical state, but beyond critical state, the thickness of shear zone sharply increases as relative density increases.

백악기 미국 걸프만 퇴적층의 지구조적, 퇴적학적, 석유지질학적 고찰 (A Review of Tectonic, Sedinlentologic Framework and Petroleum Geology of the Cretaceous U. S. enlf Coast Sedimentary Sequence)

  • Cheong Dae-Kyo
    • The Korean Journal of Petroleum Geology
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    • v.4 no.1_2 s.5
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    • pp.27-39
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    • 1996
  • In the Cretaceous, the Gulf Coast Basin evolved as a marginal sag basin. Thick clastic and carbonate sequences cover the disturbed and diapirically deformed salt layer. In the Cretaceous the salinities of the Gulf Coast Basin probably matched the Holocene Persian Gulf, as is evidenced by the widespread development of supratidal anhydrite. The major Lower Cretaceous reservoir formations are the Cotton Valley, Hosston, Travis Peak siliciclastics, and Sligo, Trinity (Pine Island, Pearsall, Glen Rose), Edwards, Georgetown/Buda carbonates. Source rocks are down-dip offshore marine shales and marls, and seals are either up-dip shales, dense limestones, or evaporites. During this period, the entire Gulf Basin was a shallow sea which to the end of Cretaceous had been rimmed to the southwest by shallow marine carbonates while fine-grained terrigengus clastics were deposited on the northern and western margins of the basin. The main Upper Cretaceous reservoir groups of the Gulf Coast, which were deposited in the period of a major sea level .rise with the resulting deep water conditions, are Woodbinefruscaloosa sands, Austin chalk and carbonates, Taylor and Navarro sandstones. Source rocks are down-dip offshore shales and seals are up-dip shales. Major trap types of the Lower and Upper Cretaceous include salt-related anticlines from low relief pillows to complex salt diapirs. Growth fault structures with rollover anticlines on downthrown fault blocks are significant Gulf Coast traps. Permeability barriers, up-dip pinch-out sand bodies, and unconformity truncations also play a key role in oil exploration from the Cretaceous Gulf Coast reservoirs. The sedimentary sequences of the major Cretaceous reseuoir rocks are a good match to the regressional phases on the global sea level cuwe, suggesting that the Cretaceous Gulf Coast sedimentary stratigraphy relatively well reflects a response to eustatic sea level change throughout its history. Thus, of the three main factors controlling sedimentation (tectonic subsidence, sediment input, and eustatic sea level change) in the Gulf Coast Basin, sea-level ranks first in the period.

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Regulation of Histamine Release by Kappa Opioid Receptor in Rat Cortical Slices (백서 대뇌피질에서 Opioid Kappa수용체의 Histamine 유리조절기능에 관한 연구)

  • Kim, Kee-Won;Cho, Kyu-Park
    • The Korean Journal of Pharmacology
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    • v.30 no.1
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    • pp.1-9
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    • 1994
  • It has been shown that there are several subtypes of ${\kappa}$ opioid receptor. We examined ligand binding profiles and the effects of various opioid agonists on high potassium-stimulated release of $[^3H]$ histamine. We have evaluated the properties of $non-{\mu},\;non-{\delta},$ binding of $[^3H]\;DIP\;([^3H]\;diprenorphine),$ anonselective opioid antagonist, in rat cortex membranes. Binding $to\;{\mu}\;and\;{\delta}$ sites was inhibited by the use of an excess of competing selective agonists (DAMGO, DPDPE) for these sites. (-) Ethylketocyclazocine (EKC), DIP and bremazocine inhibited $[^3H]$ DIP binding. However, arylacetamides (U69593 and U50488H) gave little inhibition Replacement of sodium by NMDG and the addition of guanine nucleotide influenced the inhibitory potency of (-) EKC, an agonist for {\kappa}_1-and-{\kappa}_2-binding site, but not of bremazocine. This result suggests that bremazocine can be an antagonist at this binding site. Also, we have examined the opioid modulation of $K^+(30mM)-induced\;[^3H]\;histamine$ release in rat frontal cortex slices labeled with $1-[^3H]\;histidine$. The $[^3H]\; histamine$ release from cortex slices was inhibited by EKC in a concentration-dependent manner. However, the ${\delta}$ receptor selective agonists, DPDPE and deltorphine II, ${\mu}$ receptor agonists, DAMGO and TAPS, ${\kappa}_1-agonists$, U69593 and U50488H, and ${\varepsilon}-agonist,\;{\beta}-endorphin,$ did not. The concentration-response curve of EKC was shifted to right in the presence of naloxone, nor-binaltorphimine and bremazocine, respectively. These results suggest that ${\kappa}_2$ opioid receptor regulates histamine release in the fromtal cortex of the rat.

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The Long-Term Variations of Water Quality in Masan Bay, South Sea of Korea (남해 마산만 수질의 장기 변동 특성)

  • Kwon, Jung-No;Lim, Jae-Hyun;Shim, Jeonghee;Lee, Jangho;Choi, Tae-Jun
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.17 no.3
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    • pp.212-223
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    • 2014
  • For the better understanding of long-term and seasonal variations of water quality in Masan Bay, South Sea of Korea, we analyzed the archive data monitored at three stations of the bay during the last 13 years (2000-2012). The average concentrations of the chemical oxygen demand (COD), the dissolved inorganic nitrogen (DIN) and the dissolved inorganic phosphorus (DIP) during the monitoring period are $2.70{\pm}0.09{\mu}/L$, $19.66{\pm}1.84{\mu}m$ and $1.39{\pm}0.13{\mu}m$ in surface water, respectively, and $2.22{\pm}0.07{\mu}/L$, $18.53{\pm}1.36{\mu}m$ and $1.47{\pm}0.12{\mu}m$ in bottom water, respectively. The trophic state of the surface water was the eutrophic level in Masan Bay during the four seasons. The DIN concentrations of both surface and bottom waters increased from August to November and showed the highest average in November. However, The DIN decreased from February to May and showed the lowest average in May. The concentrations of the DIP and the dissolved silicate (DSi) in bottom waters had the highest averages in August because of the high water temperature and oxygen deficient condition. The results of correlation analysis and factor analysis showed that the main factors of surface waters were inflow of nutrients from terrestrial areas and internal production, and the main factors of bottom waters were the variations of the dissolved oxygen (DO), the DIP, and the DSi. The DIN and DIP average concentrations (2007~2012) had decreased in range of 68.1%~76.0% and 66.2~76.6%, respectively from 2007 in which the "Regulation of Total Emission" was established in Masan Bay. Therefore, it could have had positive effects on water quality improvement to take the "Regulation of Total Emission" and other actions such as reducing water pollutions in Masan Bay from 2007.

Biaxial Accelerometer-based Magnetic Compass Module Calibration and Analysis of Azimuth Computational Errors Caused by Accelerometer Errors (2 축 가속도계 기반 지자기 센서 모듈의 교정 및 가속도계 오차에 의한 방위각 계산 오차 분석)

  • Cho, Seong Yun
    • Journal of Institute of Control, Robotics and Systems
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    • v.20 no.2
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    • pp.149-156
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    • 2014
  • A magnetic compass module must be calibrated accurately before use. Moreover, the calibration process must be performed taking into account any magnetic dip if the magnetic compass module has tilt angles. For this, a calibration method for a magnetic compass module is explained. Tilt error of the magnetic compass module is compensated using a biaxial accelerometer generally. The accelerometer error causes a tilt angle calculation error that gives rise to an azimuth calculation error. For error property analysis, error equations are derived and simulations are performed. In the simulation results, the accuracy of derived error equations is verified. If a biaxial magnetic compass module is used instead of a triaxial one, the magnetic dip and z-axis magnetic compass data must be estimated for tilt compensation. Lastly, estimation equations for the magnetic dip and z-axis magnetic compass data are derived, and the performance of the equations is verified based on a simulation.