• Bulletin of the Korean Chemical Society
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• 제20권8호
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• pp.897-904
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• 1999

We have presented the thermodynamic, structural and dynamic properties of liquid pentane isomers - normal pentane, isopentane, and neopentane - using an expanded collapsed atomic model. The thermodynamic properties show that the intermolecular interactions become weaker as the molecular shape becomes more nearly spherical and the surface area decreases with branching. The structural properties are well predicted from the site-site radial, the average end-to-end distance, and the root-mean-squared radius of gyration distribution func-tions. The dynamic properties are obtained from the time correlation functions - the mean square displacement (MSD), the velocity auto-correlation (VAC), the cosine (CAC), the stress (SAC), the pressure (PAC), and the heat flux auto-correlation (HFAC) functions - of liquid pentane isomers. Two self-diffusion coefficients of liquid pentane isomers calculated from the MSD's via the Einstein equation and the VAC's via the Green-Kubo relation show the same trend but do not coincide with the branching effect on self-diffusion. The rotational re-laxation time of liquid pentane isomers obtained from the CAC's decreases monotonously as branching increases. Two kinds of viscosities of liquid pentane isomers calculated from the SAC and PAC functions via the Green-Kubo relation have the same trend compared with the experimental results. The thermal conductivity calculated from the HFAC increases as branching increases.

• The Journal of Korean Physical Therapy
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• 제34권6호
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• pp.326-331
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• 2022

Purpose: The stroke patients have gait dysfunction due to impaired neural tracts; corticospinal tract (CST), corticoreticular pathway (CRP), and vestibulospinal tract (VST). In this study, we investigated characteristics of gait pattern according to the injury aspect of the neural track in a stroke patient. Methods: One patient and six control subjects of similar age participated. A 19-year-old male patient with spontaneous intracerebral hemorrhage on right basal ganglia, thalamus, corona radiata and cerebral cortex due to arteriovenous malformation rupture. Diffusion tensor imaging (DTI) data was acquired 21 months after the stroke. Kinematic and spatio-temporal parameters of gait were collected using a three-dimensional gait analysis system. Results: On 21 months DTI, the CST and CRP in affected hemisphere showed severe injury, in contrast, the VST in affected hemisphere showed intact integrity. Result of gait analysis, walking distance and speed were significantly decreased in a patient. The stance rate of unaffected lower limb, the swing rate of affected lower limb and the duration of double stance significantly increased compared with normal control. The knee and hip joint angle were significantly decreased in a patient. Conclusion: We found recovered independent gait ability may be associated with unimpaired VST in a patient with severe injury in CST and CRP.

• 한국해안해양공학회지
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• 제16권2호
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• pp.92-102
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• 2004

본 논문은 조류의 대ㆍ소조 변동이 존재하는 해역에서의 점열원에 대한 초과수온 분포를 예측하는 해석해를 다룬다. 해석해는 Jung et al.(2003)이 제시한 2차원 해석해를 기본으로 하여 조류의 대ㆍ소조 변동과 수평 확산계수의 대ㆍ소조 변화를 반영할 수 있는 형태로 확장되었다. 일련의 해석모형 실험을 통해 조류 및 난류확산의 변동에 따른 열오염의 이동ㆍ확산 변화를 검토하였다. 실험결과 열오염의 이동ㆍ확산은 tidal excursion 거리 이내에서는 조류의 크기에 좌우되며 tidal excursion 거리를 벗어난 해역에서는 주로 수평 확산에 의해 결정되는 것으로 나타났다. 특히 tidal excursion 거리 이내 해역에서 초과수온 분포는 수평 확산계수의 대ㆍ소조 변동에 큰 영향을 받는 것으로 나타났다. 즉, 1$^{\circ}C$이상의 비교적 높은 초과수온이 발생하는 범위는 수평 확산계수의 대ㆍ소조 변동을 고려하는 경우가 상대적으로 더 멀리 확장하는 경향을 보여주었다.

• 대한기계학회논문집B
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• 제28권7호
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• pp.818-825
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• 2004

In this paper, the study of effects of flow parameters on flame structure and NOx emission concentration was performed in co-axial. laminar partially premixed methane/air flames. Such (low parameters as equivalence ratio(${\Phi}$), fuel split percentage($\sigma$), and mixing distance(x/D$\_$i/) were defined as a premixing degree and varied within ${\Phi}$=1.36∼9.52, $\sigma$=50∼100, and x/D$\_$i/=5∼20. The image of OH$\^$*/ and NOx concentration were obtained with an ICCD camera and a NOx analyzer. The flame structure observations show a categorization of partially premixed flames into three distinct flame regimes corresponding to ${\Phi}$<1.7(premixed flame structure), 1.7<${\Phi}$<3.3(hybrid structure), and ${\Phi}$>3.3(diffusion flame structure existing a luminous sooting region) at $\sigma$=75%, and x/D$\_$i/=10. As o decreases from 100% to 50%, and x/D$\_$i/ decreases, nonpremixed flame structure appear at low equivalence ratio relatively. In addition, the measured emissions for NOx rise steeply from ${\Phi}$=1.7, to ${\Phi}$=3.3, then constants ${\Phi}$>4.76. NOx emissions decrease with increase the level of premixing level. In conclusion, the main effect on flame structure and NOx production was at first equivalence ratio(${\Phi}$), and next fuel split percentage($\sigma$), and finally mixing distance(x/D$\_$i/).

• 한국추진공학회지
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• 제21권2호
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• pp.1-8
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• 2017

본 연구에서는 모델연소실 내부 메탄-산소 확산화염의 연소특성을 분석하기 위해 추진제의 다양한 분사조건에서 연소실험을 수행하여 연소안정한계 측정 및 화염의 형상변이를 관찰하였다. 연구 결과, 추진제가 이론당량비 조건으로 접근할수록 높은 산소 Reynolds 수($Re_o$) 구간에서도 안정적인 부상화염이 관찰되었으며, 가시화염의 길이는 증가하고, 부상높이는 감소하는 경향이 나타났다. 스월 동축형 인젝터에 의한 추진제의 스월효과로 인해 폭이 넓고, 길이가 짧은 화염이 생성되어 연소실 크기가 제한적인 추력기에서의 사용이 적합함을 확인하였다.

• 대한전자공학회논문지SP
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• 제41권5호
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• pp.77-85
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• 2004

본 논문에서는 64개 기준색을 사용한 다단계 벡터 오차 확산법에서 나타나는 밝은 영역에서의 색 자극 문제를 개선하는 방법을 제안하였다. 벡터 오차 확산법은 양자화 과정에서 입력 벡터와 기준색 벡터간의 기하학적 거리만을 이용하기 때문에 밝은 영역에서 어두운 기준색이 선택되는 색 자극이 발생한다 이러한 문제를 해결하기 위해서 오차 보정된 입력 벡터의 채도를 계산하여 유채색과 무채색으로 나누고, 유채색일 경우 입력 벡터의 휘도를 이용하여 밝은 영역, 중간 밝기 영역, 어두운 영역으로 구분한다. 밝은 영역일 경우 60개 유채색 기준색중에서 입력 벡터와의 휘도차가 작은 N개의 후보 기준색을 구성한다. 최종 기준색을 선택할 때는 N개의 후보 기준색과 4개의 무채색 기준색중에서 오차 보정된 입력 벡터와의 최소 기하학적 거리를 가지는 기준색을 출력색으로 결정한다 실험 결과, 제안한 방법은 자은 영역에서 색 자극이 줄어들어 시각적으로 보기 좋은 결과를 보였다.

• 한국화재소방학회논문지
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• 제32권3호
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• pp.76-87
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• 2018

본 연구는 화학공장에서 원료 및 중간재로 많이 사용되는 Heavy Gas인 염소를 화학설비의 가압 염소포화액체 저장탱크에서 2상 흐름 연속누출에 대한 유해위험거리를 정량적으로 예측하기 위한 피해영향 모델링이다. 피해예측을 위한 평가방법과 사고영향평가모델들을 기준으로 액체염소 저장용기의 누출사고에서 사고결과에 미치는 최적의 변수를 나타나기 위해 조업조건을 표준조건으로 하였다. 장외영향평가의 위험성 평가에 사용되는 것으로 USEPA와 NOAA에서 공동 개발된 대기확산 모델인 ALOHA (V5.4.4) 모델을 사용하였다. 화학물질을 대량으로 제조 및 취급하고 있는 여수 국가산업단지를 연구 대상지역으로하여, 기상변수와 공정변수들을 설정하여 시나리오별로 모델링을 하여 누출사고에 대한 특성을 도출하였다. 가우시안 확산모델에 따른 관심지점의 농도 추정치를 산출하였고, ALOHA 모델링 결과 염소 확산에 의한 유해위험거리는 대기온도가 높고 풍속의 감소와 대기 안정도가 안정할수록 증가 하는 것으로 분석되었다.

• 한국수처리학회지
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• 제26권6호
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• pp.3-12
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• 2018

The objective of this study was to evaluate the radius of influence of effluent of water treatment system developed for the purpose of improvement of reservoir water quality using fluorescent dye (Rhodamine-WT) tracer experiment and 3-D numerical model. The tracer experiment was carried out in a medium-sized agricultural reservoir with a storage capacity of $227,000m^3$ and an average depth of 1.6 m. A guideline with a total length of 160 m was installed at intervals of 10 m in the horizontal direction from the discharge part, and a Rhodamine measurement sensor (YSI 6130, measurement range $0-200{\mu}g/L$) was used to measure concentration changes in time, distance, and depth. Experimental design was established in advance through Jet theory and the diffusion process was simulated using ELCOM, a three dimensional hydraulic dynamics model. As a result of the study, the direct effect radius of the jet emitted from the applied water treatment system was about 50-70 m, and the radius of physical effect by the advection diffusion was judged to be 100-120 m. The numerical simulations of effluent advection-diffusion of the water treatment system using ELCOM showed very similar results to those of the impact radius analysis using the tracer experiment and jet flow empirical equations. The results provide valuable information on the spatial extent of the water quality improvement devices installed in the reservoir and the facility layout design.

• Geomechanics and Engineering
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• 제34권2호
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• pp.155-171
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• 2023

Aiming at the grouting treatment of water inflow in karst conduits, a visualized experiment system for conduit-type grouting blocking was developed. Through the improved water supply system and grouting system, and the optimized multisource information monitoring system, the real-time observation of diffusion and deposition of slurry, and the data acquisition of pressure and velocity during the whole process of grouting were realized, which breaks through the problem that the monitoring element is easy to fail due to slurry adhesion in conventional test system. Based on the grouting experiments in static and flowing water, the diffusion and deposition behavior of the quick-setting slurry under different working conditions were analyzed. The temporal and spatial variation behavior of the pressure and velocity were studied, and the blocking mechanism of the grouting were further revealed. The results showed that: (1) Under the flowing water condition, the counter-flow diffusion distance of slurry was negatively correlated with the flow water velocity and the volume ratio of cement and sodium silicate (C-S ratio), and positively correlated with the grouting volume. The slurry deposition thickness was negatively correlated with the flowing water velocity, and positively correlated with the grouting volume and C-S ratio. (2) The pressure increased slowly before blocking of the flowing water and rapidly after blocking in karst conduits. (3) With the continuous progress of grouting, the flowing water velocity decreased slowly first, then significantly, and finally tended to be stable. According to the research results, some engineering recommendations were put forward for the grouting treatment of the conduit-type water inflow disaster, which has been successfully applied in the treatment project of the China Resources Cement (Pingnan) Limestone Mine. This study provided some guidance and reference for the parameter optimization of grouting for the treatment projects of water inflow in karst conduits.

• 한국분말재료학회지
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• 제31권3호
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• pp.220-225
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• 2024

Molten salt reactors represent a promising advancement in nuclear technology due to their potential for enhanced safety, higher efficiency, and reduced nuclear waste. However, the development of structural materials that can survive under severe corrosion environments is crucial. In the present work, pure Ni was deposited on the surface of 316H stainless steel using a directed energy deposition (DED) process. This study aimed to fabricate pure Ni alloy layers on an STS316H alloy substrate. It was observed that low laser power during the deposition of pure Ni on the STS316H substrate could induce stacking defects such as surface irregularities and internal voids, which were confirmed through photographic and SEM analyses. Additionally, the diffusion of Fe and Cr elements from the STS316H substrate into the Ni layers was observed to decrease with increasing Ni deposition height. Analysis of the composition of Cr and Fe components within the Ni deposition structures allows for the prediction of properties such as the corrosion resistance of Ni.