• Elastomers and Composites
• /
• v.48 no.4
• /
• pp.276-281
• /
• 2013

Polyester type polyurethane foam modified with acrylic polyol was prepared by quasi prepolymer method. Thermal and dynamic mechanical properties of polyurethane foam were analysed by thermal gravimetric analysis(TGA) and dynamic mechanical analysis(DMA). Also, glass transition temperature was measured by differential scanning calorimeter(DSC). As acrylic polyol contents were increased, thermal stability measured by TGA was slightly decreased. Storage modulus was increased and tan delta was decreased with increasing of acrylic polyol contents.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
• /
• 1994.05a
• /
• pp.30-33
• /
• 1994

This paper studies on the effect of DSC(Differential Scanning Calorimeter) analysis condition on the glass transition temperature of silica filled epoxy network polymer used for ultra-high voltage apparatus. The effects of temperature scanning rate specimen size and gas flow rate on measured glass transition temperature have been studied in order to select optimum thermal analysis condition.

• Journal of the Korean Society of Manufacturing Technology Engineers
• /
• v.21 no.6
• /
• pp.976-981
• /
• 2012

In this study, hardness, microstructure and temperature of glass transition are measured respectively by using SEM (Scanning electron microscope) and DSC (Differential scanning calorimeter) to analyze the effects on material properties by after-curing in the epoxy resin. As the result of hardness test according to the after-curing conditions, the higher the temperature of after-curing, hardness and heat resistance are, the higher hardness is. As a result of microstructure for each specimen by SEM, it could be confirmed that the specimen with after-curing has more dense fracture surface. It is also found that temperatures of glass transitions by DSC are comparatively higher in the specimens with after-curing, and the differences between after-curing conditions are negligible.

• Journal of the Korean Society of Safety
• /
• v.25 no.3
• /
• pp.61-65
• /
• 2010

Most of the chemical reactions performed in the chemical industry are exothermic, meaning that thermal energy is released during the reaction. It is also important to understand the thermal hazards such as thermal stabilities and runaway reactions, which are governed by thermodynamics and reaction kinetics of the mixed materials. The paper was described the evaluation of thermal behavior caused by an exothermic batch process in manufacture of the vinyl acetate resin. The aim of the study was to evaluate the thermal stabilities of raw materials with operating conditions such as a reaction inhibitor, heating rate, reaction atmosphere and the mount of methanol charged in the vinyl acetate polymerization process. The experiments were performed in the differential scanning calorimeter(DSC), C 80 calorimeter, and thermal screening unit($TS^u$). It was suggested that we should provide the thermal characteristics for raw materials to present safe precautions with operating conditions in the vinyl acetate polymerization process.

• Journal of the Korean Society of Safety
• /
• v.16 no.2
• /
• pp.75-79
• /
• 2001

For handling and storage of reactive chemicals, the hazard evaluations have been extremely important. In the chemical industry, the most concerns are focused on the thermal harzards such as runaway reactions and thermal decompositions, which are mostly governed by thermodynamics and reaction kinetics or these reactive chemical in the system. This study no investigated the thermal decomposition characteristics of nitrophenylhydrazine isomers by using differential scanning calorimeter(DSC) and accelerating rate calorimeter(ARC). Experimental results showed that exothermic onset-temperatures in nitrophenylhydrazine(NPH) isomers were about 160-$210^{\circ}C$ by DSC and 100-$150^{\circ}C$ by ARC. The decomposition temperature acquired by ARC was about 50-$60^{\circ}C$ lower than that by DSC. Reaction heats were about 40-100cal/g by DSC and 330-750ca1/g by ARC. While ortho isomer of NPH show two distinct exothermic peaks, para isomer shows a single peak in DSC curves. The first exothermic peak for 2-NPH is mainly due to intramolecular dehydration forming 1-hydroxybenzotriazole(HOBT) and the second exothermic peak is mainly due to the decomposition of HOBT formed in the first step of decomposition. The exothermin peak in the DSC curve for 4-NPH is mainly due to dissociation of hydrazino and nitro groups.

• Transactions on Electrical and Electronic Materials
• /
• v.11 no.2
• /
• pp.69-72
• /
• 2010

This study investigates the thermal and mechanical properties of insulation elements through the mixing of epoxy based micro and nano particles. Regarding their thermal properties, differential scanning calorimeter and dynamic mechanical analyser were used to calculate the cross-linking densities for various types of insulation elements. The mechanical properties of the bending strength, the shape and scale parameters, were obtained using the Weibull plot. This study obtained the best results in the scale parameters, at 0.5 phr, for the bending strength of the epoxy nano-and-micro mixture composites.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
• /
• v.14 no.2
• /
• pp.168-174
• /
• 2002

In order to obtain a new heat transfer fluid having a high thermal capacity, micro-capsules of a phase-change material can be a successful candidate to be added into water. In this study, 25, 50, 100, and $200\mu$m diameter micro-encapsulated Lauric acids were tested by a differential scanning calorimeter. The Lauric acid itself had a single freezing curve, but the micro-encapsulated Lauric acid had double freezing curves. The second freezing dominated for $25\mu$m diameter Lauric acids. But the first freeing energy became big as the size of the capsule increased.

• Journal of the Society of Cosmetic Scientists of Korea
• /
• v.26 no.1
• /
• pp.213-232
• /
• 2000

Cetostearyl alcohol has been incorporated into cosmetic or pharmaceutial emulsions to give them an appropriate consistency and a long term stability. It is well known that cetostearyl alcohol forms a gel phase with a nonionic surfactant in an aqueous system, and the properties of the gel phase depend on several factors such as the ratio of fatty alcohols. The aim of the present Paper is to investigate the effect of the structural difference of the lipophilic part of surfactants on the stability of the gel phase in the nonionic surfactant / cetostearyl alcohol / water ternary systems using differential scanning calorimeter. It is concluded that the gel phase formed by the surfactant having the bended alkyl chain is more unstable than that formed by the case of the straight alkyl chain, and we discussed the reason why the former is more unstable after long term storage by means of the measurements of the ${\Delta}$H.

• Journal of Adhesion and Interface
• /
• v.9 no.2
• /
• pp.1-7
• /
• 2008

Using biodegradable polycaprolactone, the microcapsules were prepared by solvent evaporation method. Retinol was selected as a core material, which was used as an important ingredient material in cosmetic fields. Poly(vinyl alcohol) was used as a stabilizer. The shape and property of the microcapsules were characterized by scanning electron microscope and differential scanning calorimeter, and the release rate of the microcapsule was measured by UV spectrophotometer. The microcapsules were prepared, changing the concentration of wall material, the stirring rate, and the concentration of stabilizer. Under the optimum condition, the microcapsules were formed, which showd 5~6 um in diameter and got the homogeneous sphere shape.

• The Korean Journal of Food And Nutrition
• /
• v.24 no.4
• /
• pp.740-745
• /
• 2011

Ohmic heating uses electric resistance heat which occurs equally and rapidly inside food when an electrical current is passed throught. In this study, we observed the physical & chemical characteristics changes which occurs in soybean protein during heating denaturation by using ohmic and conventional heating. After the ohmic heating process, we could not find any change of the primary protein structure in the denaturated soy protein samples. However, the rate of imbibed water(RIW) of the ohmic samples was 2 times faster than that of the conventional samples. Also the ANS-surface hydrophobicity was decreased, which is very closely related to RIW. In the differential scanning calorimeter(DSC) analysis result, all 7S soyprotein fraction samples were completely denaturated by ohmic and conventional heating. However, the 11S samples were completely denatured only by ohmic heating. According to the DSC result, we decided that soyprotein was damaged by temperature and electrical current during ohmic heating. The damage of electrical current was a cause of the characteristic changes.