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http://dx.doi.org/10.5012/bkcs.2010.31.5.1155

Solvent-Free Michael Addition Between EMME and Secondary Amine under Focused Microwave Irradiation  

Kim, Ki-Won (Department of Chemistry, Kyungsung University)
Lee, Hee-Jung (Department of Chemical Education, Kyungsung University)
Jo, Jeong-Im (Department of Chemistry, Kyungsung University)
Kwon, Tae-Woo (Department of Chemistry, Kyungsung University)
Publication Information
Bulletin of the Korean Chemical Society / v.31, no.5, 2010 , pp. 1155-1158 More about this Journal
Abstract
Microwave-assisted Michael reaction between EMME and various amines such as diphenylamine, 4-methyl-N-phenylbenzenamine, N-phenylnaphthalen-1-amine, dihexylamine, diisopropylamine, and 4-nitrobenzenamine were described. Solvent-free conditions on alumina as solid support in the presence of $K_2CO_3$ catalysts gave moderate to good yields (55 - 93%) of diethylmalonate analogues having enamine moieties under focused microwave irradiation.
Keywords
Focused microwave-assisted irradiation; Solvent-free Michael addition; Diethyl ethoxymethylenemalonate; Secondary amines; Diethyl 2-((diaryl or dialkyl lamino) methylene) malonate;
Citations & Related Records
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