• Title/Summary/Keyword: Dioxide nitrogen

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Studies on the Gas Permeation Behaviors Using the Surface Fluorinated Poly(phenylene oxide) Membranes (표면불소화에 따른 Poly(phenylene oxide)막의 기체투과거동 연구)

  • Lee, Bo-Sung;Kim, Dae-Hoon;Rhim, Ji-Won
    • Membrane Journal
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    • v.20 no.2
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    • pp.106-112
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    • 2010
  • This study deals with the surface fluorination of poly(phenylene oxide) (PPO) with the direct contact of 100 ppm fluorine gas. To characterize the surface fluorinated membranes, the contac angle measurement, X-ray photoelectron microscopy analysis and the gas permeation experiments were performed. As the fluorination time increases, the hydrophobicity of membrane surfaces is increased by the surface characterization. In general, as expected, the overall gas permeability was reduced. Typically, the permeability reduction of 33% for nitrogen, 23% for oxygen and 3% for carbon dioxide were observed when the membranes were exposed in 100 ppm environment for 60 min., meanwhile the selectivity was increased from 3.92 to 4.47 for $O_2/N_2$ and 18.09 to 25.4 for $O_2/N_2$, respectively.

A Study of the Flame Transfer Function Characteristics using Cold-flow Transfer Function in a Partially Premixed Model Gas Turbine Combustor (부분 예혼합 가스터빈 연소기에서의 비연소 전달함수 계측으로부터의 화염전달함수 특성 파악)

  • Joo, Seongpil;Kim, Seongheon;Yoon, Jisu;Yoh, Jai-ick;Yoon, Youngbin
    • Journal of the Korean Society of Propulsion Engineers
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    • v.21 no.5
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    • pp.54-60
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    • 2017
  • In order to identify the characteristics of the flame transfer function gain, cold-flow transfer function was introduced, which is the part of the combustion instability research. Nitrogen and carbon dioxide was used to obtain the cold-flow transfer function and input/output variables was measured by hot wire anemometry. Density and fluid flow rate affect the cold-flow transfer function gain and peak frequency. In addition, acoustic resonance frequency affects the peak frequency of gain in the fuel feeding line.

Historical Development of Nutrient and Calorimetry and Expired Gas Analysis Indirect Calorimetry (영양소와 열량측정법의 발달과정 및 간접 열량 측정법)

  • Yoon, Byung-Kon;Kim, Jong-Won;Kim, Do-Yeon
    • Journal of Life Science
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    • v.20 no.8
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    • pp.1159-1165
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    • 2010
  • Indirect calorimetry is the measurement of the amount of heat generated in an oxidation reaction by determining the intake or consumption of oxygen or by measuring the amount of carbon dioxide or nitrogen released and translating these quantities into a heat equivalent. In the last 20 years there has been significant development in both laboratory and computerized metabolic systems used in indirect calorimetry. In addition, there has been increased use of breath-by-breath EGAIC. Several researchers have suggested that breath-by-breath analysis, because of their practicality, could fulfill this need for a valid and reliable expired gas analysis indirect calorimetry instrument. It was hoped this investigation would determine the best validation for a precise measurement of breath-by-breath expired gas analysis indirect calorimetry. The problem with the available research is that few studies have examined the validity and reliability of all these different systems for breath-by-breath expired gas analysis indirect calorimetry. Therefore, there is a need to find out the most valid, reliable, and precise measurement of the breath-by-breath expired gas analysis indirect calorimetry.

Botryococcus braunii 배양에서 탄화수소의 two-stage 동시추출공정

  • An, Jin-Yeong;Choe, Jeong-Gyu;Sim, Sang-Jun;Kim, Byeong-U
    • 한국생물공학회:학술대회논문집
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    • 2000.11a
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    • pp.229-232
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    • 2000
  • The carbon dioxide, nitrogen, and phosphate removals from wastewater using microalgae have extensively been studied. Especially, the green colonial algae Botryococcus braunii is characterized by unusual high hydrocarbon contents, ranging from 15 to 75% of dry weight, as long-chain unsaturated hydrocarbons. These hydrocarbons suggest that the possibility of renewable biofuels to be converted into useful fuels such as gasoline by simple catalytic cracking. The poor recovery (18 - 32%) of hydrocarbon from B. braunii culture in two-phase bubble column seems to be caused by insufficient mixing between two phases, which was operated using only aeration on the narrow interface between hydrophobic solvent and cell suspension. In addition, hydrocarbon was entrapped tightly in cell-matrix (formed by exopolysaccharide) of algal colony, which make difficult to extract using two-phase system. In order to overcome low recovery efficiency, two-stage extraction culture system including culture vessel and two-phase separator is now under development, resulted improving contact between solvent phase and cell suspension. Hydrocarbon recovery using this process was more than two times as that using two-phase extraction culture.

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Reaction Characteristics of Five Kinds of Oxygen Carrier Particles for Chemical-Looping Combustor (매체순환식 가스연소기 적용을 위한 5가지 산소공여입자들의 반응특성)

  • Ryu, Ho-Jung;Kim, Gyoung-Tae;Lim, Nam-Yun;Bae, Seong-Youl
    • Transactions of the Korean hydrogen and new energy society
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    • v.14 no.1
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    • pp.24-34
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    • 2003
  • For gaseous fuel combustion with inherent $CO_2$ capture and low NOx emission, chemical-looping combustion may yield great advantages for the savings of energy to $CO_2$ separation and suppressing the effect on environment, In chemical-looping combustor, fuel is oxidized by metal oxide medium in a reduction reactor. Reduced particles are transported to oxidation reactor and oxidized by air and recycled to reduction reactor. The fuel and the air are never mixed, and the gases from reduction reactor, $CO_2$ and $H_2O$, leave the system as separate stream. The $H_2O$ can be easily separated by condensation and pure $CO_2$ is obtained without any loss of energy for separation. In this study, five oxygen carrier particles such as NiO/bentonite, NiO/YSZ, $(NiO+Fe_2O_3)VYSZ$, $NiO/NiAl_2O_4$, and $Co_{\chi}O_y/CoAl_2O_4$ were examined &om the viewpoints of reaction kinetics, oxygen transfer capacity, and carbon deposition characteristics. Among five oxygen particles, NiO/YSZ particle is superior in reaction rate, oxygen carrier capacity, and carbon deposition to other particles. However, at high temperature ($>900^{\circ}C$), NiO/bentonite particle also shows enough reactivity and oxygen carrier capacity to be applied in a practical system.

Effect of Multiple Injection on the Performance and Emission Characteristics of Lean Burn Gasoline Direct Injection Engines (다단분사가 초희박 GDI 엔진의 성능 및 배기에 미치는 영향)

  • Oh, Jin-Woo;Park, Cheol-Woong;Kim, Hong-Suk;Cho, Gyu-Baek
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.36 no.2
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    • pp.137-143
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    • 2012
  • Currently, in order to meet the reinforced emissions regulations for harmful exhaust gas including carbon dioxide ($CO_2$) as a greenhouse gas, technologies for reducing $CO_2$ emission and fuel consumption are being developed. Gasoline direct injection (GDI) systems have the advantage of improved fuel economy and higher power output than port fuel injection gasoline engine systems. The aim of this study is to examine the performance and emission characteristics of a lean burn GDI engine equipped with spray-guided-type combustion system. Stable lean combustion was achieved with a late fuel injection strategy under a constant operating condition. Further improvement in specific fuel consumption is possible with the introduction of multiple fuel injection strategies, which also increases hydrocarbon (HC) and nitrogen oxide ($NO_x$) emissions and decreases carbon monoxide (CO) emission.

$NO_2$ gas sensing properties of $SnO_2$ thin films dopped with Pd and CNT (Pd 및 CNT 첨가에 따른 $SnO_2$ 박막의 이산화질소 감지특성)

  • Kim, H.K.;Lee, R.Y.
    • Journal of the Microelectronics and Packaging Society
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    • v.15 no.4
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    • pp.101-106
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    • 2008
  • The $SnO_2$ thin films doped with Pd and CNT as $NO_2$ gas sensor were prepared by spin coating and then the $NO_2$ gas response of these films were evaluated under $1ppm{\sim}5ppm\;NO_2$ concentration and operating temperature of $200^{\circ}C$. It was found that the sensor resistance was increased with $NO_2$ exposure and $NO_2$ concentration. The 3wt% Pd doped sample showed a sensitivity of 26.5 which was 10 times higher than that of pure $SnO_2$. And also the sensitivity of CNT doped sample increased with CNT content and it had 72 when 0.225 wt% of CNT was added under 5ppm $NO_2$ concentration.

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Study on Computational Fluid Dynamics(CFD) simulation for NOx dispersion around combined heat and power plant (열병합발전소 질소산화물 확산에 관한 전산유체역학 simulation 연구)

  • Kim, Ji-Hyun;Park, Young-Koo
    • Journal of the Korean Applied Science and Technology
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    • v.32 no.1
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    • pp.62-71
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    • 2015
  • In order to deal with the globally increasing electric power demand and reduce $CO_2$ emission, complex thermoelectric power plants are being constructed in densely populated downtown areas. As the environmental regulations are continuously strengthened, various facilities like low NOx burner and SCR are being installed to reduce NOx emission. This study is applied using the TMS emission of $NO_2$ from combined heat and power plant located in Goyang-si Gyeonggi-do. Applying data to the computational fluid dynamics(CFD), and compared with the actual measurement results. It is judged that even though there might be differences between actual measurements and CFD results due to the instant changes of wind direction and wind speed according to measurement time during measurement period, modeling results and actual measurement results showed similar concentration at most forecasting areas and therefore, the forecasting concentration could be deducted which is close to actual measurement by calculating the contribution concentration considering the surrounding concentration in the future.

Sawdust cultures of Lepista nuda (민자주방망이버섯 (Lepista nuda)의 톱밥배양)

  • Lee, Sang-Sun;Choi, Kyoung-Jin;Oh, Chang-Ho
    • The Korean Journal of Mycology
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    • v.24 no.4 s.79
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    • pp.274-279
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    • 1996
  • An isolate of Lepista nuda was cultivated on the solid media consisted of various cereal grains or those of the acacia sawdust mixed with other cereal grains. The mycelia grew well on the solid cultures made from millet cereals, but did not on those from sorghum or corn cereals. Thus, the millet and the acacia sawdust, as the solid media, were employed for the next experiments related to mycelial growths. For growth of this isolate, it was shown that the nitrogen source is needed for those of millet. Also, the rice bran or minerals were considered to be needed for the acacia sawdust. As minerals, however, the rice bran is shown as the best additive in the solid cultures of the acacia sawdust. The mycelia of L. nuda were cultivated directly through the solid cultures. Their growths were measured' by the production of carbon dioxide with gas chromatography.

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Preparation of Mg(OH)2-Melamine Core-Shell Particle and Its Flame Retardant Property (멜라민이 코팅된 수산화마그네슘 입자의 제조와 그 복합입자의 난연특성)

  • Lim, Hyung-Mi;Yoon, Joon-Ho;Jeong, Sang-Ok;Lee, Dong-Jin;Lee, Seung-Ho
    • Korean Journal of Materials Research
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    • v.20 no.12
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    • pp.691-698
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    • 2010
  • Magnesium hydroxide-melamine core-shell particles were prepared through the coating of melamine monomer on the surface of magnesium hydroxide in the presence of phosphoric acid. The melamine monomer was dissolved in hot water but recrystallized on the surface of magnesium hydroxide by quenching to room temperature in the presence of phosphoric acid. The core-shell particle was applied to low-density polyethylene/ ethylene vinyl acetate (LDPE/EVA) resin by melt-compounding at $180^{\circ}C$ as flame retardant. The effect of magnesium hydroxide and melamine content has been studied on the flame retardancy of the core-shell particles in LDPE/EVA resin according to the preparation process and purity of magnesium hydroxide. Magnesium hydroxide prepared with sodium hydroxide rather than with ammonia solution revealed higher flame retardancy in core-shell particles with LDPE/EVA resin. At 50 wt% loading of flame retardant, core-shell particles revealed higher flame retardancy compared to that of the exclusive magnesium hydroxide in LDPE/EVA composite, and it was possible to satisfy the V0 grade in the UL-94 vertical test. The synergistic flame retardant effect of magnesium hydroxide and melamine core-shell particles was explained as being due to the endothermic decomposition of magnesium hydroxide and melamine, which was followed by the evolution of water from the magnesium hydroxide and porous char formation due to reactive nitrogen compounds, and carbon dioxide generated from melamine.