• Journal of Power System Engineering
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• 제18권6호
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• pp.106-112
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• 2014

The diesel engine, which has high compression ratio than other heat engines, has been using as the main power source of marine transport. Especially, since marine diesel engines offer better specific fuel consumption (SFC), it is environment-friendly compared to those used in other industries. However, attentio should be focused on emissions such as nitrous oxide ($N_2O$) which is generated from combustion of low-grade fuels. Because $N_2O$ in the atmosphere is very stable, the global warming potential (GWP) of $N_2O$ is 310 times as large as that of $CO_2$, and it becomes a source of secondary contamination after photo-degradation in the stratosphere. It has been hitherto noted on the $N_2O$ exhaust characteristics from stationary power plants and land transportations, but reports on $N_2O$ emission from the marine diesel engine are very limited. In this experimental study, a author investigated $N_2O$ emission characteristics by using changed diesel fuel components of nitrogen and sulfur concentration, assessed on the factors which affect $N_2O$ generation in combustion. The experimental results showed that $N_2O$ emission exhibited increasement with increasing of sulfur concentration in fuel. However, all kinds of nitrogen component additives used in experiment could not change $N_2O$ emission.

• Journal of Advanced Marine Engineering and Technology
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• 제38권9호
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• pp.1045-1050
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• 2014

$N_2O$(Nitrous Oxide) is known as the third major GHG(Green House Gas) following $CO_2$(Carbon Oxide) and $CH_4$(Methane). The GWP(Global Warming Potential) factor of $N_2O$ is 310 times as large as that of $CO_2$ because $N_2O$ in the atmosphere is very stable, and it becomes a source of secondary contamination after photo-degradation in the stratosphere. Investigation on the cause of the $N_2O$ formation have been continuously reported by several researchers on power sources with continuous combustion form, such as a boiler. However, in the diesel engine, research on $N_2O$ generation which has effected from fuel components has not been conducted. Therefore, in this research, author has investigated about $N_2O$ emission rates which was changed by nitrogen and sulfur concentration in fuel on the diesel engine. The test engine was a 4-stroke direct injection diesel engine with maximum output of 12 kW at 2600rpm, and operating condition of that was set up at a 75% load. Nitrogen and sulfur concentrations in fuel were raised by using six additives : nitrogen additives were Pyridine, Indole, Quinoline, Pyrrol and Propionitrile and sulfur additive was Di-tert-butyl-disulfide. In conclusion, diesel fuels containing nitrogen elements less than 0.5% did not affect $N_2O$ emissions in the all concentrations and kinds of the additive agent in the fuel. However, increasing of the sulfur additive in fuel increased $N_2O$ emission in exhaust gas.

• Journal of Power System Engineering
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• 제19권3호
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• pp.16-21
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• 2015

Nitrous oxide($N_2O$) concentration in the atmosphere has been constantly increased by the human activities with industrial growth after the industrial revolution. One of factors to increase $N_2O$ concentration in the atmosphere is the $N_2O$ emission caused by the combustion of marine fuel. Especially, a sulfur component included in marine fuel oils is known as increasing the $N_2O$ formation in diesel combustion. Form this point of view, $N_2O$ emission from a ship is not negligible. On the other hand, Exhaust gas recirculation(EGR) that have thermal, chemical and dilution effect is effective method for reducing the NOx emission. In this study, an author investigated $N_2O$ reduction by using EGR on a direct injection diesel engine. The test engine was a 4-stroke diesel engine with maximum output of 12 kW at 2600rpm, and operating condition of the engine was a fixed load of 75%. The experimental oil was a blend-fuel that were adjusted with sulfur ratio of 3.5%, and EGR ratio of 0%, 10%, 20% and 30%. In conclusion, diesel fuel that contained 3.5% sulfur component increased $SO_2$ emission in exhaust gas, and increment of EGR ratio reduced NO emission. Moreover, $N_2O$ emission was decreased as over 50% at EGR ratio of 10% and reduced 100% at EGR ratio of 30% compared with $N_2O$ emission of 0% EGR ratio.

• Journal of Advanced Marine Engineering and Technology
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• 제38권9호
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• pp.1051-1056
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• 2014

Nitrous oxide ($N_2O$) is naturally generated from biological activity, such as bacteria's material exchange. However, recent $N_2O$ concentration in the atmosphere has being increased by the human activities such as industrial growth. One of factors to increase $N_2O$ concentration in the atmosphere is a $N_2O$ emission caused by the combustion of marine fuel oils. The marine transportation presently handles over 99 percent of the international freight cargoes and the number of ship is continuously increasing with increment of cargoes. In this study, author conducted a series of the experimental investigations on which combustion of fuels containing different element concentrations used in a 4-stroke marine diesel engine affect $N_2O$ emissions in the exhaust gas. Moreover, it is assessed on the extent to which fuel combustion patterns in the combustion chamber affect $N_2O$ emissions.

• Journal of the Korean Society of Marine Environment & Safety
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• 제21권2호
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• pp.188-193
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• 2015

It has been generally recognized that $N_2O$(Nitrous Oxide) emission from marine diesel engines has a close correlation with $SO_2$(Sulfur Dioxide) emission, and diversity of fuel elements using ships affects characteristics of the $N_2O$ emission. According to recent reports, in case of existence of an enough large NO(Nitric Oxide) generated as fuel combustion, effect of the $SO_2$ emission in exhaust gas on the $N_2O$ formation is more vast than effect of the NO. Therefore, $N_2O$ formation due to the $SO_2$ element operates on a important factor in EGR(Exhaust Gas Recirculation) systems for NOx reduction. An aim of this experimental study is to investigate that intake gas of the diesel engine with increasing of $SO_2$ flow rate affects $N_2O$ emission in exhaust gas. A test engine using this experiment was a 4-stroke direct injection diesel engine with maximum output of 12 kW at 2600rpm, and operating condition was set up at a 75% load. A standard $SO_2$ gas with 0.499%($m^3/m^3$) was used for changing of $SO_2$ concentration in intake gas. In conclusion, the diesel fuel included out sulfur elements did mot emit the $SO_2$ emission, and the $SO_2$ emission in exhaust gas according as increment of the $SO_2$ standard gas had almost the same ratio compared with $SO_2$ rate in mixture inlet gas. Furthermore, the $N_2O$ element in exhaust gas was formed as $SO_2$ mixture in intake gas because increment of $SO_2$ flow rate in intake gas increased $N_2O$ emission. Hence, diesel fuels included sulfur compounds were combined into $SO_2$ in combustion, and $N_2O$ in exhaust gas should be generated to react with NO and $SO_2$ which exist in a combustion chamber.

• Journal of the Korean Society of Manufacturing Process Engineers
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• 제12권1호
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• pp.43-51
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• 2013

This is a thesis about the experiment of comparison characteristic of power and exhaust gas in the same condition between diesel engine that is equipped turbocharger different from response power to increase effectiveness of the engine which is recently used in a lot of industry which requires high power. Resulting of the experiment with natural aspiration diesel engine and turbocharger diesel engine, difference in low speed is not significant, but in high speed, effectiveness of turbocharger diesel engine is much higher than the other one. In other hand, in exhaust gas experiment, turbocharger model exhausts more $NO_X$ and $O_2$, but it doesn't significantly affect the result when it comes with decreasing of $CO_2$ and effectiveness of increased power characteristic. As a result, the turbocharger diesel engine is economically effective comparing with the natural aspiration diesel engine.

• Journal of the Korean Society of Manufacturing Process Engineers
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• 제11권6호
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• pp.100-106
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• 2012

This is a thesis about the experiment of comparison characteristic of power and exhaust gas in the same condition between diesel engine that is equipped turbocharger to increase effectiveness of the engine which is recently used in a lot of industry which requires high power. Resulting of the experiment with natural aspiration diesel engine and turbocharger diesel engine, difference in low speed is not significant, but in high speed, effectiveness of turbocharger diesel engine is much higher than the other one. In other hand, in exhaust gas experiment, turbocharger model exhausts more NOX and $O_2$, but it doesn't significantly affect the result when it comes with decreasing of $CO_2$ and effectiveness of increased power characteristic. As a result, the turbocharger diesel engine is economically effective comparing with the natural aspiration diesel engine.

• Journal of Advanced Marine Engineering and Technology
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• 제23권4호
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• pp.543-551
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• 1999

Diesel engine is a major source of the air pollution. In general the concentrations of these pollu-tants in diesel engine exhaust differ from values calculated assuming chemical equibrium. Thus the detailed chemical mechanisms by which these pollutions form and the kinetic of these process-es are important in determining emission levels. In this study the computer program has been developed to calculate the required thermodynam-ic properties of combustion products(10 spacies) for both equilibrium and non-equilibrium in cylin-der for diesel engines. Nitric oxide emissions are calculated by using the extended Zeldovich Kinet-ic mechanism with a steady state assumption for the N concentration and equilibrium values used for H, O, $O_2$ and OH concentrations. By the results it is confirmed that developed simulations program with the NO prediction model is validated against residual mass fraction combustion index of Wiebe's functions pre-mixed com-bustion ration fuel injection timing.

• Journal of Korean Society for Atmospheric Environment
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• 제28권2호
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• pp.203-210
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• 2012

The purpose of this study is to evaluate the diesel retrofit program which have been proceeded for the last 7 years in Gyeonggi-do. Diesel retrofit programs in Gyeonggi-do consist of the attachment of DPF (Diesel Particulate Filter), p-DPF (partial-DPF) and DOC (Diesel Oxidation Catalyst), switching to LPG engine, scraping an old cars. Emission reduction by diesel retrofit program was estimated $N_2O$ 8,313.4 ton/year, PM10 3,626.4 ton/year, VOC 8,078.5 ton/year in 2010. The benefit-cost analysis shows that the 964 billion wons of benefits are greater than the 853 billion wons of total costs. Diesel retrofit programs could be one of the most effective measures to improve PM10 concentration in metropolitan area. But retrofit programs also need to be properly maintained by each vehicle.

• Transactions of the Korean Society of Automotive Engineers
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• 제5권4호
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• pp.93-99
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• 1997

The re quest to develop the engines that are able to run without air or with very little oxygen condition is raised with the interest of ocean science or the mines. This research had already be gun before the world war II, but had been stagnant owing to the appearance of nuclear power. Recycle diesel engines have ability to run under the above mentioned condition the recycle diesel engine recirculates exhaust gases into intake port and consumes additional oxygen supplied by oxygen tank. Carbon dioxide is controlled by the absorber. The combustion and emission characteristics of recycle diesel engines are quite different with conventional one because the working fluids of recycle diesel engines consist of Ar, $CO_2$ and $O_2$ as well as $N_2$. Recycle diesel engine is therefore different with general diesel engine from the viewpoint of intake air composition. It is required to investigate the effect of intake composition in the combustion and emission to know recycle diesel engine. In this study, NOx concentration, smoke and cylinder pressure are measured with the variation of Ar and $CO_2$ Reduces show that the addition of Ar reduces NOx but increases smoke. Otherwise $CO_2$ reduces smoke and NOX simultaneously. Only $CO_2$ increases the ignition delay and both gases increase fuel consumption Ar addition is superior to $CO_2$ addition for the performance of recycle diesel engine system but $CO_2$ has the avantage with respect to emission.