• Title/Summary/Keyword: Diffusion zone

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Oxidation Behavior around the Stress Corrosion Crack Tips of Alloy 600 under PWR Primary Water Environment (PWR 1차측 환경에서 Alloy 600 응력부식균열 선단 부근에서의 산화 거동)

  • Lim, Yun Soo;Kim, Hong Pyo;Hwang, Seong Sik
    • Corrosion Science and Technology
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    • v.11 no.4
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    • pp.141-150
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    • 2012
  • Stress corrosion cracks in Alloy 600 compact tension specimens tested at $325^{\circ}C$ in a simulated primary water environment of pressurized water reactor were analyzed by analytical transmission electron microscopy and secondary ion mass spectroscopy (SIMS). From a fine-probe chemical analysis, oxygen was found on the grain boundary just ahead of the crack tip, and chromium oxides were precipitated on the crack tip and the grain boundary attacked by the oxygen diffusion, leaving a Cr/Fe depletion (or Ni enrichment) zone. The oxide layer inside the crack was revealed to consist of a double (inner and outer) layer. Chromium oxides existed in the inner layer, with NiO and (Ni,Cr) spinels in the outer layer. From the nano-SIMS analysis, oxygen was detected at the locations of intergranular chromium carbides ahead of the crack tip, which means that oxygen diffused into the grain boundary and oxidized the surfaces of the chromium carbides. The intergranular chromium carbide blunted the crack tip, thereby suppressing the crack propagation.

Effect of Chaff Vinegar on the Growth of Food-Borne Pathogenic Bacteria

  • Jo, Seong-Chun;Rim, A-Ram;Park, Hee-Jin;Park, Sun-Min;Lee, Seung-Cheol
    • Preventive Nutrition and Food Science
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    • v.10 no.2
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    • pp.130-133
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    • 2005
  • The growth inhibitiory effect of chaff vinegar against various food-borne pathogenic bacteria was evaluated. Bacterial growth was evaluated in chaff vinegar at concentrations of 15, 30, 50, 65, 80, and $100\%$ using the paper disc diffusion method and 0.5, 1.0, 1.5, 1.8, 2.0, 2.2 and $2.5\%$ in broth. In the paper disc diffusion assay, chaff vinegar showed a clear zone on both the Gram-positive bacteria; Listeria monocytogenes, Staphylococcus aureus and Gram-negative bacteria; Escherichia coli O157:H7, Salmonella Typhimurium, and Vibrio parahaemolyticus. Chaff vinegar exhibited the greatest growth inhibition for V. parahaemolyticus. The bactericidal effect of chaff vinegar on the E. coli O157:H7 was tested at concentrations ranging from 0.5 to $2.5\%$ (v/v) in the LB broth media. Chaff vinegar retarded the lag phase time of the growth curve in proportion in a concentration-dependent manner. Chaff vinegar at $2.5\%$ completely inhibited the growth of E. coli O157:H7.

The Effect of Swirl on the Structure of Concentric Laminar Jet Diffusion Flame (동축분류 층류제트 확산화염의 구조에 미치는 선회의 영향)

  • 김호영;민성기
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.16 no.3
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    • pp.578-588
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    • 1992
  • In order to predict the effect of swirl on the structure of concentric laminar jet diffusion flame, present study examined the effect of swirl on the flame characteristics by numerical numerical analysis through theoretical model. The theoretical model has been developed for the co-axial laminar jet flame such that the fuel and air are supplying with swirl through inner and outer co-axial tube respectively. For the parametric study, swirl number, Reynolds number of fuel and air and directions of swirl are chosen as important parametes. The results of study show that the flame with width and shorter length is formed by larger swirl number. The important factor of the flame shape is the recirculating zone formed around jet axis near the exit of nozzle. In case of weak swirl, the effect of directions of swirl is not appeared. However, for the strong swirl, the flame with shorter length are appeared in case of counter-swirl compared with the case of co-swirl.

Measurements of $^{224}Ra\;and\;^{223}Ra$ in the Nakdong River estuary and the South Sea of Korea

  • Hwang, Dong-Woon;Kim, Gue-Buem;Yang, Han-Soeb
    • Journal of the korean society of oceanography
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    • v.38 no.2
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    • pp.80-86
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    • 2003
  • The horizontal distributions of $^{224}Ra$ (half life=3.4 days) and $^{223}Ra$ (half life=11.3 days) were measured in surface seawaters of the Nakdong River estuary and the South Sea of Korea in April and October 2002. In order to determine these short-lived Ra isotopes, we used a delayed coincidence counter which is much more rapid and accurate than traditional methods. In an estuarine mixing zone (salinity, ~l6 ppt), the activities of $^{224}Ra\;and\;^{223}Ra$ were much greater than what would be expected from a mixture of freshwater and seawater in the Nakdong River estuary. This excess Ra may be a result of Ra desorption from fresh sediments originating from the river upstream. However, in the more open areas of the Nakdong River estuary (salinity>30 ppt) and the South Sea of Korea, $^{224}Ra\;and\;^{^{223}Ra$ activities decreased exponentially as a function of distance offshore. Using the decrease of $^{223}Ra$ with distance offshore in the South Sea of Korea, we estimated the apparent horizontal eddy diffusivities. The apparent eddy diffusion coefficients in South Sea of Korea are calculated to be approximately $3500-8000\;\textrm{m}^2/sec$.

Simulation of the Migration of 3H and 14C Radionuclides on the 2nd Phase Facility at the Wolsong LILW Disposal Center

  • Ha, Jaechul;Son, Yuhwa;Cho, Chunhyung
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.18 no.4
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    • pp.439-455
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    • 2020
  • Numerical model was developed that simulates radionuclide (3H and 14C) transport modeling at the 2nd phase facility at the Wolsong LILW Disposal Center. Four scenarios were simulated with different assumptions about the integrity of the components of the barrier system. For the design case, the multi-barrier system was shown to be effective in diverting infiltration water around the vaults containing radioactive waste. Nevertheless, the volatile radionuclide 14C migrates outside the containment system and through the unsaturated zone, driven by gas diffusion. 3H is largely contained within the vaults where it decays, with small amounts being flushed out in the liquid state. Various scenarios were examined in which the integrity of the cover barrier system or that of the concrete were compromised. In the absence of any engineered barriers, 3H is washed out to the water table within the first 20 years. The release of 14C by gas diffusion is suppressed if percolation fluxes through the facility are high after a cover failure. However, the high fluxes lead to advective transport of 14C dissolved in the liquid state. The concrete container is an effective barrier, with approximately the same effectiveness as the cover.

Evaluation of Pressurized Water Diffusion in Water Treatment Process Using CFD (전산유체역학(CFD)를 활용한 정수공정에서 압력수 확산공정 진단)

  • Cho, Young-Man;Yoo, Soo-Jeon;Roh, Jae-Soon;Bin, Jae-Hoon;Choe, Kwang-Ju;Lee, Kwang-Ug;Lee, Gi-Bong;Lee, Jeong-Gyu
    • Journal of Korean Society of Environmental Engineers
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    • v.33 no.5
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    • pp.359-367
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    • 2011
  • The Process of Pressurized water diffusion is mixing process by pressurized water injection with coagulate and chlorine water in the water treatment system. The objectives of this research were to evaluate the mixing length and diameter of diffusion plate and distance from injection pipe for complete mixing by using computational fluid dynamics. From the results of CFD simulation, when diameter of injection pipe is 50 mm, 100 mm and injection pressure is $5kg/cm^2$ and the diameter of inlet pipe is 2,200 mm, the complete mixing length is 4D (D: Length as diameter of inlet pipe). When diameter of injection pipe is 50 mm, the diameter of the diffusion plate in o.1D and distance from injection pipe is 0.2D, the complete mixing length is 3D that is the most short mixing length. But when diameter of injection pipe is 100 mm and mutually related the diameter, distance of diffusion plate, the complete mixing length is 4D over. Therefore, as the diameter of inlet pipe is 2,200 mm, the injection pipe 50 mm is more efficient than 100 mm.

Evaluation of Cumulative and Conditional Antibiotic Release from Vancomycin-Embedded Fibrin Sealant and Its Antibacterial Activity : An In Vitro Study

  • Shin, Dong-Won;Sohn, Moon-Jun;Cho, Chong-Rae;Koo, Hae-won;Yoon, Sang Won
    • Journal of Korean Neurosurgical Society
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    • v.63 no.1
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    • pp.45-55
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    • 2020
  • Objective : Fibrin sealants have been used for hemostasis, sealant for cerebrospinal fluid leakage, and adhesive barrier in neurosurgery. Further, as its clinical use and role of an effective drug delivery vehicle have been proposed. This study was performed to measure antibacterial activity and continuous local antibiotic release from different concentrations of vancomycin-impregnated fibrin sealant in vitro. Methods : Antibacterial activity was investigated by disk diffusion test by measuring the diameter of the growth inhibition zone of bacteria (methicillin-resistant Staphylococcus aureus, ATCC29213) from vancomycin-embedded fibrin sealant disc diluted at five different concentrations (C1-C5; 8.33, 4.167, 0.83, 0.083, and 0.0083 mg/disc, respectively). Continuous and conditioned release of vancomycin concentration (for 2 weeks and for 5 days, respectively) were also measured using high-performance liquid chromatography (HPLC) method. To mimic the physiologic wound conditions with in vitro, conditioned vancomycin release in phosphate buffer solution (PBS) was measured and replaced PBS for five consecutive days, half a day or completely daily. Results : In the disk diffusion test, the mean diameters of bacterial inhibition zone were 2.54±0.07 cm, 2.61±0.12 cm, and 2.13±0.15 cm (C1, C2, and C3 respectively) but 1.67±0.06 cm and 1.23±0.15 cm in C4 and C5, respectively. Continuous elution test elicited the peak release of vancomycin from the fibrin sealant at 48 hours, with continued release until 2 weeks. However, conditioned vancomycin release decreased to half or more on day 2, however, the sustainable release was measured over the therapeutic dose (10-20 ㎍/mL) for 5 days and 4 days in assays of half and total exchange of PBS. Conclusion : This study suggests that fibrin sealant can provide an efficient vehicle for antibiotic drug release in a wide range of neurosurgical procedures and the safe and effective therapeutic dose will be at the concentration embedded of 4.167 mg/disc or more of vancomycin.

Effect of Micro-Cracks on Chloride Ions Penetration of Concrete: Phonomenological Model (미세균열이 콘크리트의 염소이온 침투에 미치는 영향: 현상학적 모델)

  • Yoon, In-Seok
    • Journal of the Korea Concrete Institute
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    • v.19 no.1
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    • pp.57-65
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    • 2007
  • Over the past few decades, considerable numbers of studies on the durability of concrete have been carried out extensively. A lot of improvements have been achieved especially in both measuring techniques as well as modeling of ionic flows. However, the majority of these researches have been performed on sound uncracked concrete, although most of in-situ concrete structures have more or less micro-cracks. It is only recent approach that the attention has shifted towards the influence of cracks and crack width on the penetration of chloride into concrete. The penetration of chlorides into concrete through the cracks can make a significant harmful effect on reinforcement corrosion. On the other hand, a general acceptable crack width of 0.3 mm has been recognized for keeping the serviceability of concrete structures in accordance with a lot of codes. However, there seems to be rare established description to explain the critical crack width in terms of the durability of concrete. To make a bad situation worse, there is little agreement on critical crack width among a few of literatures for this issue. Critical crack width is still controversial problem. Nevertheless, since the critical crack width is important key for healthy assessment of concrete structures exposed to marine environment, it should be established. The objective of this study is to define a critical crack width. The critical crack width in this study is designed for a threshold crack width, which contributes to the first variation of chloride diffusion coefficient in responsive to the existence of cracks. A simple solution is formulated to realize the quantifiable parameter, chloride diffusion coefficient for only cracked zone excluding sound concrete. From the examination on the trend of chloride diffusion coefficient of only cracked zone for various crack widths, a critical crack width is founded out.

Anti-Helicobacter pylori, Cytotoxic, and Anti-inflammatory Activities of White Ginseng Extract

  • Jee, Hee-Sook;Chang, Kyung-Hoon;Moon, Sun-Hee;Park, Se-Ho;Paik, Hyun-Dong
    • Food Science and Biotechnology
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    • v.17 no.5
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    • pp.1106-1109
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    • 2008
  • The anti-Helicobacter pylori activity, cytotoxicity, and anti-inflammatory activity of white ginseng extract (WGE) were investigated in vitro in this study. The antimicrobial effects of WGE toward H. pylori strains 52 J99, SSI, and 51 were tested using the disk diffusion method. Among these H. pylori strains, H. pylori 52 was the most sensitive, having the largest inhibition zone (19 mm), followed by J99, SSI, and 51. The zone of inhibition due to WGE increased significantly with increasing dosage. The cytotoxicity of WGE toward the human cancer cell lines A-549 (human lung carcinoma), HEC-1-B (human endometrial adenocarcinoma), HeLa (human uterin adenocarcinoma), and SW-156 (human kidney carcinoma) was measured using the 3-(4,5-dimethylthizol-2-yl)-2,5-diphenylate-tetrazolium bromide (MTT) assay. WGE exhibited an inhibitory effect on cell growth at 2.0 mg/mL for all tumor cell lines. An analysis of anti-inflammatory activity using the RAW 264.7 cell line showed that the inhibition of nitric oxide (NO) production increased as the WGE content increased. These results demonstrate the potential of WGE to be used as a health-promoting substance.

A Sensitivity Analysis on Numerical Grid Size of a Three-Dimensional Hydrodynamic and Water Quality Model (EFDC) for the Saemangeum Reservoir (새만금호 3차원 수리.수질모델(EFDC)의 수치격자 민감도 분석)

  • Jeon, Ji Hye;Chung, Se Woong
    • Journal of Korean Society on Water Environment
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    • v.28 no.1
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    • pp.26-37
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    • 2012
  • Multi-dimensional hydrodynamic and water quality models are widely used to simulate the physical and biogeochemical processes in the surface water systems such as reservoirs and estuaries. Most of the models have adopted the Eulerian grid modeling framework, mainly because it can reasonably simulate physical dynamics and chemical species concentrations throughout the entire model domain. Determining the optimum grid cell size is important when using the Eulerian grid-based three-dimensional water quality models because the characteristics of species are assumed uniform in each of the grid cells and chemical species are represented by concentration (mass per volume). The objective of this study was to examine the effect of grid-size of a three dimensional hydrodynamic and water quality model (EFDC) on hydrodynamics and mass transport in the Saemangeum Reservoir. Three grid resolutions, respectively representing coarse (CG), medium (MG), and fine (FG) grid cell sizes, were used for a sensitivity analysis. The simulation results of numerical tracer showed that the grid resolution affects on the flow path, mass transport, and mixing zone of upstream inflow, and results in a bias of temporal and spatial distribution of the tracer. With the CG, in particular, the model overestimates diffusion in the mixing zone, and fails to identify the gradient of concentrations between the inflow and the ambient water.