• Title/Summary/Keyword: Diffusion Coefficient

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Simulation of nanosilver migration from polystyrene nanocomposite into food simulants

  • Soleimani, Jaber;Ghanbarzadeh, Babak;Dehgannya, Jalal;Islami, Sima Baheri;Sorouraddin, Saeed M.
    • Advances in nano research
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    • v.6 no.3
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    • pp.243-255
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    • 2018
  • Polystyrene granules were combined with nanosilver to form a nanocomposite film. One-side migration was conducted to test into three food simulants (3% acetic acid, 10% ethanol and 95% ethanol) at $40^{\circ}C$ temperature on different period of time (2, 4, 6, 8 and 10 days). It was found that, among the simulants, the highest migration amount was obtained with 3% acetic acid, while the 95% ethanol revealed the least migration level. Diffusion coefficients of nanosilver particles into simulants were estimated by inverse simulation using experimental data of concentration variation in the simulants. The finite element method used to solve the mass transfer equation and the numerical results indicates the sameresponse with the experimental data. The numerical results confirmed that the highest diffusion coefficient for acetic acid 3% (1.82E-10 to $1.76E-9m^2\;s^{-1}$) and the lowest diffusion coefficient for ethanol 95% from 2 to 10 days were obtained, respectively. Also, results of diffusion coefficient - concentration relation showed, the diffusion coefficient had in direct correlation with time and concentration. The results indicated that, in the 3% acetic acid, due to the increasing of diffusion coefficient of silver nanoparticles, they are released faster and distributed uniformly.

On Probability Distribution of Chloride Diffusion Coefficient for Recycled Aggregate Concrete

  • Ying, Jingwei;Xiao, Jianzhuang;Meng, Qiujiang
    • International Journal of Concrete Structures and Materials
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    • v.10 no.1
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    • pp.61-73
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    • 2016
  • In predicating the probability distribution of chloride diffusion coefficient of recycled aggregate concrete ($D_{RAC}$), the morphological characteristics of three phases, i.e., the old attached mortar, the natural aggregate and the new mortar, should all be taken into account. The present paper attempts to develop a probability density evolution method (PDEM) to achieve this. After verifying the derived PDEM results with experimental results, the effects of old attached mortar to the $D_{RAC}$ are examined in a quantitative manner. It is found that (1) the variation of the attached mortar content is much sensitive to $D_{RAC}$; (2) given the probability distribution of the content and chloride diffusion coefficient of old mortar, the probability distribution of DRAC can be analysed based on the PDEM; and (3) the critical chloride diffusion coefficient at a certain assurance rate can be obtained by the PDEM. The analysis results of this investigation will be valuable to the durability design for RAC.

A Study on the Prediction of Chloride Diffusion Coefficient in Concrete for mediocre apply (범용적 적용을 위한 콘크리트의 염화물 확산계수 예측에 관한 연구)

  • Kim, Dong-Seok;Yoo, Jae-Kang;Kim, Young-Jin
    • Proceedings of the Korea Concrete Institute Conference
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    • 2006.05b
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    • pp.189-192
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    • 2006
  • This study was performed to suggest the mediocre prediction equation of chloride diffusion coefficient which is used to estimate the service life of marine concrete, in order to provide the useful data for concrete mix design of marine concrete. As a result, the mediocre prediction equation of chloride diffusion coefficient which set W/B and mineral admixture replacement ratio as parameters was presented by performing the multivariate non linear regression analysis.

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Chloride Diffusion Coefficient from NT BUILD 443 (NT BUILD 443에 의한 염소이온 확산계수 고찰)

  • Kim, Ki-Hyun;Cha, Soo-Won;Jang, Sung-Yup
    • Proceedings of the Korea Concrete Institute Conference
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    • 2009.05a
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    • pp.295-296
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    • 2009
  • It is often the case with the durability design to use diffusion coefficient obtained from experimental test. From the analytic solution considering the starting time of exposure, it is confirmed that the diffusion coefficient from NT BUILD 443 underestimates real reference value.

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Life Expectation of Salt Attack for Fire Damaged RC Structure (화재피해를 입은 콘크리트 건축물의 염해 내구수명 산정)

  • Park, Dong-Cheon
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2017.05a
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    • pp.15-16
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    • 2017
  • The properties of concrete damaged by fire change according to the temperature. Diffusion coefficient of chloride ion also can change which affect the life expectation under salt circumstance. Diffusion coefficient was measured by NT BUILD 492 using the concrete specimen damaged by high temperature. FEM analysis was performed to predict the life expectancy which can help to diagnose the concrete diagnose and to design maintenance strategy.

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Probabilistic Characteristics of Effective Diffusion Coefficient in the Porous Media

  • Khim, Jeehyeong
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 1996.11a
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    • pp.58-62
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    • 1996
  • To check the variability of the effective diffusion coefficient in the unsaturated porous soil media. a Monte Carlo simulation was done for the equation suggested by Millington and Quirk(1961). The results shows that the probability density function of D$_{c}$/D$_{o}$ is positively skewed. It means the chance of having less effective diffusion coefficient values in the soil media than mean value is high. Also, the distribution types of D$_{c}$/D$_{o}$ are about same regardless of assumed distribution types of input parameters.ers.ers.

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Evaluation of Chloride Ion Diffusion Coefficient of Coating Materials based on Halo-philic Bacteria (호염성 박테리아 기반 코팅재의 염소이온 확산계수 평가)

  • Yoon, Hyuun-Sub;Lee, Jae-Wuk;Yang, Keun-Hyeok
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2020.11a
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    • pp.159-160
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    • 2020
  • This study examined the potentials for developing a biological coating material with high chloride resistance. The bacteria strains isolated were Halomonas alkaliphile, Halomonas venusta, and Sulfidobacter mediterraneus. Test results revealed that the developed approach is very promising in reducing the chloride ion diffusion coefficient of concrete.

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Prediction of the Durability Life for RC Structures through the Analyzing Chloride Diffusion Coefficient of the Establish Data (기존 자료를 통한 염소이온 확산계수 분석 및 철근콘크리트 구조물의 염해 수명예측)

  • Lee, Woo-Jin;Lee, Sung-Bok;Lee, Han-Seung;Ryu, Jae-Jun;Yun, Byung-Soo
    • Proceedings of the Korea Concrete Institute Conference
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    • 2004.05a
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    • pp.846-849
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    • 2004
  • It is important to decide the precise chloride diffusion coefficient in order to predict the durability plan of concrete structure chloride and prediction of remaining lifetime. However, the inland references are limited to the rapid test in laboratory. The purpose of this study is to examine and analyze the established data, which are restricted by chloride diffusion coefficient, and to examine the prediction of the concrete structure durability by an FEM interpretation and the chloride diffusion coefficient as a variable.

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Influence of Air Void Characteristic on Chloride Diffusion Coefficient and Compressive Strength of Concrete using Urea and Sulfur (요소와 유황을 첨가한 콘크리트의 압축강도와 염화물 확산계수에 대한 공극특성의 영향)

  • Kim, Jae Hyun;Hong, Ki Nam;Jeon, Byeong Gu
    • Journal of the Korean Society of Safety
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    • v.31 no.4
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    • pp.75-81
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    • 2016
  • This study presents the effect of urea and sulfur admixture on compressive strength, chloride diffusion coefficient, and internal void distribution of concrete. Compressive strength of concretes with urea admixture by 5% increased by 5% relative to Control. However, that of concretes with urea admixture over 10% decreased. Chloride diffusion coefficient of concrete with urea and sulfur admixture decreased by 40% relative to Control. Additionally, the volume of internal void of concrete with urea and sulfur admixture decreased by 20% relative to Control. Therefore, it can be mentioned from test results that the use of adequate urea and sulfur admixture improves the mechanical properties and durability of concrete.

Estimation of Probability Valuable for Diffusion Coefficient of Chloride Ion (염소이온 확산계수의 확률변수 평가)

  • Bae Su Ho;Lee Kwang Myong;Kim Jee Sang;Jung Sang Hwa
    • Proceedings of the Korea Concrete Institute Conference
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    • 2005.11a
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    • pp.515-518
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    • 2005
  • In recent years, many research works have been carried out in order to obtain a more controlled durability and long-term performance of concrete structures exposed to chloride environments. In particular, the development of new procedures for probability-based durability analysis and design has been proved to be very valuable. To carry out the procedures described above, the statistical properties of design valuables such as diffusion coefficient of chloride ion, surface chloride concentration, and chloride threshold value etc. should be known. For this purpose, this paper presents the statistical properties of the diffusion coefficient of chloride ion such as mean value and standard deviation with water-cement(w/c) ratio and curing conditions, respectively. It was observed from the test that the standard deviation for the diffusion coefficient of chloride ion was found to be small with decrease in the w/c ratio irrespective of curing conditions and that of standard curing was found to be smaller than that of field curing.

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