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Characterization of LiNi1/3Co1/3Mn1/3O2 Cathode Materials Prepared from Different Precursors in Lithium Rechargeable Batteries (리튬2차전지에서 다른 전구체로부터 합성된 LiNi1/3Co1/3Mn1/3O2 양극 활물질의 특성)

  • Kim, Sung-Keun;Hong, Sung-Wan;Han, Kyeong-Sik;Lee, Hong-Ki;Shim, Joong-Pyo
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.21 no.11
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    • pp.1029-1035
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    • 2008
  • $LiNi_{1/3}Co_{1/3}Mn_{1/3}O_2$ cathode materials prepared from different precursors in lithium rechargeable batteries were characterized by various analytical methods. $LiNi_{1/3}Co_{1/3}Mn_{1/3}O_2$ powders were synthesized by using solid-state reaction method and their physical and chemical properties were analyzed by XRD, SEM, particle size analyzer and TCP-AES. These materials showed different crystallinity, particle size, surface morphology and chemical composition. Also, the charge/discharge cycling of $LiNi_{1/3}Co_{1/3}Mn_{1/3}O_2$ electrodes was carried out under various cut-off voltages and it showed different behaviors. It was found that the electrochemical cyclability of $LiNi_{1/3}Co_{1/3}Mn_{1/3}O_2$ was strongly related to its crystallinity.

DSSCs Efficiency by Tape Casting Pt Counter Electrode and Different Thickness Between Two Substrates (Pt 상대전극 성막 두께와 두 기판 간격에 따른 DSSC의 효율 특성)

  • Kwon, Sung-Yeol;Yang, Wook;Zhou, Zeyuan
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.26 no.3
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    • pp.209-215
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    • 2013
  • DSSCs electrical characteristics and efficiency fabricated with different tape casting thickness Pt counter electrodes and different thickness between $TiO_2$ photo electrode and Pt counter electrode substrate were studied. 1 layer Pt counter electrode shows 3.979% efficiency. Efficiency increased as tape casting thickness decreased. The lowest open-circuit voltage was a 0.726 V and the highest short-circuit current was a 2.188 mA on 1 layer Pt counter electrode. On the different thickness between two substrates, the lowest open-circuit voltage 0.712 V and the highest short-circuit current 2.787 mA was measured at $60{\mu}m$ surlyn film thickness and it shows the highest value of 5.067% efficiency.

Electrical Properties of Silicone Rubber with Different Particle Size and Amount of ATH (ATH의 입자크기 및 첨가량에 따른 실리콘 고무의 전기적 특성)

  • Park, Hoy-Yul;Kang, Dong-Pil;Ahn, Myeong-Sang;Myung, In-Hae;Lee, Tae-Hui;Lee, Tae-Joo
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.11a
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    • pp.227-230
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    • 2003
  • Silicone rubber has very excellent chemical stability and hydrophobicity. A hydrophobic surface can prevent the formation of continuous water films on the surface in wet and heavily contaminated conditions. This phenomenon contributes to the suppression of leakage current and partial discharges on insulator surfaces. Silicone rubber has been used much for housing materials of polymer insulators. ATH is added to the silicone rubber for improvement of its resistance against surface discharge. In this paper, ATH with different particle size and content was added to the silicone rubber during compounding. Silicone rubber was deteriorated by a corona treatment. Hydrophobicity recovery rate after corona treatment and arc resistance of silicone rubber were investigated. Hydrophobicity recovery rate of silicone rubber was evaluated by the measurement of contact angle. Arc resistance was evaluated by measuring weight loss of silicone rubber after arc resistance test. It was observed that the hydrophobicity recovery rate and arc resistance of silicone rubber were different when different particle size and content of ATH were added.

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Effects of Span-to-depth Ratio and Poisson's Ratio on Elastic Constants from Bending and Plate Tests

  • Jeong, Gi Young;Kong, Jin Hyuk
    • Journal of the Korean Wood Science and Technology
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    • v.43 no.2
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    • pp.177-185
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    • 2015
  • The goal of this study is to evaluate the limitation of ASTM D 198 bending and ASTM D 3044 in determination of elastic modulus and shear modulus. Different material properties and span to depth ratios were used to analyze the effects of material property and testing conditions. The ratio of true elastic modulus to apparent elastic modulus evaluated from ASTM D 198 bending sharply decreased with increment of span to depth ratio. Shear modulus evaluated from ASTM D 198 bending decreased with increment of depth, whereas shear modulus evaluated from ASTM D 3044 was hardly influenced by increment of depth. Poisson's ratio influenced shear modulus from ASTM D 198 bending but did not influence shear modulus from ASTM D 3044. Different shearing factor was obtained for different depths of beams to correct shear modulus obtained from ASTM D 198 bending equivalent to shear modulus from theory of elasticity. Equivalent shear modulus of materials could be obtained by applying different shearing factors associated with beam depth for ASTM D 198 bending and correction factor for ASTM D 3044.

Variation of reliability-based seismic analysis of an electrical cabinet in different NPP location for Korean Peninsula

  • Nahar, Tahmina Tasnim;Rahman, Md Motiur;Kim, Dookie
    • Nuclear Engineering and Technology
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    • v.54 no.3
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    • pp.926-939
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    • 2022
  • The area of this study will cover the location-wise seismic response variation of an electrical cabinet in nuclear power point (NPP) based on classical reliability analysis. The location-based seismic ground motion (GM) selection is carried out with the help of probabilistic seismic hazard analysis using PSHRisktool, where the variation of reliability analysis can be understood from the relation between the reliability index and intensity measure. Two different approaches such as the first-order second moment method (FOSM) and Monte Carlo Simulation (MCS) are helped to evaluate and compare the reliability assessment of the cabinet. The cabinet is modeled with material uncertainty utilizing Steel01 as the material model and the fiber section modeling approach is considered to characterize the section's nonlinear reaction behavior. To verify the modal frequency, this study compares the FEM result with recorded data using Least-Squares Complex Exponential (LSCE) method from the impact hammer test. In spite of a few investigations, the main novelty of this study is to introduce the reader to check and compare the seismic reliability assessment variation in different seismic locations and for different earthquake levels. Alongside, the betterment can be found by comparing the result between two considered reliability estimation methods.

Chaotic phenomena in the organic solar cell under the impact of small particles

  • Jing, Pan;Zhe, Jia;Guanghua, Zhang
    • Steel and Composite Structures
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    • v.46 no.1
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    • pp.15-31
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    • 2023
  • Organic solar cells utilized natural polymers to convert solar energy to electricity. The demands for green energy production and less disposal of toxic materials make them one of the interesting candidates for replacing conventional solar cells. However, the different aspects of their properties including mechanical strength and stability are not well recognized. Therefore, in the present study, we aim to explore the chaotic responses of these organic solar cells. In doing so, a specific type of organic solar cell constructed from layers of material with different thicknesses is considered to obtain vibrational and chaotic responses under different boundaries and initial conditions. A square plate structure is examined with first-order shear deformation theory to acquire the displacement field in the laminated structure. The bounding between different layers is considered to be perfect with no sliding and separation. On the other hand, nonlocal elasticity theory is engaged in incorporating the structural effects of the organic material into calculations. Hamilton's principle is adopted to obtain governing equations with regard to boundary conditions and mechanical loadings. The extracted equations of motion were solved using the perturbation method and differential quadrature approach. The results demonstrated the significant effect of relative glass layer thickness on the chaotic behavior of the structure with higher relative thickness leading to less chaotic responses. Moreover, a comprehensive parameter study is presented to examine the effects of nonlocality and relative thicknesses on the natural frequency of square organic solar cell structure.

Analysis of stiffened Al/SiC FGM plates with cutout under uniaxial and localized in-plane edge loadings

  • P. Balaraman;V.M. Sreehari
    • Structural Engineering and Mechanics
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    • v.89 no.6
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    • pp.601-615
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    • 2024
  • Effect of ring and straight stiffeners in the buckling as well as vibration characteristics of metal-ceramic functionally graded plates with cutout subjected to various uniaxial and localized in-plane compressive edge loadings was explored in the present work. In the current work, the distinguishing characteristics of metal and ceramic are merged in a single volume, and power law was used for estimating the material composition throughout thickness. Buckling and free vibration characteristics were studied initially for unstiffened Al/SiC functionally graded plates with cutout. Subsequently, the influence of cutout ratio on buckling load as well as natural frequency for different power law indices was discussed. The functionally graded plate was stiffened by three different stiffener patterns, namely; ring stiffener, straight stiffener, as well as a combination of the ring and the straight stiffener, to enhance the buckling as well as vibration characteristics. The effect of stiffener depth ratio for different stiffener patterns was also presented for functionally graded plates having different cutout sizes under various loading conditions. Such studies on functionally graded material have potential applications in a variety of technological fields including the aerospace and defense sectors.

Influence of time-dependency on elastic rock properties under constant load and its effect on tunnel stability

  • Aksoy, C.O.;Aksoy, G.G. Uyar;Guney, A.;Ozacar, V.;Yaman, H.E.
    • Geomechanics and Engineering
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    • v.20 no.1
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    • pp.1-7
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    • 2020
  • In structures excavated in rock mass, load progressively increases to a level and remains constant during the construction. Rocks display different elastic properties such as Ei and ʋ under different loading conditions and this requires to use the true values of elastic properties for the design of safe structures in rock. Also, rocks will undergo horizontal and vertical deformations depending on the amount of load applied. However, under constant loads, values of Ei and ʋ will vary in time and induce variations in the behavior of the rock mass. In some empirical equations in which deformation modulus of the rock mass is taken into consideration, elastic parameters of intact rock become functions in the equation. Hence, the use of time dependent elastic properties determined under constant loading will yield more reliable results than when only constant elastic properties are used. As well known, rock material will play an important role in the deformation mechanism since the discontinuities will be closed due to the load. In this study, Ei and ʋ values of intact rocks were investigated under different constant loads for certain rocks with high deformation capabilities. The results indicated significant time dependent variations in elastic properties under constant loading conditions. Ei value obtained from deformability test was found to be higher than the Ei value obtained from the constant loading test. This implies that when static values of elastic properties are used, the material is defined as more elastic than the rock material itself. In fact, Ei and ʋ values embedded in empirical equations are not static. Hence, this workattempts to emerge a new understanding in designing of safer structures in rock mass by numerical methods. The use of time-dependent values of Ei and ʋ under different constant loads will yield more accurate results in numerical modeling analysis.

The optical properties of ZnS/$Na_3AlF_6$/ZnS/Cr multi-layered thin film with different optical thickness (ZnS/$Na_3AlF_6$/ZnS/Cr 다층 박막의 광학적 두께 변화에 따른 광특성)

  • Kim, Jun-Sik;Jang, Gang-Jae;Jang, Gun-Eik
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.06a
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    • pp.535-536
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    • 2008
  • Multi-layered thin films of ZnS/$Na_3AlF_6$/ZnS/Cr were deposited on glass substrate by evaporation process. ZnS and $Na_3AlF_6$ were selected as high and low refractive index material, and additionally Cr was chosen as mid reflective layer respectively. The multi-layered thin films were prepared in terms of different optical thickness and different staking sequence and layers. The optical properties were systematically characterized with different optical thickness of $Na_3AlF_6$ especially $0.25\lambda$ and $0.5\lambda$. In order to expect the experimental result, the simulation program, the Essential Macleod Program(EMP) was adopted. Based on the results taken by spectrophotometer at viewing angle $45^{\circ}$, the ZnS/$Na_3AlF_6$/ZnS/Cr multi-layered thin film shows purple colour range in $0.25\lambda$, bluish green in $0.5\lambda$, red purple in $0.75\lambda$, and purple in $1.0\lambda$ respectively.

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Effects of different surface finishing procedures on the change in surface roughness and color of a polymer infiltrated ceramic network material

  • Ozarslan, Mehmet Mustafa;Buyukaplan, Ulviye Sbnem;Barutcigil, Cagtay;Arslan, Merve;Tuker, Nurullah;Barutcigil, Kubilay
    • The Journal of Advanced Prosthodontics
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    • v.8 no.1
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    • pp.16-20
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    • 2016
  • PURPOSE. Polymer infiltrated ceramic network (PICN) materials, also called hybrid ceramics, are new materials in dental market. The manufacturer of the PICN material VITA Enamic suggests 3 different finishing procedures for this new material. In the present study, surface roughness and color differences caused from different finishing procedures of VITA Enamic were investigated. MATERIALS AND METHODS. 120 specimens were prepared in dimensions $2{\times}10{\times}12mm$ from VITA Enamic hybrid ceramic blocks with 'high translucency' and 'translucency 2M2' shades. The specimens were divided into 8 groups. For each group, different finishing procedures suggested by the manufacturer were performed. Surface roughness values were determined by a tactile portable profilometer. Color changes were evaluated using a clinical spectrophotometer. The data were analyzed using one-way ANOVA and Tukey's post-hoc comparison. The significance level was set at ${\alpha}=0.05$. RESULTS. The roughest surfaces were observed in Glaze Groups. Their surface roughness values were similar to that of the control group. Clinical Kit and Technical Kit groups did not show a statistically significant difference regarding surface roughness (P>.05). The largest color difference regarding ${\Delta}E_{00}$ was observed in Clinical Kit finishing groups. There were also statistically significant color changes between the groups (P<.05). However, all the groups showed clinically acceptable color change (${\Delta}E_{00}$<2.25) except Clinical Kit Groups (${\Delta}E_{00}$>2.25). CONCLUSION. Within the limitations of the present study, it may be suggested that finishing the VITA Enamic restorations by Technical Kit instead of Glaze and Clinical Kit gives better clinical performance in regard to surface roughness and shade matching.