• Korean Journal of Food Science and Technology
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• 제27권3호
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• pp.387-393
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• 1995

Diffusion coefficients of moisture and solid, reaction rate constants of carotene destruction, and the fitness of drying models for moisture transfer were determined to study the characteristics of mass transfer during osmotic dehydration. Moisture loss and solid gain were increased with increase of temperature and concentration; temperature had higher osmotic effect than concentration. Diffusion coefficient showed similar trend with osmotic effect. Diffusion coefficients of solids were larger than those of moisture because the movement of solid was faster than that of moisture at the high temperature. Reaction rate constants were affected to the greater extent by concentration changes than by temperature changes. Arrhenius equation was applied to determine the effect of temperature on diffusion coefficients and reaction rate constants. Moisture diffusion required high activation energy in $20^{\circ}Brix$, while relatively low in $60^{\circ}Brix$. To predict the diffusion coefficients and reaction rate constants, a model was established by using the optimum functions of temperature and concentration. The model had high $R^2$ value when applied to diffusion coefficients, but low when applied to reaction rate constants. Quadratic drying model was most fittable to express moisture transfer during drying. In conclusion, moisture content of carrots could be predictable during the osmotic dehydration process, and thereby mass transfer characteristics could be determined by predicted moisture content and diffusion coefficient.

• Membrane Journal
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• 제10권1호
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• pp.19-29
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• 2000

To estimatc mutual diffusion coefficient for the analysis of mass transfer phenomena in polymer/solvent system, two models are proposed and the equations are derived. The estimates of mutual diffusion coefficients are obtained by two models suggested in this work and compared with and experimental data and Vrentas-Duda's. Vrentas-Duda's self diffusion coefficient was used for the mutual diffusion coefficient. Derivative of chemical potential on solvent was derived and used using original UNIFAC-FV and modified UNIFAC-FV. However, Vrentas-Duda's equation for mutual diffusion coefficient contains Flory-Huggins parameter x. For the derivative of chemical potential term, Vrentas-Duda assumed that parameter x was constant and independent of temperatures and concentrations The assumption is one of shortcoming in vrentas-Duda's mutual diffusion coefficient. New methods proposed in this work do not have such assumptions and simplifications. For the solvent of cyclohexane, n-pentane, and n-hexane in PIB(polyisolbutylene) and PMS-BR (poly(p-methylstyrene-co-isobutylene), new methods well correlate the experimental data at various temperatures and concentrations, and predicted the experimental data much better than Vrentas-Duda's for the PIB/toluene system. It is shown that new methods are excellent tools for correlating mutual diffusion coefficient data in polymer/solvent system over wide ranges of temperature and concentration without any assumptions or simplifications.

• Transactions of the Korean Society of Mechanical Engineers B
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• 제34권2호
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• pp.99-103
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• 2010

A new analytic solution was derived for the diffusion into or from an immobile zone of a rectangular 2-D pore. For a long time, the new solution converges to a traditional mobile-immobile zone (MIM) model, but only if the latter is used with an apparent initial concentration that is smaller by almost 20% than the true one. This is the tradeoff for using a simple MIM model instead of an exact model based on the diffusion equation. The mass-transfer coefficient was found to be constant for a sufficiently long time; it was proportional to the molecular diffusion and inversely proportional to the square of the pore depth. The mass-transfer coefficient was time-dependent for a sufficiently short time and may be significantly larger than its asymptotic value.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• 제26권8호
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• pp.366-374
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• 2014

Experimental mass transfer data, which were obtained for the $CO_2$-water slug flows in vertical tubes with 2, 5, and 8mm diameters, were analyzed in comparison with the penetration theory. It was found that a penetration model with molecular diffusion coefficient cannot predict the experimental data accurately. An effective diffusion coefficient, which considers enhancement effect of interfacial waves, was suggested to improve prediction. Another empirical factor was also suggested to consider the effect of non-uniform interface velocity. A modified penetration model was found to be capable of predicting the experimental data reasonably well.

• Transactions of the Korean Society of Mechanical Engineers B
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• 제21권5호
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• pp.589-601
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• 1997

A computer simulation program of a high efficiency condensing heat exchanger is developed. The flue gas flows outside bare tube bundles both in strong cross flow and in weak counter flow and the cooling water inside the tubes. Condensing heat exchangers achieve high efficiency by reducing flue-gas temperatures to a level at which most of the water vapor in the flue gas is condensed and the latent heat associated with phase change of the water is recovered. The computer model has been verified by comparison with measured data. To verify the model, heat transfer coefficient was adjusted, along with the mass transfer diffusion coefficient and pressure drop coefficient, to achieve agreement between predicted and measured data. The efficiencies of heat exchanger increase 2.3 ~ 8.1% by condensations of 6.3 ~ 62.6% of the water vapor in the flue gas.

• Transactions of the Korean Society of Mechanical Engineers
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• 제16권6호
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• pp.1171-1178
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• 1992

An experiment was performed to describe the heat and mass transfer occurring between hot waste gas and cold water through direct contact in a direct contact heat exchanger. This model was then used to obtain an equation of overall heat transfer coefficent based on heat exchanger volume. The diffusion heat transfer rate is 2-3 times larger than the convection heat transfer rate as results of condensation of the water vapor contained in the waste gas. The boiler efficiency increases over 10%.

• Advances in nano research
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• 제6권3호
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• pp.243-255
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• 2018

Polystyrene granules were combined with nanosilver to form a nanocomposite film. One-side migration was conducted to test into three food simulants (3% acetic acid, 10% ethanol and 95% ethanol) at $40^{\circ}C$ temperature on different period of time (2, 4, 6, 8 and 10 days). It was found that, among the simulants, the highest migration amount was obtained with 3% acetic acid, while the 95% ethanol revealed the least migration level. Diffusion coefficients of nanosilver particles into simulants were estimated by inverse simulation using experimental data of concentration variation in the simulants. The finite element method used to solve the mass transfer equation and the numerical results indicates the sameresponse with the experimental data. The numerical results confirmed that the highest diffusion coefficient for acetic acid 3% (1.82E-10 to $1.76E-9m^2\;s^{-1}$) and the lowest diffusion coefficient for ethanol 95% from 2 to 10 days were obtained, respectively. Also, results of diffusion coefficient - concentration relation showed, the diffusion coefficient had in direct correlation with time and concentration. The results indicated that, in the 3% acetic acid, due to the increasing of diffusion coefficient of silver nanoparticles, they are released faster and distributed uniformly.

• 한국해양학회지
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• 제10권2호
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• pp.57-66
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• 1975

Structure of thermocline, characteristics of stability and intensity of vertical transfer have been studied with hourly oceanographic data in each layers on Line 207 from 1968 to 1969. It is found that a typical thermocline is formed at depths of 10 to 50 meters in summer and early autumn and its core is located near depths of 25 meters. The maximum diffusion coefficient of vertical turbulent is found to be 140$\textrm{cm}^2$/sec at the surface layer(i.e., 0-10 meters), while the minimum is 5$\textrm{cm}^2$/sec at depths of 25 meters, consistent with characteristics of stability and structure of thermocline layers. Our computed diffusion coefficient and stability indicate that the mixing hardly takes place below depths of 80 meters during summer and early autumn, but for the rest of the season mixing could move up to the depth of 50 meters. It appears that the Western Channel of the Korea Strait consist of three different water masses during summer and autumn, and for the rest of the season, two kinds are present.

• Journal of the Korean Wood Science and Technology
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• 제22권2호
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• pp.61-70
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• 1994

This study was executed to find the applicability of press drying of tree disk by investigating the shrinkage and drying defect and to form appropriate model by comparing the actual moisture content(MC) and internal temperature in respect of drying time with calculated values based computer simulation to which was applied finite difference method. In press drying disk, heating period, constant drying rate period maintained plateau temperature at 100$^{\circ}C$ and falling drying rate period were significantly distinguished. Actual MC and internal temperature were analogous to those calculated at comparing points. Heat transfer model formed by Fourier's law using specific heat of moist wood and conduction coefficient considering fractional volume of each element of wood cell wall, bound water, free water and air showed applicability as basic data to developing heat expansion, shrinkage and drying stress during press drying. Also mass transfer model formed by Fick's diffusion law using water vapor diffusion coefficient showed applicability. Longitudinal shrinkage was developed by pressure of hot press and tangential shrinkage was restrained by hygrothermal recovery. The heart check, surface check and ring failure were occurred differently in species, but V-shaped crack didn't develop.

• International Journal of Air-Conditioning and Refrigeration
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• 제8권2호
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• pp.69-79
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• 2000

Falling film rectification involves simultaneous heat and mass transfer between vapor and solution film. In the present work, the adiabatic rectification process of ammonia-water vapor by the falling solution film on the vertical plate was investigated. The continuity momentum, energy and diffusion equations for the solution film and the vapor mixture were formulated in integral forms and solved numerically, The model could predict the film thickness, the pressure gradient, and the mass transfer rate. The effects of Reynolds number and ammonia concentration of solution and vapor mixture, rectifier length, and the enhancement of mass transfer coefficient in each phases were investigated. The stripping of water in vapor mixture occurred near the entrance of ammonia solution, which imposed the proper size of an adiabatic rectifier. Rectifier efficiency increased as film Reynolds number increased and as vapor mixture Reynolds number decreased. The improvement of rectifier efficiency was significant with the enhancement of mass transfer coefficient in falling film.