• Korean Chemical Engineering Research
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• v.59 no.4
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• pp.644-651
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• 2021

Alkyl amines are widely used in various industries. Nowadays these are also used in CO₂ capture technology because amines react with CO₂ and remove it from the flue gas. To make the amines more compatible towards this technology, physico chemical properties may be altered by mixing with other solvents. In the present report, we measured the refractive properties of pure diisopropylamine (DIPA) (1) + isomeric butanol (2) at 298.15 K to 308.15 K. The 𝚫n values were positive for DIPA + n-butanol or sec-butanol or isobutanol or tert-butanol mixtures. The measured data was correlated with Redlich-Kister equation. The excess molar volume data were predicted from refractive index data using Nakata and Sakurai model. The experimental data were also predicted by various correlations, and the prediction capability of these correlations was reported through standard deviation. Further, the deviation in refractive index (𝚫n) data was interpreted by the consideration of specific molecular interactions between DIPA and isomeric butanol.

• Macromolecular Research
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• v.16 no.6
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• pp.489-491
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• 2008

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• Clean Technology
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• v.13 no.2
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• pp.127-133
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• 2007

Celite with enormous pore space inside can hold small molecules and can be well blended with polyethylene (PE) to make a Celite-PE film. Two types of Celite-PE film were prepared, one with Celite surface-treated with surfactant to reduce the hydrophilicity and another with plain Celite. The anti-rust chemical such as dicyclohexylamine, dicyclohexylamine nitrite, or diisopropylamine was allowed to permeate into celite pore in the film, and slowly evaporated to protect the packaged steel material from the rust for a long period of time. The chemical concentration in the different packaging film bags was analyzed by a gas chromatography for a month, and the anti-rust effect on iron labware was compared for a six month period. The Celite film was superior to PE film in anti-rust effect and the long-term anti-rust chemical evaporation.

• Bulletin of the Korean Chemical Society
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• v.31 no.5
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• pp.1155-1158
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• 2010

Microwave-assisted Michael reaction between EMME and various amines such as diphenylamine, 4-methyl-N-phenylbenzenamine, N-phenylnaphthalen-1-amine, dihexylamine, diisopropylamine, and 4-nitrobenzenamine were described. Solvent-free conditions on alumina as solid support in the presence of $K_2CO_3$ catalysts gave moderate to good yields (55 - 93%) of diethylmalonate analogues having enamine moieties under focused microwave irradiation.

• Journal of the Korean Chemical Society
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• v.67 no.6
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• pp.429-440
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• 2023

1,1-Dialkyl-2,5-bis(trimethylsilylethynyl)-3,4-diphenylsiloles (R=Et, i-Pr, n-Hex; 3a-c) were prepared and utilized as anode active materials for lithium-ion batteries; 3a was also used as a filler for the solid-state electrolytes (SSE). Siloles 3a-c were prepared by substitution reactions in which the two bromine groups of 1,1-dialkyl-2,5-dibromo-3,4-diphe- nylsiloles, used as precursors, were substituted with trimethylsilylacetylene in the presence of palladium chloride, copper iodide, and triphenylphosphine in diisopropylamine. Among siloles 3a-c, 3a had the best electrochemical properties as an anode material for lithium-ion batteries, including an initial capacity of 758 mAhg^-1 (0.1 A/g), which was reduced to 547 mAhg^-1 and then increased to 1,225 mAhg^-1 at 500 cycles. A 3a-composite polymer electrolyte (3a-CPE) was prepared using silole 3a as an additive at concentrations of 1, 2, 3, and 4 wt.%. The 2 wt.% 3a-CPE composite afforded an excellent ionic conductivity of 1.09 × 10^-3 Scm^-1 at 60℃, indicating that silole 3a has potential applicability as an anode active material for lithium-ion batteries, and can also be used as an additive for the SSE of lithium-ion batteries.