• The Korean Journal of Ceramics
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• v.5 no.4
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• pp.379-385
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• 1999

Minute boehmite crystals with high aspect rations, which were hydrothermally synthesized from gibbsite in $Ba(OH)_2$ solution, occluded Ba with the Ba/Al molar ratio of about 0.03 in their interlayers. Their surface areas were about 14$\m^2$/g. The Ba-intercalated bohemite samples were partly used for producing $BaAl_{12}O){19}$ with low sinterability by externally supplementing $Ba(OH)_2$, and for forming transient aluminas. The surface area of $BaAl_{12}O){19}$ obtained by firing at $1500^{\circ}C$ for 3 h was 5.3$\m^2$/g, which was significantly lower than 12$\m^2$/g of the sol-gel origin. While a mixture ${\gamma}$-alumina and BaO is known to from $BaAl_{12}O){19}$ at $1200^{\circ}C$, solid state reaction between η-alumina transformed from the Ba-intercalated boehmite and BaO formed from $Ba(OH)_2$ deposited on the boehmite started above $1300^{\circ}C$. This suggests that large sized $Ba^{2+}$ ion occluded in η-alumina considerably suppresses the diffusion of $Al^{3+}$ ion. The surface area of the Ba-intercalated boehmite fired at $1400^{\circ}C$ for 3h was as high as 14$\m^2$/g indicative of its potential applicability to combustion catalysts. But it was decreased to 5.0$\m^2$/g after firing at $1500^{\circ}C$ for 3 h, accompanied by abrupt formations of $\alpha$-alumina and $BaAl_{12}O){19}$ as main products. The suppression of $\alpha$-alumina formation up to $1400^{\circ}C$ also suggests the significant blocking effect of $Ba^{2+}$ ion on the diffusion of the component ions.

• Transactions of the Korean Society of Mechanical Engineers
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• v.12 no.4
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• pp.847-864
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• 1988

The main purpose of this study is to investigate the local velocity acceleration in a boundary layer diffusion flame over a flat plate. In order to know the effect of separation on the local velocity acceleration, two typical cases, flows with and without separation, are considered. For these cases, flow visualization using paraffine smoke tracers has been made. Mean velocity and r.m.s. value of fluctuating velocity are measured by using a laser Doppler velocimeter. In addition, measurements of time-mean concentration and time-mean temperature have been made. Time-mean density profiles have been obtained from the data of concentration and temperature. The obtained results are summarized as follows : (1) In the case without separation, the local velocity acceleration is clearly observed near the visible flame zone for all flow conditions. On the while, in the case with serration, the local velocity acceleration is observed only at low free stream velocity and high fuel injection velocity. As increasing the free stream velocity or decreasing the fuel injection velocity, it is not distinctly observed in the mean velocity profile. (2) The r.m.s. value of fluctuating velocity is significantly decreased by combustion in the case with separation. But in the case without separation, the r.m.s. value is increased near the visible flame zone in comparison with cold flow. In both cases, the peak value of r.m.s. appeared just at the visible flame zone, where the mean velocity gradient is not too high.

• Journal of Advanced Marine Engineering and Technology
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• v.30 no.3
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• pp.403-412
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• 2006

The effect of a wall temperature on the soot deposition process from a diffusion flame to a solid wall was investigated in a microgravity environment to attain in-situ observations of the process. The fuel for the flames was an ethylene ($C_2H_4$). The surrounding oxygen concentration was 35% with surrounding air temperatures of $T_a=600K$. In the study, three different wall temperatures. $T_w$=300, 600, 800K, were selected as major test conditions. Laser extinction was adopted to determine the soot volume fraction distribution between the flame and burner wall. The experimental results showed that the maximum soot volume fractions at $T_w$=300, 800 K were $8.8{\times}10^{-6},\;9.2{\times}10^{-6}$, respectively. However, amount of soot deposition on wall surface was decreased because of lower temperature gradient near the wall with increasing wall temperature. A numerical simulation was also performed to understand the motion of soot particles in the flame and the characteristics of the soot deposition to the wall. The results from the numerical simulation successfully predicted the differences in the motion of soot particles by different wall temperature near the burner surface and are in good agreement with observed soot behavior that is, the 'soot line', in microgravity.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.25 no.4
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• pp.600-609
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• 2001

WSGGM based low-resolution spectral model for calculating radiation transfer in combustion gases is applied to estimate self-absorption of radiation energy in one-dimensional opposed flow flames. Development of such a model is necessary in order to enable detailed chemistry-radiation interaction calculations including self-absorption. Database of band model parameters which can be applied to various one-dimensional opposed flow diffusion and partially premixed flames is created. For the validation of the model and database, low resolution spectral intensities at fuel exit side are calculated and compared with the results of a narrow band model with those based on the Curtis-Godson approximation. Good agreements have been found between them. The resulting radiation model is coupled to the OPPDIF code to calculate the self-absorption of radiant energy and compared with the results of an optically thin calculation and the results of a discrete ordinates method in conjunction with the statistical narrow band model. Significant self-absorption of radiation is found for the flames considered here particularly for the fuel side of the reacting zone. However, the self-absorption does not have significant effects on the flame structure in this case. Even in the case of the low velocity diffusion flame and the partially premixed flame of low equivalence ratio, the effects of self-absorption of radiation on the flame temperature and production of minor species are not significant.

• Transactions of the Korean Society of Automotive Engineers
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• v.5 no.3
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• pp.54-65
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• 1997

To quantify the LII signals from soot particle of flames in diesel engine cylinder, a new method has been proposed for correcting LII signal attenuated by soot particles between the measuring point and the detector. It has been verified by an experiment on a laminar jet ethylene-air diffusion flame. Being proportional to the attenuation, the ratio of LII signal at two different detection wavelengths can be used to correct the measured LIIsignal and obtain the unattenuated LII signal, from which the soot volume fraction in the flame can be estimated. Both the 1064-nm and frequency-doubled 532-nm beams from the Nd : YAG laser are used. Single-shot, one-dimensional(1-D) line images are recorded on the intensified CCD camera, with the rectangular-profile laser beam using 1-mm-diameter pinhole. Two broadband optical interference filters having the center wavelengths of 647 nm and 400 nm respectively and a bandwidth of 10 nm are used. This two-wavelength correction has been applied to the ethylene-air coannular laminar diffusion flame, previously studied on soot formation by the laser extinction method in this laboratory. The results by the LII measurement technique and the conventional laser extinction method at the height of 40 nm above the jet exit agreed well with each other except around outside of the peaks of soot concentration, where the soot concentration was relatively high and resulting attenuation of the LII signal was large. The radial profile shape of soot concentration was not changed a lot, but the absolute value of the soot volume fraction around outside edge changed from 4ppm to 6.5 ppm at r=2.8mm after correction. This means that the attenuation of LII signal was approximately 40% at this point, which is higher than the average attenuation rate of this flame, 10~15%.

• Journal of the Korean Society of Marine Environment & Safety
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• v.11 no.1 s.22
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• pp.53-59
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• 2005

It is very dongerous for ship‘s fire which occurs from navigating because of it will not be able to expect fire fighting from land so that handle with the oneself to control. Additionally, in the case of passenger ship is more serious for the reason of not only the property damage but also large life accident can be occurred continuously. When the fire occurs, the many smoke to occur simultaneously as well as the heat from combustion process and the poisonous smoke is brought the life damage as the death from suffocation The purpose of this study is to examine the smoke movement characteristics in the ship's indoor spaces with fire size and location An experimental study was carried out with two sized of fires and three typed of fire source locations. As the results, the smoke and heat diffusion characteristics Ms been showed the most quick rise curve in the case of comer type fire.

• Proceedings of KOSOMES biannual meeting
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• 2005.05a
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• pp.167-173
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• 2005

It is very dangerous for ship‘s fire which occurs from navigating because of it will not be able to expect fire fighting from land so that handle with the oneself to control. Additionally, in the case of passenger ship is more serious for the reason of not only the properly damage but also large life accident can be occurred continuously. When the fire occurs, the many smoke to occur simultaneously as well as the heat from combustion process and the poisonous smoke is brought the life damage as the death from suffocation. The purpose of this study is to examine the smoke movement characteristics in the ship's indoor spaces with fire size and location An experimental study was carried out with two sized of fires and three typed of fire source locations. As the result of it, the smoke and heat diffusion characteristics has been showed the most quick rise curve in the case of comer type fire.

• Journal of the Korean Society of Propulsion Engineers
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• v.22 no.1
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• pp.28-35
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• 2018

In order to analyze the flammability limit and structure of the gaseous methane-gaseous oxygen diffusion flame formed through a shear coaxial injector, combustion experiments were carried out according to the condition of injector recess and propellant mass-flow rate. As a result, it was confirmed that stable anchored flame was observed even at the high oxygen Reynolds number as the propellant momentum flux ratio increased, and that the recess had no significant influence on the flame shape and flammability limit. The anchored flame visualized through a chemiluminescence showed the maximum OH radical emission intensity at a specific position, irrespective of the propellant injection condition, and the radical intensity was greatly reduced by the injector recess.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.36 no.3
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• pp.285-291
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• 2012

A lot of research on the stability of nonpremixed flames has focused on the fuel-nozzle and quarl geometries. Of the work carried out, only a small amount has focused on the stability of the nonpremixed flame according to the recession distance and air-nozzle geometry. Therefore, in this study, a coaxial-diffusion-type gas burner with a swirler is designed for the systematic investigation of the combustion characteristics of a $CH_4$ flame depending on the recession distance and secondary air-nozzle geometry. 1st air is flowed through the swirler, and 2nd air is flowed through each nozzle. It is shown that the secondary air velocity greatly influences the flame length and shape. There is an optimum recession distance for each nozzle for the best combustion efficiency. In this study, it is shown that the optimized recession distance is nearly half the outer diameter of the air-supply nozzle.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.19 no.3
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• pp.112-118
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• 2018

In order to meet the strict emission regulations for internal combustion engines based on fossil fuel, the proportion of after-treatments for vehicles and vessels is gradually increasing. Diesel engines have high power, good fuel economy, and lower $CO_2$ emissions, and their market shares are increasing in commercial vehicles and passenger cars. However, NOx is generated in the localized high-temperature combustion regions, and particulate matter is formed in the zones of diffusion combustion. LNT and urea-SCR catalysts have been developed for after-treatment of the exhaust gas to reduce NOx in diesel vehicles. This study aims to improve the NOx reduction performance of Cu SCR catalyst, which is widely used in light, medium, and heavy-duty diesel engines. The de-NOx performance of $5Cu-2ZrO_2$/93Zeolyst(Si/Al=13.7) SCR catalyst was about 5-50% higher than that of $5Cu-2ZrO_2$/93Zeolite(Si/Al=2.9) at catalyst temperatures of $300^{\circ}C$ or higher. The zeolite had lower metal dispersion than zeolyst, and the reaction rate of the catalyst decreased as the average particle size increased. The $10Cu-2ZrO_2$/88Zeolyst catalyst loaded with 10wt% Cu had the highest NOx conversion rate of 40% at $200^{\circ}C$ and about 65% at $350^{\circ}C$. The ion exchange rate of Cu ions increased with that of Al, the crystalline compound of zeolite, and the de-NOx performance was improved by 20-40% compared to other catalysts.