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Temporal and Spatial Fluctuations of Coastal Water Quality and Effect of Small Tide Embankment in the Muan Peninsula of Korea (무안반도 연안수질의 시ㆍ공간적 변동과 소규모 방조제의 영향)

  • Lee Dae-In;Cho Hyeon-Seo;Lee Gyu-Hyung;Lee Moon-Ok
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.6 no.4
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    • pp.24-36
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    • 2003
  • In this study, we estimated the seasonal fluctuations of water quality and effect of small tide embankment in coastal water around the Muan Peninsula, which is located in the northern part of Mokpo city, and layer farming ground is spread around there. Some physical and chemical factors were analyzed to characterize water quality from Jan. to Oct. in 1994. The results were as follows: Dissolved oxygen was slightly under saturation in the almost areas of July, and in some bottom layer at ebb tide of October. Distribution of COD showed high values that over 2㎎/L in October and flood tide of April by the discharge of freshwater and resuspension of benthic sediment, which exceeded water quality criteria II. Maximum values of dissolved inorganic nitrogen ware appeared in surface layer during the flood tide of October, while minimum of that showed in surface layer in April. Concentration of dissolved inorganic phosphorus was higher at July than the others, which ranged from 0.24 to 2.08㎍-at/L. Mostly mean values of N/P ratio were lower than 16, it mean that nitrogen is more limiting nutrient than phosphorus for the growth of phytoplankton. The values of eutrophication index were in the range of 0.07~0.81. However, very high values due to increase of COD were estimated near the tide embankment and southern part in relation to tidal current in October. Water quality around tide embankment was suddenly changed worse within a short period after opening the water gate during the rainfall.

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3D analysis of fracture zones ahead of tunnel face using seismic reflection (반사 탄성파를 이용한 터널막장 전방 파쇄대의 3차원적 예측)

  • Lee, In-Mo;Choi, Sang-Soon;Kim, Si-Tak;Kim, Chang-Ki;Jun, Jea-Sung
    • Journal of Korean Tunnelling and Underground Space Association
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    • v.4 no.4
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    • pp.301-317
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    • 2002
  • Recently, a geophysical exploration technology is frequently utilized in the civil engineering field as well as in the resource exploration. It might be important for civil engineers to understand the fundamental theory of seismic survey and limitation of the technique when utilizing these techniques in the civil engineering field. A 3-dimensional migration technique based on the principle of ellipsoid to predict the fractured zone ahead of tunnel face utilizing the tunnel seismic survey was proposed so that the geometry of the fractured zone can be estimated, i.e. the angle between tunnel axis and discontinuity zone, and the dip. Moreover, a numerical analysis technique to simulate the TSP (Tunnel Seismic Prediction) test was proposed in this paper. Based on parametric studies, the best element size, the analysis time step, and the dynamic characteristics of pressure source were suggested to guarantee the stability and accuracy of numerical solution. Example problems on a hypothetical site showed the possibility that the 3-dimensional migration technique proposed in this paper appropriately estimate the 3D-geometry of fractures ahead of tunnel face.

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Temporal Variation of Water Quality of the Western Chinhae Bay in Summer (진해만 서부해역의 하계 수질의 시간변동 특성)

  • Cho Hyeon-Seo;Lee Dae-In;Yoon Yang-Ho;Lee Moon-Ok;Kim Dong-Myung
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.7 no.1
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    • pp.13-21
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    • 2004
  • Temporal changes of Chl-α, physical and chemical factors were investigated by diurnal observation at 2-hour interval at three fixed stations in the western Chinhae Bay from 12 Aug. to 13 Aug. 1999. Difference of dissolved oxygen between surface and bottom layer was maximum when the thermocline were strong. Organic distribution such as COD was affected by the growth of phytoplankton. Limitting factor was nitrogen, that is, inorganic nitrogen plays a significant role on regulating the algal growth. Surface distribution of dissolved inorganic nitrogen was very low compared to bottom layer by uptake of organisms. Maximum value of Chl-α at station C2 and C11 were observed from subsurface layer, ranges of which exceeded possibility concentration of red tide outbreak, 10 mg/㎥. On the other hand, that of C15 exist at surface layer. In this area, DIN and DIP concentrations increased by input sources such as rainfall and benthic flux before the bloom of phytoplankton. Accumulation of phytoplankton occurred at subsurface layer by the rapid uptake of DIN, especially nitrate ion, when strong thermocline existed as approach to the afternoon, which led to the increase of organics in water column and oxygen deficiency water mass at bottom layer until late at evening. Since then, DIN increases gradually as water temperature decrease to minimum. The quantitative understanding of nitrogen of fluxed to and from the various sources is necessary for environmental management.

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Conservational Treatment and Deterioration Assessment of the Sculptured Standing Buddha Named Taehwa 4 Year in the Jincheon, Korea (진천태화4년명 마애불의 풍화훼손도 평가와 보존처리)

  • Lee, Chan Hee;Kim, Sun Duk;Han, Byeong Il;Kim, Yeong Taek;Lee, Myeong Seong
    • Journal of Conservation Science
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    • v.16 s.16
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    • pp.39-51
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    • 2004
  • The standing Buddha named Taehwa 4 yew in the Jincheon were sculptured with rock cliff of the dark grey shale. Front of the Buddha statue shows $N40^{\circ}W$ strike with nearly vertical dip toward the back side. Rock blocks of the Buddha statue well developed with bedding and laminations whereas rock surface distributed into the various irregular discontinuities. Sculptured lines of the Buddha were uncertain because of degradation and exfoliations on the rock surface. The surface near the Buddha statue is highly contaminated with lichen and mosses, and accelerate physical and biological weathering owing to the roots of weed and bush along the fracture systems. For the conservational treatment, we treated with primary wet cleaning by air gun and secondary cleaning treatment using distilled water. Separated rock surface and fractured parts fasten and/or fill up the boundaries of the rock blocks using epoxy resin for conservation of rock properties. Some brittle surface was treatment with water repellent consolidant of ethyl silicates, and heterogeneous surface carried out color matching by acrylic pigments. Upper part of the Buddha statue dig out small ditch for rain water drainage, and near surface of the Buddha statue treat removal works for lichen, weeds and bush. The duration capacity of the Buddha constituting rocks are degraded by various weathering factors, therefore we suggest that this Buddha statue have need to do long term monitoring and synthetic conservation researches.

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SiOC Coating on Stainless Steel Using Polyphenylcarbosilane, and Its Anti-corrosion Properties (폴리페닐카보실란을 이용한 SiOC가 코팅된 스테인리스스틸 제조 및 이의 내부식성 특징)

  • Kim, Jong-Il;Lee, Yoon-Joo;Kim, Soo-Ryong;Kim, Young-Hee;Kim, Jung-Il;Woo, Chang-Hyn;Choi, Doo-Jin
    • Korean Journal of Materials Research
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    • v.21 no.1
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    • pp.8-14
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    • 2011
  • To improve the chemical stability of metal, the ceramic coatings on metallic materials have attracted interest from many researchers due to the chemical inertness of ceramic materials. To endure strong acids, SiOC coating on metal substrate was carried out by dip coating method using 20wt% polyphenylcarbosilane solution; SiC powder was added to the solution at 10wt% and 15wt% to improve the mechanical properties and to prevent cracks of the film. Thermal oxidation as a curing step was carried out at $200^{\circ}C$ for crosslinking of the polyphenylcarbosilane, and the coating samples were pyrolysized at $800^{\circ}C$ under argon to convert the polyphenylcarbosilane to SiOC film. The thicknesses of the SiOC coating films were $2.36{\mu}m$ and $3.16{\mu}m$. The quantities of each element were measured as $SiO_{1.07}C_{6.33}$ by EPMA, and it can be confirmed that the SiOC film from polyphenylcarbosilane was formed in a manner that was carbon rich. The hardness of the SiOC film was found to be 3.2Gpa through nanoindentor measurement. No defect including cracks appeared in the SiOC film. The weight loss of the SiOC coated stainless steel was within 2% after soaking in 10% HCl solution at $80^{\circ}C$ for one week. From these results, SiOC coating shows good potential for application to protect against severe chemical corrosion of stainless steel.

대홍활석광상 주위의 편마암류의 지화학적 특징과 공존광물의 화학적 평형

  • 이상헌;최기주
    • The Journal of the Petrological Society of Korea
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    • v.3 no.2
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    • pp.138-155
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    • 1994
  • Granitic gneiss containing biotite banded gneiss relict around the Daeheung talc deposit are widely distributed which were formed by regional metamorphism of both epidote-amphibolite and iater greenschist facies and granitization. They were derived from same silico-aluminous rocks of sedimentary origin. The mineral assemblages, which are common in the biotite banded gneiss, formed during regional metamorphisms, are survived in the granitic gneiss. The mineral assemblages of the latter greenschist facies may be formed retrogressively from the first epidote-amphibolite facies. The chemical compositions of biotite, muscovite, and chlorite, the important constituents of the gneisses, were controlled by the bulk composition, the chemical composition of the original mineral, and environment of the regional metamorphisms and granitization. The chemical equilibrium between coexisting'minerals, especially biotite and muscovite, is relatively well established, which was controlled mainly by tschermakitic and phengitic substitutions. Cholrite was formed mainly from either biotite or muscovite by retrogressive alteration or granitization, and have nearly similar chemical compositions regardless of the occurrences. The orientation trend of the foliation, joint and quartz vein developed in the gneisses was analyzed by equal area projection which the latter two show nearly identical trend in the strike and dip. This may suggest that the hydrothermal solution was introduced along joint during wet granitization.

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Preparation of Photosynthesis Nanofiber Composite Membrane by Using Chlorophyll and Polymer Nanofiber (식물 엽록소와 고분자 나노섬유를 이용한 광합성 나노섬유복합막의 제조)

  • Yun, Jaehan;Jang, Wongi;Byun, Hongsik
    • Membrane Journal
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    • v.25 no.1
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    • pp.75-83
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    • 2015
  • In this study, chlorophylls were been extracted from common local plants, deposited on polypropylene (PP) substrate using various approaches, and the oxygen generation effect of the chlorophylls were investigated. The loading of chlorophylls on the substrates was achieved by dipping and spraying methods, where the spraying coating showed overall better results regarding oxygen generation from the combustion experiments in the closed vessel or in the isolated vacuum oven cell than those of dip coating. In addition, a composite substrate was prepared by nylon6/6 nanofiber on the PP substrate, and it exhibited an increase in the activation of chlorophylls. In the case of samples containing titanium dioxide ($TiO_2$), the reaching time of oxygen concentration from 16% to 21% and the combustion test using a candle for a sample with 50% chlorophylls showed similar results to those of a sample without $TiO_2$. As such, combining a spray coating and $TiO_2$ incorporation into gas separation membrane systems are expected to be useful to understand the fundamentals of material properties for their applications as oxygen generation membranes and air filtration systems.

The Effect of Porous Support and Intermediate Layer on the Silica-zirconia Membranes for Gas Permeation Performance (실리카-지르코니아 분리막 성능에 대한 다공성 지지체와 중간층의 영향)

  • Lee, Hye Ryeon;Seo, Bongkuk
    • Membrane Journal
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    • v.25 no.1
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    • pp.15-26
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    • 2015
  • In this study, porous metal (O.D. = 10 mm, length = 10 mm, 316 L SUS, Mott Corp.) and ${\alpha}$-alumina tube (O.D. = 10 mm, length = 50 mm, Pall, German) support was modified with suspension sols, which were consisted of $3{\sim}4{\mu}m$ and 150 nm size of ${\alpha}$-alumina particle in the water or silica-zirconia colloidal sol. The porous support was fabricated by dip coating method for 5 seconds with suspension of alumina particles. After drying at $100^{\circ}C$ for 1 h, it was calcined at $550^{\circ}C$ for 30 min. It was repeated several times in order to decrease big pore on support. The surface roughness and largest pore size on the porous support was decreased by increasing coating times with $3{\sim}4{\mu}m$ size of ${\alpha}$-alumina particle and alumina coating with 150 nm size of ${\alpha}$-alumina particle served as further smoothening the surface and decreasing the pore size of the substrate. And the silica-zirconia membranes were successfully prepared on the modified porous metal and ${\alpha}$-alumina supports, and showed hydrogen permeance in the range of $1.8-8.4{\times}10^{-4}mol{\cdot}m^{-2}{\cdot}s^{-1}{\cdot}Pa^{-1}$ and $3.3-5.0{\times}10^{-5}mol{\cdot}m^{-2}{\cdot}s^{-1}{\cdot}Pa^{-1}$, respectively.

Structural and electrochemical characterization of K2NiF4 type layered perovskite as cathode for SOFCs (K2NiF4 type 층상 페롭스카이트 구조 La(Ca)2Ni(Cu)O4-δ의 SOFC 양극 특성 및 결정구조 평가)

  • Myung, Jae-ha;Hong, Youn-Woo;Lee, Mi Jai;Jeon, Dae-Woo;Lee, Young-Jin;Hwang, Jonghee;Shin, Tae Ho;Paik, Jong Hoo
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.25 no.3
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    • pp.116-120
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    • 2015
  • $La_2NiO_{4+{\delta}}$ based oxides, a mixed electronic-ionic conductors (MIECs) with $K_2NiF_4$ type structure, have been considerably investigated in recent decades as electrode materials for advanced solid oxide fuel cells (SOFCs) due to their high electrical conductivity, and oxidation reduction reaction (ORR). In this study, structure properties of $La(Ca)_2Ni(Cu)O_{4+{\delta}}$ were studied as a potential cathode for intermediate temperature SOFCs (IT-SOFCs).

A Case Study on the Data Processing to Enhance the Resolution of Chirp SBP Data (Chirp SBP 자료 해상도 향상을 위한 전산처리연구)

  • Kim, Young-Jun;Kim, Won-Sik;Shin, Sung-Ryul;Kim, Jin-Ho
    • Geophysics and Geophysical Exploration
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    • v.14 no.4
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    • pp.289-297
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    • 2011
  • Chirp sub-bottom profilers (SBP) data are comparatively higher-resolution data than other seismic data and it's raw signal can be used as a final section after conducting basic filtering. However, Chirp SBP signal has possibility to include various noise in high-frequency band and to provide the distorted image for the complex geological structure in time domain. This study aims at the goal to establish the workflow of Chirp SBP data processing for enhanced image and to analyze the proper parameters for the domestic continental shelf. After pre-processing, we include the dynamic S/N filtering to eliminate the high-frequency component noise, the dip scan stack to enhance the continuity of reflection events and finally the post-stack depth migration to correct the distorted structure on the time domain sections. We demonstrated our workflow on the data acquired by domestically widely used equipments and then we could obtain the improved seismic sections of depth domain. This workflow seems to provide the proper seismic section to interpretation when applied to data processing of Chirp SBP that are largely used for domestic acquisition.