• 분석과학
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• 제6권1호
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• pp.83-92
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• 1993

0.05M TEAP를 지지전해질로 한 아세톤용액에서, 란탄늄 및 네오디늄과 몇 가지 리간드의 착물에 대한 전기화학적 거동인 환원전류의 유형, 가역성, 안정도상수, 전류함수 등을 폴라로그래피와 순환전압전류법으로 조사하였다. 환원파는 2단계로 나타났으며, 반응은 확산지배적이고 비가역적이었다. 또한 란탄족 금속이온의 착물에 대하여 안정도상수를 측정하였다.

• KSII Transactions on Internet and Information Systems (TIIS)
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• 제15권6호
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• pp.2069-2085
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• 2021

A Social Networking Service (SNS) platform provides digital footprints to discover users' interests and track the social diffusion of product adoptions. How to identify a small set of seed users in a SNS who is potential to adopt a new promoting product with high probability, is a key question in social networks. Existing works approached this as a social influence maximization problem. However, these approaches relied heavily on text information for topic modeling and neglected the impact of seed users' relation in the model. To this end, in this paper, we first develop a general product adoption function integrating both users' interest and social influence, where the user interest model relies on historical user behavior and the seed users' evaluations without any text information. Accordingly, we formulate a product adoption maximization problem and prove NP-hardness of this problem. We then design an efficient algorithm to solve this problem. We further devise a method to automatically learn the parameter in the proposed adoption function from users' past behaviors. Finally, experimental results show the soundness of our proposed adoption decision function and the effectiveness of the proposed seed selection method for product adoption maximization.

• Corrosion Science and Technology
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• 제22권4호
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• pp.297-303
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• 2023

This study aimed to evaluate hydrogen permeation behaviors of pre-strained twinning-induced plasticity steel with or without Zn coating using electrochemical permeation technique. In contrast to un-strained and 30% strained samples, permeation current density was measured in the 60% strained sample. Tensile pre-straining at 60% involved microstructural modifications, including a high level of dislocation density and stacking fault with a semi-coherent twin boundary, which might provide a high diffusion path for hydrogen atoms. However, reproducibility of measurements of hydrogen permeation current was low due to non-uniform deformation and localized stress concentration. On the other hand, the permeation current was not measured in pre-strained TWIP steel with Zn coating. Instead, numerous blisters with some cracks were observed on the surface of the coating layer. In locally damaged Zn coating under tensile straining, hydrogen atoms could relatively easily permeate through the coating layer. However, they were trapped at the interface between the coating layer and the substrate, which might delay hydrogen penetration into the steel substrate.

• Nuclear Engineering and Technology
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• 제55권3호
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• pp.895-901
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• 2023

Oxide-dispersion- strengthened nickel alloys with Hf additions are expected to present high temperature mechanical properties and durable helium resistance based on first-principles density functional theory (DFT) calculations. Energetic and charge density evaluations of the helium behaviors were performed in Ni matrix, Y₂Hf₂O₇ oxide and the oxide/matrix interface. With the presence of coherent Y₂Hf₂O₇ in Ni matrix, chances of helium bubbles in Ni can be greatly diminished. The helium atoms shall occupy the interfacial site initially, then diffuse into in the octahedral sites of Y₂Hf₂O₇, and these oxide-captured He atoms prefer to separate individually. Much higher diffusion barrier of He in Y₂Hf₂O₇ than in nickel is related to the strong hybridization between interstitial He-1s and nearest-neighboring O-2p orbitals.

• 한국산학기술학회논문지
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• 제11권10호
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• pp.3647-3653
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• 2010

본 오디오 스피커로 음향 가진과 비가진 된 충돌 역 확산화염에서 화염의 형상과 열전달 특성에 관한 실험적 연구를 수행하였다. 가진에 의해 화염은 반응대가 넓어지고 화염 길이는 좀 더 짧아지는 경향을 보이며 충돌판의 정체점에서 열전달 성능인 열유속은 가진에 의해 향상되는 것으로 나타났다. 이러한 가진 효과는 당량비가 높은 과농한 상태 보다 상대적으로 낮은 혼합 상태에서 효과적으로 영향을 미치는 것으로 파악되는데 이는 가진에 의해 주위산화제가 연료 분류로의 유입이 향상되어 나타나는 것으로 판단된다. 이러한 현상으로 본 연구에서는 당량비가 0.8인 경우 정체점에서 총 열유속이 최대 57% 증가되는 것으로 나타났다. 따라서 본 연구를 통해 가진 연소가 충돌 분류 화염에서 열전달 성능을 향상시키는데 효과적인 방법임을 확인하게 되었다.

• 대한치과기공학회지
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• 제27권1호
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• pp.97-104
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• 2005

The effect of Nb on interfacial bonding characteristics of Ni-Cr alloy for porcelain fused to metal crown (PFM) has been studied in order to investigate oxide layer. A specimens, which is 0.8mm in thickness, were fired at 1,000$^{\circ}C$ with four tests such as air, vacuum, air for 5 minutes and vacuum for 5 minutes in order to examine an oxide behavior of alloy surface generated by the adding of Nb to be controlled at a rate of 0, 1, 3 and 5. It observed oxide film form of the fired specimens with optical microscope and scanning electron microscope (SEM), and chemical formation of them with energy disperse X-ray spectroscopy (EDX). The other specimens, which is 2mm in thickness, were fired at 1,000$^{\circ}C$ with air and vacuum in order to analyze the diffusion behaviors of alloy-porcelain interface by X-ray dot mapping. The results of this study were as follows: 1. The observation of microstructure of specimens by SEM showed that the more Nb content is high, the more much intermediate compound of rich Nb is observed. 2. The surface morphology of oxide film is most dense in 3% Nb. The heat treatment in air constitutes denser oxide film than heat treatment under vacuum. 3. The diffusion behavior of oxide layer by X-ray dot mapping showed that Si, Al of porcelain diffuse toward metal.

• 한국연소학회지
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• 제18권4호
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• pp.37-43
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• 2013

The effects of preferential diffusion of hydrogen in interacting counterflow $H_2$-air and CO-air premixed flames were investigated numerically. The global strain rate was varied in the range $30-5917s^{-1}$, where the upper bound of this range corresponds to the flame-stretch limit. Preferential diffusion of hydrogen was studied by comparing flame structures for a mixed average diffusivity with those where the diffusivities of H, $H_2$ and $N_2$ were assumed to be equal. Flame stability diagrams are presented, which show the mapping of the limits of the concentrations of $H_2$ and CO as a function of the strain rate. The main oxidation route for CO is $CO+O_2{\rightarrow}CO_2+O$, which is characterized by relatively slow chemical kinetics; however, a much faster route, namely $CO+OH{\rightarrow}CO_2+H$, can be significant, provided that hydrogen from the $H_2$-air flame is penetrated and then participates in the CO-oxidation. This modifies the flame characteristics in the downstream interaction between the $H_2$-air and CO-air flames, and can cause the interaction characteristics at the rich and lean extinction boundaries not to depend on the Lewis number of the deficient reactant, but rather to depend on chemical interaction between the two flames. Such anomalous behaviors include a partial opening of the upper lean extinction boundary in the interaction between a lean $H_2$-air flame and a lean CO-air flame, as well as the formation of two islands of flame sustainability in a partially premixed configuration with a rich $H_2$-air flame and a lean CO-air flame. At large strain rates, there are two islands where the flame can survive, depending on the nature of the interaction between the two flames. Furthermore, the preferential diffusion of hydrogen extends both the lean and the rich extinction boundaries.

• 콘크리트학회논문집
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• 제28권2호
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• pp.149-156
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• 2016

염해에 노출된 콘크리트의 내구수명은 매우 중요한데, 주로 Fick's 2법칙에 근거한 결정론적인 방법과 확률론에 근거한 방법이 사용되고 있다. 본 연구에서는 시간의존적 확산계수와 표면염화물량을 고려하여 내구적 파괴확률과 이에 따른 내구수명의 변화를 평가하였다. 이를 위해 3.5~4.5년, 비교적 짧은 기간 염해에 노출된 RC 교각에 대하여 해상부(9.0 m)와 간만대(6.0 m) 구분하여 실태조사를 수행하였다. 피복두께, 표명염화물량, 염화물 확산계수에 대한 확률변수를 도출하였으며, MCS을 이용하여 내구적 파괴확률과 내구수명을 평가하였다. Life365를 이용한 결정론적 방법과 다르게, 시간의존성을 고려한 확률해석에서는 내구수명의 변동이 크게 발생하였으며, 표면염화물량이 낮은 조건에서는 초기에 빠른 내구수명의 감소가 평가되었다. 실태조사 결과를 이용하여 확률론적인 내구성 평가를 할 경우, 장기간 염해에 노출되어 $10.0kg/m^3$ 이상의 높은 표면염화물량이 필요함을 알 수 있으며, 확산계수의 시간의존성에 따른 감소를 고려하면 합리적인 내구수명을 평가할 수 있다.

• 열처리공학회지
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• 제7권3호
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• pp.169-174
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• 1994

The reaction layer formed at interface between matrix and fiber has significant effects on the mechanical properties and behaviors of deformation m FRM. In this study, the mechanical properties and interfacial behaviors according to surface finishing on the fibers and according to heat treatment in FRM were investigated. FRM was fibricated by diffusion bonding method. In W/Al alloy composite and W/Al composite, W of which was coated with $WO_3$, the heat treatment was carried out thermal cycling method from 373K to 673K. In W/Al composite, W of which was coated with $WO_3$, growth of interface layer was hardly occured in spite of the increasing various thermal cycles. It was exhibited that oxidized W/Al composite were higher strength than non-oxidezed W/Al composite with the increasing thermal cycles. The compounds of fiber/matrix interface were analyzed into $WAl_{12}$, $WAl_7$, and $AlWO_3$, respectivly. Therefore the interfacial compounds of fiber/matrix seriously affected the mechanical properties and behaviors of deformation in FRM.

• Bulletin of the Korean Chemical Society
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• 제28권10호
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• pp.1729-1734
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• 2007

The electrochemical behaviors of estrone in the presence of various surfactants were examined with great details. It is found that a cationic surfactant, cetyltrimethylammonium bromide (CTAB), obviously facilitates the electro-oxidation of estrone at carbon paste electrode (CPE) from the significant peak current enhancement and the negative shift of peak potential. Additionally, chronocoulometry and electrochemical impedance spectroscopy (EIS) were also used for further investigation of the electrode process of estrone, indicating that low concentration of CTAB exhibits excellent enhancement effects on the electrochemical oxidation of estrone, greatly enhances the diffusion coefficient and the electron transfer rate. Based on this, an electrochemical method was proposed for the determination of estrone. The oxidation peak current is proportional to the concentration of estrone in the ranges over 9.0 × 10?8 - 8.0 × 10?6 mol/L, and a low detection limit of 4.0 × 10?8 mol/L was obtained for 180s accumulation at open circuit (S/N = 3). Finally, this proposed method was demonstrated using estrone tablets with good satisfaction.