• Bulletin of the Korean Chemical Society
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• v.22 no.4
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• pp.367-371
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• 2001

Lithium inserted into artificial carbon has been synthesized as a function of the Li concentration. The characteristics of these prepared compounds were determined from the studies using X-ray diffraction(XRD), solid nuclear magnetic resonance (NM R) spectrophotometric and differential scanning calorimeter(DSC) analysis. X-ray diffraction showed that lower stage intercalation compounds were formed with increasing Li concentration. In the case of the AG3, most compounds formed were of the stage 1 structure. Pure stage 1 structural defects of artificial graphite were not observed. 7Li-NMR data showed that bands are shifted toward higher frequencies with increasing lithium concentration; this is because non-occupied electron shells of Li increased in charge carrier density. Line widths of the Li inserted carbon compounds decreased slowly because of nonhomogeneous local magnetic order and the random electron spin direction for located Li between graphene layers. The enthalpy and entropy changes of the compounds can be obtained from the differential scanning calorimetric analysis results. From these results, it was found that exothermic and endothermic reactions of lithium inserted into artificial carbon are related to the thermal stability of lithium between artificial carbon graphene layers.

• Computers and Concrete
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• v.31 no.2
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• pp.139-149
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• 2023

This article investigates the statically analysis regarding the thermal buckling behavior of a nonuniform small-scale nanobeam made of functionally graded material based on classic beam theories along with the nonlocal Eringen elasticity. The material distribution of functionally graded structures is composed of temperature-dependent ceramic and metal phases in axial and thickness directions, called two-dimensional functionally graded (2D-FG). The partial differential (PD) formulations and end conditions are extracted by using to the conservation energy method. The porosity voids are assumed in the nonuniform functionally graded (FG) structure. The thermal loads are in the axial direction of the beam. The extracted nonlocal PD equations are also solved by employing generalized differential quadrature method (GDQM). Last but not least, the information acquired is used to produce miniature sensors, providing a unique perspective on the growth of nanoelectromechanical systems (NEMS).

• Applied Chemistry for Engineering
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• v.4 no.1
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• pp.75-81
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• 1993

The thermochemical stability of $Ni^{2+}-faujasite$ was studied by differential thermal analysis(DTA), thermal gravitational analysis(TGA), X-ray diffraction analysis(XRD) and quantum chemical calculations. Dehydration of $Ni^{2+}-faujasite$ was observed at 373-773K. A CNDO/2 calculations have been applied on cluster models for the representative T sites in faujasite to get total energy and wiberg bond orders. It has proved that the decrease of zeolitic crystallinity is directly related to the weakening of Al-O bonds in framework.

• Journal of Sericultural and Entomological Science
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• v.49 no.2
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• pp.77-80
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• 2007

Silk fibroin/poly (vinyl pyrrolidone) conjugates were prepared and characterized through differential thermal calorimeter and thermogravimetry. The glass transition temperature (Tg) of poly (vinyl pyrrolidone) was not changed by reaction with silk fibroin. However, abnormal exothermic peak was observed at the silk fibroin/poly (vinyl pyrrolidone) conjugates. Thermogravimetric analysis showed that thermal stability of silk fibroin was relatively increased by reaction with PVP.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2011.04a
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• pp.421-424
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• 2011

Thermal Analyses are conducted to measure various factors of a liquid fuel required for numerical analysis. Thermal Analyses are divided into two different methods of TGA (Thermo Gravimetric Analysis) and DSC (Differential Scanning Calorimetry). Non-isothermal experimental results are analyzed using by TGA. The results are filtered by a Freeman Carroll method. At the same time, chemical parameters of unknown liquid fuel, activation temperature and reaction order are measured to 6128.2 K and 1.4, respectively. Furthermore, the parameters can be obtained by various mathematical methods. It is found that tha parameters depend on the processing method.

• Advances in Computational Design
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• v.2 no.2
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• pp.107-119
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• 2017

The Micro circular diaphragm (MCD) is the mechanical actuator part used in the micro electro-mechanical sensors (MEMS) that combine electrical and mechanical components. These actuators are working under harsh mechanical and thermal conditions, so it is very important to study the mechanical and thermal behaviors of these actuators, in order to do with its function successfully. The objective of this paper is to determine the thermo-mechanical behavior of MCD by developing the traditional bulge test technique to achieve the aims of this work. The specimen is first pre-stressed to ensure that is no initial deflection before applied the loads on diaphragm and then clamped between two plates, a differential pressure (P) and temperature ($T_b$) is leading to a deformation of the MCD. Analytical formulation of developed bulge test technique for MCD thermo-mechanical characterization was established with taking in-to account effect of the residual strength from pre-stressed loading. These makes the plane-strain bulge test ideal for studying the mechanical and thermal behavior of diaphragm in both the elastic and plastic regimes. The differential specimen thickness due to bulge effect to describe the mechanical behavior, and the temperature effect on the MCD material properties to study the thermal behavior under deformation were discussed. A finite element model (FEM) can be extended to apply for investigating the reliability of the proposed bulge test of MCD and compare between the FEM results and another one from analytical calculus. The results show that, the good convergence between the finite element model and analytical model.

• Structural Engineering and Mechanics
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• v.59 no.2
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• pp.343-371
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• 2016

In this paper thermo-mechanical vibration analysis of a porous functionally graded (FG) Timoshenko beam in thermal environment with various boundary conditions are performed by employing a semi analytical differential transform method (DTM) and presenting a Navier type solution method for the first time. The temperature-dependent material properties of FG beam are supposed to vary through thickness direction of the constituents according to the power-law distribution which is modified to approximate the material properties with the porosity phases. Also the porous material properties vary through the thickness of the beam with even and uneven distribution. Two types of thermal loadings, namely, uniform and linear temperature rises through thickness direction are considered. Derivation of equations is based on the Timoshenko beam theory in order to consider the effect of both shear deformation and rotary inertia. Hamilton's principle is applied to obtain the governing differential equation of motion and boundary conditions. The detailed mathematical derivations are presented and numerical investigations are performed while the emphasis is placed on investigating the effect of several parameters such as porosity distributions, porosity volume fraction, thermal effect, boundary conditions and power-low exponent on the natural frequencies of the FG beams in detail. It is explicitly shown that the vibration behavior of porous FG beams is significantly influenced by these effects. Numerical results are presented to serve benchmarks for future analyses of FG beams with porosity phases.

• Nuclear Engineering and Technology
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• v.49 no.8
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• pp.1636-1644
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• 2017

The main purpose of this article is to describe the magnetohydrodynamic stagnation point flow of Walter-B nanofluid over a stretching sheet. The phenomena of heat and mass transfer are based on the involvement of thermal radiation and chemical reaction. Characteristics of Newtonian heating are given special attention. The Brownian motion and thermophoresis models are introduced in the temperature and concentration expressions. Appropriate variables are implemented for the transformation of partial differential frameworks into sets of ordinary differential equations. Plots for velocity, temperature, and nanoparticle concentration are displayed and analyzed for governing parameters. The skin friction coefficient and local Nusselt and Sherwood numbers are studied using numerical values. The temperature and heat transfer rate are enhanced within the frame of the thermal conjugate parameter.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.13 no.12
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• pp.1223-1229
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• 2001

Though conventional calorimetry methods such as differential scanning calorimetry (DSC) and differential thermal analysis (DTA) are used generally in measuring heat of fusion, T-history method has the advantages of a simple experimental apparatus and no requirements of sampling process, which is particularly useful for measuring thermal properties of inhomogeneous phase change materials (PCMs) in sealed tubes. However, random criteria (a degree of supercooling) used in selecting the range of latent heat release and neglecting sensible heat during the phase change process can cause significant errors in determining the heat of fusion. In the present study, it was shown that a 40% discrepancy exists between the original T-history and the present methods when analyzing the same experimental data. As a result, a reasonable modification to the original T-history method is proposed.

• Journal of the Korean Institute of Telematics and Electronics
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• v.4 no.3
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• pp.28-33
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• 1967

The analysis of differential amplifier is simplified by the extention of bisection theorem. In order to reduce the thermal and porwor drifts, a self compensating circuit is employed. The optimum conditions of the self compensating circuit are: the base-emitter voltage of one transistor should be equal to the other's base-emitter voltage for basic self compensating circuit, the tempereature coefficients of base-emitter voltage of one transistor equal to the others for thermal compensation. By regarding the thermal and power drifts the experiments were performed were performed and the numerical results were consistent with the measured values.