• Title/Summary/Keyword: Diffusion coefficients

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Diffusion Kinetics of Si in GaAs and Related Defect Chemistry (GaAs에서의 Si의 확산기구와 그에 관련된 격자 결함 화학)

  • Lee, Gyeong-Ho
    • ETRI Journal
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    • v.11 no.4
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    • pp.75-83
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    • 1989
  • The diffusion mechanism of Si in GaAs was investigated using different diffusion sources based on the Si-Ga-As ternary phase equilibria. The Si profiles are measured with secondary ion mass spectrometry and differ significantly for sources taken from the different phase fields in the ternary phase diagram. Neutral As vacancy diffusion is proposed for acceptor Si diffusion anneals using a Ga - Si - GaAs source. Donor Si diffusion using As - rich sources and a Si -GaAs tie line source shows concentration dependent diffusion behavior. Concentration dependent diffusion coefficients of donor Si for As - rich source diffusion were found to be related to net ionized donor concentration and showed three regimes of different behavior: saturation regime, intermediate regime,and intrinsic regime. Ga vacancies are proposed to be responsible for donor Si diffusionin GaAs: $Si_Ga^+V_Ga^-$ (donor Si -acceptor Gavacancy) complex for the extrinsic regime and neutral $V_G$a, for the intrinsic regime.The Si - GaAs tie line source resulted in two branch profiles, intermediate between the As - rich and the Ga - rich source diffusion cases.

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Pseudo-Binary Diffusion Coefficients of Organic Aroma Component - I. The Diffusion Coefficient of Benzaldehyde in Aqueous Sugar Solution - (유기방향물질의 의사 2성분계 확산계수 - 제1보 : 설탕수용액중 Benzaldehyde의 확산계수 -)

  • Kang, An-Soo;Lee, Tae-Hee
    • Korean Journal of Food Science and Technology
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    • v.14 no.4
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    • pp.315-323
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    • 1982
  • The measurement of cell constant in a diaphragm-cell method is the most important factor. In order to get the correct cell constant, the diffusion coefficients of potassium chloride were measured, at various concentration and temperature of potassium chloride solution, and at the stirring rate in the cell. The pseudo-binary diffusion coefficients of organic aroma component (benzaldehyde) in sugar solution has been measured at various concentration and temperature with the cell constant obtained above. Experimental results were compared and discussed with the semi-empirical epuations from literatures. And, especially, the diffusion coefficient of benzaldehyde, $D_{ba}$ for a small solute diffusing in a viscous solvent of larger molecules is proportional to the -0.82 power of the viscosity of aqueous sugar solution, ${\mu}$ at constant temperature, $D_{ba}{\mu}^{0.82}=constant$.

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An innovative method for determining the diffusion coefficient of product nuclide

  • Chen, Chih-Lung;Wang, Tsing-Hai
    • Nuclear Engineering and Technology
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    • v.49 no.5
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    • pp.1019-1030
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    • 2017
  • Diffusion is a crucial mechanism that regulates the migration of radioactive nuclides. In this study, an innovative numerical method was developed to simultaneously calculate the diffusion coefficient of both parent and, afterward, series daughter nuclides in a sequentially reactive through-diffusion model. Two constructed scenarios, a serial reaction (RN_1 ${\rightarrow}$ RN_2 ${\rightarrow}$ RN_3) and a parallel reaction (RN_1 ${\rightarrow}$ RN_2A + RN_2B), were proposed and calculated for verification. First, the accuracy of the proposed three-member reaction equations was validated using several default numerical experiments. Second, by applying the validated numerical experimental concentration variation data, the as-determined diffusion coefficient of the product nuclide was observed to be identical to the default data. The results demonstrate the validity of the proposed method. The significance of the proposed numerical method will be particularly powerful in determining the diffusion coefficients of systems with extremely thin specimens, long periods of diffusion time, and parent nuclides with fast decay constants.

Time-dependent characteristics of chloride diffusion coefficient of concrete (콘크리트 염소이온 확산계수의 시간 의존적 특성)

  • Choi, Sung;Lee, Kwang-Myong;Shin, Kyung-Joon;Bae, Su-Ho
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.04a
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    • pp.545-548
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    • 2008
  • As the corrosion of reinforcing bar in concrete structures exposed to chloride attack is one of main factors to determine the remaining service life, marine concrete structures have to be designed to protect the chloride penetration. Among the durability design methods such as deterministic method and probabilistic method, design method based on the probabilistic theory has been widely studied. However, the most essential material, data of the material properties related to chloride diffusion, are still insufficient. In this paper, the probabilistic distribution of chloride diffusion coefficients and aging coefficients are derived by the experiment and analysis for the chloride coefficients of concrete containing pozzolans, which are generally used in marine structures.

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LIOUVILLE THEOREMS OF SLOW DIFFUSION DIFFERENTIAL INEQUALITIES WITH VARIABLE COEFFICIENTS IN CONE

  • Fang, Zhong Bo;Fu, Chao;Zhang, Linjie
    • Journal of the Korean Society for Industrial and Applied Mathematics
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    • v.15 no.1
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    • pp.43-55
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    • 2011
  • We here investigate the Liouville type theorems of slow diffusion differential inequality and its coupled system with variable coefficients in cone. First, we give the definition of global weak solution, and then we establish the universal estimate (does not depend on the initial value) of solution by constructing test function. At last, we obtain the nonexistence of non-negative non-trivial global weak solution within the appropriate critical exponent. The main feature of this method is that we need not use comparison theorem or the maximum principle.

The Study of Electron Transport coefficients in $SiH_4$-Ar Mixtures by Using Boltzmann Equation Analysis and Monte-Carlo Simulation (볼츠만방정식과 몬테칼로법에 의한 $SiH_4$-Ar 혼합가스의 전자수송계수에 관한 연구)

  • 하성철;전병훈
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.14 no.2
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    • pp.169-174
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    • 2001
  • The electron transport coefficients(the electron drift velocity, W, and the longitudinal and transverse diffusion coefficient, D$_{L}$ and D$_{T}$) in SiH$_4$-Ar mixtures containing 0.5% and 5.0% monosilane were calculated over the E/N range from 0.01 to 300 Td and over the gas pressure range 0.5, 1.0 and 1.5 Torr by the time-of-flight(TOF) method of the Boltzmann equation(BE.) and Monte-Carlo simulation(MCS). The electron energy distribution function in each SiH$_4$-Ar mixtures at E/N=10 Td and L=0.2 cm, which in equilibrium region in the mean electron enregy were compared.red.

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Magnetic Resonance Neurography Using the Anisotropy of Diffusion Coefficients (확산계수의 이방성을 이용한 자기공명 신경망조영술)

  • Lee, Su-Yeol;Mun, Chi-Ung;Im, Tae-Hwan
    • Journal of Biomedical Engineering Research
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    • v.15 no.4
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    • pp.401-406
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    • 1994
  • A magnetic resonance neurography technique for exclusive imaging of nerve networks is proposed. In the proposed technique, the anisotropy of diffusion coefficients of the molecules inside nerve cells was utilized to effectively suppress the magnetic resonance signal radiating from ones other than nerve tissues. Two images were obtained with diffusionweighting magnetic field gradients applied in the parallel and perpendicular directions with respect to the nerve orientation. One image was then subtract- ted from the other to form the neurogram. Experimentally obtained neurograms of the squld are presented.

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Electrogravimetric and Electrochemical Ac Response of Polypyrrole Films

  • Yang, Haesik;Lee, Hochun;Kwak, Juhyoun
    • Analytical Science and Technology
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    • v.8 no.4
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    • pp.663-668
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    • 1995
  • Ion transport of a polypyrrole/chloride (PPy/Cl) film and a polypyrrole/poly(styenesulfonate) (PPy/PSS) film as a function of applied dc potential was investigated by employing electrogravimetric impedance technique and electrochemical impedance technique. The cation and anion contribution to the whole charge capacitance and the diffusion coefficients of cation and anion in a PPy/PSS film were calculated by fitting the electrogravimetric impedance data with proposed model circuit. The diffusion coefficients of $Na^+$ in a 1 M $NaClO_4$ solution are over 1 order of magnitude larger than those of $ClO{_4}^-$, and $ClO{_4}^-$ contribution to charge compensation decreases as dc potential lowers. The charge compensation of a PPy/Cl film ir a 1 M CsCl solution is carried out largely by $Cl^-$ at 0.2 V vs. Ag/AgCl and by $Cs^+$ as well as $Cl^-$ at -0.4 V.

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Prediction of VOCs Emissions from Multi-layers Materials (복합자재에서의 VOCs 방출량 예측에 관한 연구)

  • Yoon, Chang-Hyun;Kwon, Kyung-Woo;Park, Jun-Seok
    • Proceedings of the SAREK Conference
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    • 2005.11a
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    • pp.9-14
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    • 2005
  • The purpose of this study is to predict VOCs emission rates from multi-layers materials, which are composed of single-layer materials having various VOCs emission rates, by using effective diffusion coefficients of the single-layer materials. The study was consisted of two parts; the one is the prediction of VOCs emission rates from multi-layer materials through numerical methods. The other is the measurement of VOCs emissions rates of wall composite and floor composite in Mock-up rooms for comparing the prediction and the experiments' values. The results of the study show that the short-term VOCs emission rates of multi-layers materials can be predicted from the effective diffusion coefficients of single materials in odor accuracy.

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Influence of Blending Materials on C1- Diffusion and pH of Pore Solution in Cement Pastes (시멘트 경화체 중에서의 C1-의 확산과 세공용액의 pH에 미치는 혼화재의 영향)

  • 김남중;최상흘;정재동;한기성
    • Magazine of the Korea Concrete Institute
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    • v.4 no.1
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    • pp.97-106
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    • 1992
  • Apparent diffusion coefficients of Cl- ions through hardened cement pastes(HCP), which were partly subs¬tituted blast furnace slag, fly ash and silicafume for ordinary Portland cement, were determined. Also. Cl- and OW concentration of pore solutions which were extracted from HCP and the capacities of the HCP to bind CI were determined. Diffusion coefficients of Cl- ions through HCP were increased with water cement ratio(WfC), but decreased with addition of the blending materials. On the contrary, Cl- and OH concentration of the pore solutions were reduced by adding the blending materials.