• 제목/요약/키워드: Dicationic Salts

검색결과 2건 처리시간 0.017초

Synthesis and Applications of Dicationic Iodide Materials for Dye-Sensitized Solar Cells

  • Nam, Heejin;Ko, Yohan;Kunnan, Sakeerali C.;Choi, Nam-Soon;Jun, Yongseok
    • Journal of Electrochemical Science and Technology
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    • 제10권2호
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    • pp.214-222
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    • 2019
  • Dye-sensitized solar cells (DSSCs) have been receiving growing attentions as a potential alternative to order photovoltaic devices due to their high efficiency and low manufacturing cost. DSSCs are composed of a photosensitizing dye adsorbed on a mesoporous film of nanocrystalline $TiO_2$ as a photoelectrode, an electrolyte containing triiodide/iodide redox couple, and a platinized counter electrode. To improve photovoltaic properties of DSSCs, new dicationic salts based on ionic liquids were synthesized. Quite comparable efficiencies were obtained from electrolytes with new dicationic iodide salts. The best cell performance of 7.96% was obtained with dicationic salt of PBDMIDI.

Long Chain Dicationic Phase Transfer Catalysts in the Condensation Reactions of Aromatic Aldehydes in Water Under Ultrasonic Effect

  • Esen, Ilker;Yolacan, Cigdem;Aydogan, Feray
    • Bulletin of the Korean Chemical Society
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    • 제31권8호
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    • pp.2289-2292
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    • 2010
  • Long chain dicationic ammonium salts were used successfully as phase transfer catalyst in the condensation reactions of aromatic aldehydes in water under ultrasonic irradiation for the first time. The quaternary salt having longer distance between the cation centers was more effective than the mono- and dicationic ones having short chain.