• Title/Summary/Keyword: Diammonium phosphate

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Influence of Various Sources of Non-Protein Nitrogenous Sources on In vitro Fermentation Patterns of Rumen Microbes

  • Ali, C.S.;Khaliq, T.;Sarwar, M.
    • Asian-Australasian Journal of Animal Sciences
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    • v.10 no.4
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    • pp.357-363
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    • 1997
  • The effect of replacement of cotton seed meal (CSM), with various levels and sources of non-protein nitrogenous (NPN), substances on in vitro ruminal fermentation were studied. Cotton seed meal, in control ration provided nitrogen equivalent to 12.5 percent crude protein while in experimental ration was replaced at 30, 50 & 70 percent levels with urea, diammonium phosphate (DAP) and biuret, respectively. The results of incubation upto 48 hours indicated an improvement in digestibility by replacement of CSM with urea and biuret upto 50 percent protein equivalent, but not with DAP. Bacterial count from cultures containing 50% nitrogen from biuret was significantly higher than DAP, urea and CSM. Various sources of nitrogen produced $NH_3-N$ in increasing order of CSM, biuret, DAP and urea. Increasing levels of NPN resulted in progressive increase in the levels of $NH_3-N$. The levels of various NPN sources had no effect on pH. However, the pH values determined for urea and CSM were higher than biuret and DAP.

Combustive Characteristics of Pinus Rigida Treated with Ammonium Salts (암모늄염으로 처리된 리기다 소나무의 연소특성)

  • Chung, Yeong-Jin;Jin, Eui
    • Fire Science and Engineering
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    • v.24 no.5
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    • pp.115-121
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    • 2010
  • This study was performed to test the combustive properties of Pinus rigida-based materials by the treatment of ammonium salts. Pinus rigida plate was soaked in three 20 wt% ammonium salt solutions such as ammonium sulfate (AMSF), monoammonium phosphate (MAPP), and diammonium phosphate (DAPP), respectively, at the room temperature. After drying specimen treated with chemicals, combustive properties were examined by the cone calorimeter (ISO 5660-1). Comparing with virgin pinus rigida plate, specimens treated with the ammonium salts had lower combustive properties and It is supposed that the combustion-retardation properties improved due to the treated ammonium salts in the virgin Pinus rigida. Also, the specimens with treated ammonium salts showed both the lower peak heat release rate (PHRR) and lower total heat release (THR) than those of virgin plate.

Combustion Characteristics of Fire Retardants Treated Domestic Wood (난연처리 국산 침엽수재의 연소특성 분석)

  • Seo, Hyun Jeong;Hwang, Wuk;Lee, Min Chul
    • Journal of the Korean Society of Combustion
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    • v.22 no.2
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    • pp.9-18
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    • 2017
  • In this study, we measured that fire characteristics of four wood species using indoor finish materials. Wooden specimens were treated with fire retardant chemicals such as diammonium phosphate and potassium carbonate. The wooden specimens are Larix kaempferi, Pinus koraiensis, Cryptomeria japonica, and Chamaecyparis obtusa, which are used for indoor finish. The heat release rate (HRR) values of fire retardant treated woods were confirmed lower than that of untreated woods. For specific details, the HRR values of vacuum impregnated specimens for Pinus koraiensis and Cryptomeria japonica were measured lower than coatings. However, those of Larix kaempferi and Chamaecyparis obtusa showed the opposite effect to it. Total heat release rate values of all wooden specimens, vacuum impregnated were lower than coated specimens.

Effects of Treatment Methods of Fire-retardant and Layup of Treated Veneers on the Performances of Plywoods (내화약제(耐火藥劑)의 처리방법(處理方法) 및 처리단판(處理單板)의 조판형태(調板形態)가 합판(슴板)의 성능(性能)에 미치는 영향(影響))

  • Son, Jung-Il;Cho, Jae-Sung;Suh, Jin-Suk
    • Journal of the Korean Wood Science and Technology
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    • v.27 no.3
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    • pp.39-50
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    • 1999
  • This research was carried out to investigate the development of fire-retardancy treatment technology and performance evaluation of fire-retardant treated plywoods. Radiata pine, keruing, dillenia, calophyllum and terminalia veneers were treated by normal(conventional) pressure soak(NPS) and vacuum-pressure-soak(VPS) using 20% water solution of diammonium phosphate. Then, 4.8mm thick, 3ply plywoods were fabricated with combination of fire-retardant treated, untreated or water-immersion types and several composition types of radiata pine and keruing veneers, i,e. the uniform and the mixed types in species composition, and the homogenious and the alternate layer types in veneer treatment. In composed species, the retention and the treatment effects of fire-retardant chemicals III radiata pine was still greater than those of keruing. The effect of VPS treatment was larger than that of NPS treatment, however, adhesive bonding strength and bending strength of plywoods treated by these two methods were not necessarily lowered, compared to those of untreated plywood. And also, fire endurance performance of the urea melamine resin-bonded plywood was greater than that of the phenol resin-bonded plywood. In result, the appropriate combination in veneer species and layer as well as alternate fire-retardant treatments would be more efficiently available in service.

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Study on pH Reducing Method of Recycled Fine Aggregate for Embanking or Covering (성복토용 순환잔골재의 pH 저감방법에 관한 연구)

  • Han, Min-Cheol;Han, Dongyeop
    • Journal of the Korea Institute of Building Construction
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    • v.17 no.1
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    • pp.23-30
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    • 2017
  • The aim of the research is to suggest an economical and sustainable method of reducing pH of recycled aggregate as an embanking and a covering materials. Because of the unhydrated cement based materials on the surface of the recycled aggregate, it causes a severe problem on environment with leaked high alkali water from embankment and covering by using recycled aggregate. In this research, to reduce the pH of recycled aggregate, regarding the recycled fine aggregate, eight different methods were tested and analyzed with three different categorized: natural treatment, artificial treatment, and chemical treatment. From the results of experiment, it was considered that the most efficient method of reducing pH of recycled aggregate was the chemical treatment using acid such as $CO_2$ acceleration or monoammonium phosphate (MAP), and diammonium phosphate (DAP). Especially, using MAP and DAP, fertilizers, is the most efficient method of reducing pH with its time duration and performance.

Nanostructured Hydroxyapatite for Biomedical Applications: From Powder to Bioceramic

  • Eslami, Hossein;Tahriri, Mohammadreza;Moztarzadeh, Fathollah;Bader, Rizwan;Tayebi, Lobat
    • Journal of the Korean Ceramic Society
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    • v.55 no.6
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    • pp.597-607
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    • 2018
  • In this study, a wet chemical method was used to synthesize nanostructured hydroxyapatite for biomedical applications. Diammonium hydrogen phosphate and calcium nitrate 4-hydrate were used as starting materials with a sodium hydroxide solution as an agent for pH adjustment. Scanning electron microscopy, transmission electron microscopy, Fourier-transform infrared spectroscopy, differential thermal analysis, thermal gravimetric analysis, atomic absorption spectroscopy, and ethylenediaminetetraacetic acid (EDTA) titration analysis were used to characterize the synthesized powders. Having been uniaxially pressed, the powders formed a disk-like shape. The sinterability and electrical properties of the samples were examined, and the three-point bending test allowed for the measurement of their mechanical properties. Sedimentation analysis was used to analyze the slurry ability of hydroxyapatite. As in-vitro biological properties of the samples, biocompatibility and cytotoxicity were assessed using osteoblast-like cells and the L929 cell line, respectively. Solubility was assessed by employing a simulated body fluid.

Fire Retardancy and Mechanical Properties of Paper Sludge-Wood Particle Mixed Board (제지 슬러지-목재 파티클 혼합보드의 내화성과 기계적 성질)

  • Son, Jung-Il;Lee, Phil-Woo
    • Journal of the Korean Wood Science and Technology
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    • v.22 no.1
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    • pp.54-65
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    • 1994
  • This research carried out to investigate the effects of inorganic materials in paper sludge on the thermal degradation and of paper sludge addition on physical and mechanical properties of paper sludge-wood particle mixed boards in comparison with unmodified particleboards. Also these unmodified particleboards and paper sludge-wood particle mixed boards were soaked in aqueous solutions of fire-retardant chemicals(diammonium phosphate and zinc chloride), and their fire retardancy were tested by oxygen index method and ISO ignition test to determine the feasibility of paper sludge, industrial waste, as a recyclable resource in fabrication of fire-resisting panels for building material. Since the redrying of fire-retardant treated particleboards and paper sludge-wood particle mixed boards were made by press drying method, this process was a simple and effective method. On the other hand, flexural bending strength and internal bonding strength were also analysed to evaluate mechanical properties through standard method.

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Effect of Fertilizers and Neem Cake Amendment in Soil on Spore Germination of Arthrobotrys dactyloides

  • Kumar, D.;Singh, K.P.;Jaiswal, R.K.
    • Mycobiology
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    • v.33 no.4
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    • pp.194-199
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    • 2005
  • Application of fertilizers such as urea, diammonium phosphate (DAP) and muriate of potash in soil adversely affected the spore germination of Arthrobotrys dactyloides. Amendment of soil with urea at the concentrations of 1.0%, 0.5% and 0.1 % completely inhibited spore germination and direct trap formation on the conidium, whereas muriate of potash delayed and reduced the spore germination even at the lowest concentration. DAP also inhibited spore germination at 1.0% concentration, while at lower concentration the percentage of spore germination was reduced. Application of neem cake at the concentration of 0.5% also inhibited spore germination after 24 h of amendment. The inhibitory effect of neem cake was reduced after 15 days of amendment, while after 30 days after amendment the inhibitory effect was completely lost and the spore germinated by direct trap as in unamended soil. Nematodes were not attracted to ungerminated spores after 24 h of amendment. After 15 days of amendment nematodes were attracted to agar blocks containing fewer germinated spores after 24 h of incubation but after 48 h of incubation large number of nematodes were attracted and trapped by the germinated spores with direct traps. After 30 days of amendment, larger number of nematodes were attracted and trapped by direct traps.

Electrochemical and Thermal Property Enhancement of Natural Graphite Electrodes via a Phosphorus and Nitrogen Incorporating Surface Treatment

  • Kim, Kyungbae;Kim, Han-Seul;Seo, Hyungeun;Kim, Jae-Hun
    • Corrosion Science and Technology
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    • v.19 no.1
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    • pp.31-36
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    • 2020
  • An efficient wet process approach to modifying natural graphite (NG) electrodes for Li-ion batteries is introduced in this paper. With homogeneous mixing and thermal decomposition of NG with diammonium phosphate ((NH4)2HPO4), phosphorus and nitrogen were successfully incorporated into the surface layer of NG particles. Electron microscopy and X-ray photoelectron spectroscopy analyses demonstrated that the surface was well modified by this process. As a result, the treated NG electrodes exhibited much improved electrochemical performance over pristine NG at two different temperatures: 25 ℃ and 50 ℃. Excellent capacity retention of 95.6% was obtained after 100 cycles at 50 ℃. These enhanced properties were confirmed in a morphology analysis on the cross-sections of the NG electrodes after galvanostatic cycling. The improved cycle and thermal stabilities can be attributed to the surface treatment with phosphorus and nitrogen; the treatment formed a stable solid electrolyte interphase layer that performed well when undergoing Li insertion and extraction cycling.

AUTOMATION OF QUANTITATIVE SAFETY EVALUATION IN CHEMICAL PROCESSES

  • Lee, Byung-Woo;Kang, Byoung-Gwan;Suh, Jung-Chul;Yoon, En-Sup
    • Proceedings of the Korea Institute of Fire Science and Engineering Conference
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    • 1997.11a
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    • pp.252-259
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    • 1997
  • A method to automate hazard analysis of chemical plants is proposed in this paper. The proposed system is composed of three knowledge bases - unit knowledge base, organizational knowledge base and material knowledge base, and three hazard analysis algorithms - deviation, malfunction and accident analysis algorithm. Hazard analysis inference procedure is developed based on the actual hazard analysis procedures and accident development sequence. The proposed algorithm can perform hazard analysis in two methods and represent all conceivable types of accidents using accident analysis algorithm. In addition, it provides intermediate steps in the accident propagation, and enables the analysis result to give a useful information to hazard assessment. The proposed method is successfully demonstrated by being applied to diammonium phosphate manufacturing process. A system to automate hazard analysis is developed by using the suggested method. The developed system is expected to be useful in finding the propagation path of a fault or the cause of a malfunction as it is capable to approach causes of faults and malfunctions simultaneously.

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