• Title/Summary/Keyword: Dielectric relaxation phenomena

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A Study on Displacement Current DMPC Monolayer (DMPC 단분자막의 변위전류 특성 연구)

  • Choi, Yong-Sung;Cho, Jang-Hoon;Song, Jin-Won;Lee, Kyung-Sup
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2006.11a
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    • pp.168-169
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    • 2006
  • The physical properties of DMPC monolayer were made for dielectric relaxation phenomena by the detection of the surface pressures and displacements current. The phospolipid monolayer of dielectric relaxation takes a little time and depend on the molecular area.

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Dielectric Relaxation Properties of Organic Ultra Thin Films for Nanotechnology (나노기술을 위한 유기초박막의 유전완화특성)

  • Cho, Su-Young;Song, Jin-Won;Lee, Kyung-Sup
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2004.05c
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    • pp.9-13
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    • 2004
  • In this paper, evaluation of physical properties about dielectric relaxation phenomena by the detection of the surface pressures and displacements current on the monolayer films of phospolipid monomolecular DLPC, DMPC using pressure stimulus. As a result, the changed surface pressure, displacement current and the transition forms of dipole moment of phospolipid monomolecular in area per molecular by pressure stimulus were conformed well. It was known that the monolayers by linear relationship for decision of dielectric relaxation time between compressure speed and molecule area By according to the linear relationship relation get that frictional constant, DLPC was $1.89{\times}10^{-19}$[Js] and DMPC was $0.722{\times}10^{-19}$[Js]. It is found that the phospolipid monolayer of dielectric relaxation takes a little time and depend on the molecular area.

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A study on the Dielectric Relaxation Phenomena of phospolipid monolayers Film (인지질 단분자막의 유전완화현상에 관한 연구)

  • Cho, Su-Young;Lee, Kyung-Sup
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.11a
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    • pp.431-434
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    • 2003
  • In this paper, We introduced that the method for deforming the dielectric relaxation time $\tau$ of floating monolayers on water interface. Displacement current flowing across monolayer is analyzed using a rod-like molecular model. It is revealed that the dielectric relaxation time $\tau$ of monolayers in the isotropic polar orientational phase is determined using a linear relashionship between the monolayer compression speed a and the molecular area $A_m$. A displacement current gives a peak at A=$A_m$. The dielectric relaxation time $\tau$ of phospolipid monolayers was examined on the basis of the analysis developed here.

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A Study on Displacement Current Characteristics of DMPC Monolayer (II) (DMPC 인지질 단분자막의 변위전류 특성 연구 (II))

  • Song, Jin-Won;Lee, Kyung-Sup;Choi, Yong-Sung
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.56 no.2
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    • pp.343-348
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    • 2007
  • The physical properties of DMPC monolayer were made for dielectric relaxation phenomena by the detection of the surface pressures and displacements current. Lipid thin films were deposited by accumulation and the current was measured after the electric bias across the manufactured MIM device. It is found that the phospolipid monolayer of dielectric relaxation takes a little time and depend on the molecular area. When electric bias is applied across the manufactured MIM device by the deposition condition of phospolipid mono-layer, it wasn't breakdown when the higher electric field to impress by increase of deposition layers.

Dielectric Relaxation Phenomena of DMPC LB Thin Film (DMPC LB박막의 유전완화현상)

  • Choi, Youbg-Il;Song, Jin-Won;Cho, Su-Young;Lee, Kyung-Sup
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.07b
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    • pp.822-825
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    • 2003
  • Maxwell displacement current (MDC) measurement has been employed to study the dielectric property of Langmuir-films. A method for determining the dielectric relaxation time $\tau$ of floating monolayers on water surface is presented. WC flowing across monolayers is analyzed using a rod-like molecular model. It is revealed that the dielectric relaxation time $\tau$ of monolayers in the isotropic polar orientational phase is determined using a liner relationship between the monolayer compression speed ${\alpha}$ and the molecular area Am. Compression speed ${\alpha}$ was about 30, 40, 50mm/min.

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Dielectric Relaxation Characteristics of Phospholipid Membrane (인지질막의 유전완화 특성)

  • 이경섭;조수영;박석순;정헌상;최영일
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1998.06a
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    • pp.173-176
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    • 1998
  • We experimentally investigated the dielectric relaxation phenomena of a liquid crystal monolayers by the Displacement current techique and displacement current flowing across monolayers is analyzed using rod-like molecular model. It is revealed that the dielectric reaxation time $\tau$ of monolaters in the isotropic polar orientational phase is determined using a linear relashionship between the monolayers compression speed $\alpha$ and the molecular area. The dielectric relaxation time of phospholipid monolayers was examined on the basis of the analysis developed here.

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A Comparison of the Dielectric Behavior of Aromatic and Aliphatic Polyurethanes in Relation to Transitional Phenomena

  • Kim, Chy Hyung
    • Transactions on Electrical and Electronic Materials
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    • v.18 no.4
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    • pp.211-216
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    • 2017
  • The dielectric properties of two polyurethanes (PUs) with different hard segments, i.e., aromatic methylene di-p-phenyl diisocyanate (MDI) and aliphatic hexamethylene diisocyanate (HDI), were investigated in the temperature range of -100 to $100^{\circ}C$ and in the frequency range of 1 Hz to 3 kHz. The ${\alpha}$-relaxations induced by the glass transition of the equivalent soft segments in the two PUs occurred at relaxation times of ${\tau}=3.46{\times}10^{-3}s$ for MDI-PU and ${\tau}=3.39{\times}10^{-2}s$ for HDI-PU at $-20^{\circ}C$, in accord with the temperature-frequency superposition principle, resulting in similar shifting factors. However, different I-relaxations were observed for the two PUs. The I-relaxation of MDI-PU occurred due to the mobility of the chain extenders near $80^{\circ}C$ with a slower shifting rate than the ${\alpha}$-relaxation. On the other hand, I-relaxation arising from both the extender and the unconstrained hard segments of HDI-PU occurred at $70{\sim}100^{\circ}C$, indicating complicated dielectric behavior due to partial interaction with the ${\alpha}$-relaxation at high frequencies. Thus, the I-relaxation of HDI-PU did not follow the superposition principle. The dielectric behaviors of the PUs were mainly influenced by their phase transitions, which were affected by the structure and components of the materials.

Effects of Sr/Ca Ratio of SCT thin film by RF Sputtering Method (RF 스퍼터링법에 의한 SCT 박막의 Sr/Ca 비율 영향)

  • Kim, Jin-Sa;Oh, Yong-Cheul
    • Journal of the Semiconductor & Display Technology
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    • v.5 no.4 s.17
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    • pp.5-9
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    • 2006
  • The SCT thin films are deposited on Pt-coated electrode($Pt/TiN/SiO_2/Si$) using RF sputtering method with Sr/Ca ratio. The maximum grain of thin films is obtained by ratio of Ca at 15 mol%. The dielectric constant was increased with increasing the ratio of Ca, while it was decreased if the ratio of Ca exceeded over 15 mol%. The dielectric constant changes almost linearly in temperature ranges of $-80{\sim}+90$. All SCT thin films used in this study show the phenomena of dielectric relaxation with the increase of frequency, and the relaxation frequency is observed above 200 kHz. The current-voltage characteristics of SCT thin films showed the increasing leakage current as the measuring temperature increases.

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Dielectric Relaxation Time for Alkyl Chain of Phospolipid Organic Monolayers Film (인지질 유기단분자막의 알킬체인에 의한 유전완화시간)

  • Song, Jin-Won;Cho, Su-Young;Kim, Young-Keun;Lee, Kyung-Sup
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2004.04b
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    • pp.111-115
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    • 2004
  • In this paper, evaluation of physical properties about dielectric relaxation phenomena by the detection of the surface pressures and displacements current on the monolayer films of phospolipid monomolecular DLPC, DMPC using pressure stimulus. As a result, the changed surface pressure, displacement current and the transition forms of dipole moment of phospolipid monomolecular in area per molecular by pressure stimulus were conformed well. It was known that the monolayers by linear relationship for decision of dielectric relaxation time between compressure speed $\alpha$ and molecule area $A_m$ By according to the linear relationship relation get that frictional constant $\xi$, DLPC was $1.89{\times}10^{-19}$[Js] and DMPC was $0.722{\times}10^{-19}$[Js]. It is found that the phospolipid monolayer of dielectric relaxation takes a little time and depend on the molecular area.

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Relaxation and Freezing in Pb-based Relaxer Ferroelectrics (Pb계 완화형 강유전체에서의 relaxation 및 freezing거동)

  • 박재환;김윤호;박재관
    • Korean Journal of Crystallography
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    • v.12 no.3
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    • pp.157-161
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    • 2001
  • The observe relaxation phenomena and freezing behavior in Pb(Mg/sub ⅓/Nb/sub ⅔/O₃, relaxor ferroelectrics, weak electric-field properties as well as strong electric-field properties were investigated. The temperature dependence of the dielectric properties obtained using the low electric-field of 1 V/w was investigated. The dielectric properties obtained from the slope of the dielectric hysteresis loop and the temperature dependence of the pyroelectric properties were also investigated. When fitting all the experimental data with the Vogel-Filcher relation, a close agreement between the experimental data and equation was observed. The freezing temperature could be consistently calculated by the various methods.

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