• Fisheries and Aquatic Sciences
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• 제2권1호
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• pp.1-7
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• 1999

Antioxidant activity of a methanol extract of Symphyocladia latiuscula was evaluated by the thiocyanate method in the linoleic acid system. The methanol extract inhibited the peroxidation of linoleic acid in a dose-dependent manner. The MeOH extract was then sequentially partitioned with n-hexane, $CH_2Cl_2$, EtOAc, n-BuOH and H20. The antioxidant activity of the fractions increased in order of $CH_2Cl_2$, n-hexane, EtOAc, and n-BuOH. There was no activity found in $H_2O$ partitoned fraction by the thiocyanate method. Especially, the activities of the fractions of n-hexane and $CH_2Cl_2$ were comparable to that of 2,6-di-tert­butylhydroxytoluene (BHT). Column chromatography of the $CH_2Cl_2$ fraction over silica gel yielded cholesterol (1) and 2,3,6-tribromo 4,5-dihydroxybenzyl methyl ether (2) which were identified by instrumental analysis of MS and $^1H-$ and $^{13}C-NMR$. The latter (2) demonstrated significant antioxidant activity.

• 한국수소및신에너지학회논문집
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• 제31권1호
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• pp.89-95
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• 2020

The main scope of this paper is to see if the conventional pump can be properly used for a specific fuel, Di-methyl Ether (DME) despite of its low lubricity and high reactivity in the experimental conditions. A wobble plate type fuel pump was connected to the common rail to verify that the pump could deliver the fuel at the required pressure and resultantly DME could be used as fuel without modifying the original pump. At each required pressure (30 Mpa, 35 Mpa, 40 Mpa, 45 Mpa, and 50 Mpa), the pump met the pressure required by the common rail. In addition, pump performance experiments tended to follow the usual performance curve while the flow rate decreased as the pressure increased. The maximum flow rate of the pump was 470 kg/h at 30 Mpa and all measurements were taken with keeping DME temperature below 60℃.

• 한국자동차공학회논문집
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• 제14권6호
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• pp.9-16
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• 2006

Variable valve timing is one of the attractive ways to control homogeneous charge compression ignition (HCCI) engine. Hot internal residual gas which can be controlled by variable valve timing(VVT) device, makes fuel evaporated easily, and ignition timing advanced. Regular gasoline was used as main fuel and di-methyl ether(DME) was used as ignition promoter in this research. HCCI engine operating range is limited by high combustion peak pressure and engine noise. High combustion pressure can damage the engine during operation. To avoid engine damage, the rich limits have to define using various methods. Peak combustion pressure, rate of cylinder pressure rise was considered to determine rich limit of engine operating range. Knock probability was correlated with the rate of cylinder pressure rise as well as the peak combustion pressure.

• 대한기계학회논문집B
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• 제31권8호
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• pp.672-679
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• 2007

The combustion characteristics of a liquefied petroleum gas-di-methyl ether (LPG-DME) compression ignition engine was investigated under homogeneous charge and stratified charge conditions. LPG was used as the main fuel and injected into the combustion chamber directly. DME was used as an ignition promoter and injected into the intake port. Different LPG injection timings were tested to verify the combustion characteristics of the LPG-DME compression ignition engine. The combustion was divided into three region which are homogeneous charge, stratified charge, and diffusion flame region according to the injection timing of LPG. The hydrocarbon emission of stratified charge combustion was lower than that of homogeneous charge combustion. However, the carbon monoxide and nitrogen oxide emission of stratified charge combustion were slightly higher than those of the homogeneous charge region. The indicated mean effective pressure was reduced at stratified charge region, while it was almost same level as the homogeneous charge combustion region at diffusion combustion region. The start of combustion timing of the stratified charge combustion and diffusion combustion region were advanced compared to the homogeneous charge combustion. It attributed to the higher cetane number and mixture temperature distribution which locally stratified. However, the knock intensity was varied as the homogeneity of charge was increased.

• 한국자동차공학회논문집
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• 제16권1호
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• pp.78-85
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• 2008

The exhaust emission characteristics of a liquefied petroleum gas-di-methyl ether (LPG-DME) compression ignition engine was investigated under homogeneous charge, stratified charge and diffusion combustion conditions. LPG was used as the main fuel and injected into the combustion chamber directly. DME was used as an ignition promoter and injected into the intake port. Different LPG injection timings were tested to verify the combustion characteristics of the LPG-DME compression ignition engine. The combustion was divided into three region which are homogeneous charge, stratified charge, and diffusion combustion region according to the injection timing of LPG. The HC emission was reduced with LPG stratification. However, the carbon monoxide and particulate matter emissions were increased. The ignition timing was advanced with LPG stratification. This advance combustion was because of charge temperature and cetane number stratification with LPG.

• 대한기계학회논문집B
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• 제32권11호
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• pp.841-848
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• 2008

DME(Di-methyl Ether) has been expected to be one of the promising alternative fuels for compression ignition engines due to its low emission characteristics for particulate matter. However, its physical properties such as density, bulk modulus and viscosity are not comparable to those of conventional diesel fuel. Especially, problems caused by low lubricity and high compressibility need to be understood more thoroughly, when a DME fuel is used for compression ignition engine, especially with mechanical fuel supply system. In this study, measurement and calculation of DME's bulk modulus were carried out over the range of temperatures from $-3^{\circ}C$ to $53^{\circ}C$, and pressures from 50 bar to 250 bar using an experimental apparatus built in this work. The results show that DME is prone to be compressed more easily compared to diesel fuel. A comparison of bulk modulus with butane and propane were also made in this work.

• 한국분무공학회지
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• 제18권1호
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• pp.55-60
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• 2013

In this study, injection flow rates and material of the solenoid sealing of the injectors were improved for the development of a di-methyl Ether(DME) common-rail system. To deliver the same amount of energy provided by injection pressure of diesel $P_{inj}$ = 160 MPa, the DME injectors need to have larger diameter of nozzle hole and more No. of hole at low injection pressure of $P_{inj}$ = 40~50 MPa. The simplified nozzle flow model, which takes account of nozzle geometry and injection condition, was employed in order to design the concept of a injector nozzle such as No. of hole, diameter of hole and diameter of needle seat, etc. Injection amount and rate were tested by diesel and DME test stand. As a result, the diameter of nozzle hole were enlarged by 0.25 mm. The diameter of the orifice in the high pressure line was increased by 1.0 mm to maintain hydraulic force in the nozzle. The material of the solenoid sealing was changed to HNBR, which was strong against the corrosive. Experimental results showed that the injection amount of the DME injector drastically increased by 191.9% comparison to that of diesel at $P_{inj}$ = 40 MPa.

• 한국가스학회지
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• 제13권6호
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• pp.21-28
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• 2009

본 연구의 목적은 온도 성층화와 농도 성층화의 효과가 HCCI 연소에서 압력상승률 저감과 배기가스에 어떤 영향을 미치는지 알아보는 것이다. 2단계 열발생이 생기는 디메틸에테르(Di-Methyl Ether, DME) 연료를 사용하였다. 수치계산은 멀티 존 모델과 상세 화학 반응 스킴을 이용하였다. 수치계산 결과, 온도 성층화와 농도 성층화는 연소기간을 길게 하여 압력상승률을 저감시키는 것을 확인하였다. 그러나 농도 성층화의 폭이 너무 커지면 오히려 일산화탄소와 질소산화물이 증가하였으며, 연소 효율은 감소하였다.

• Natural Product Sciences
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• 제6권4호
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• pp.193-198
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• 2000

Phytochemical study of the constitutive polyphenolics of the flower aqueous alcohol extract of Tamarix tetragyna was carried out. The new sulphated flavonol, quercetin 3',4'-dimethyl ether $3-O-KSO_3$ as well as the new natural galloyl glucose, $2-O-galloyl-({\alpha}/{\beta})-^4C_1-glucopyranose$ were isolated and characterized. The known sulphated flavonols, kaempferol 7,4-dimethyl ether $3,5-di-O-KSO_3$, quercetin 7-methyl ether $3,3',4'-tri-O-KSO_3$, quercetin 7,4'-dimethyl ether $3-O-KSO_3$ and quercetin $3-O-KSO_3$ and the known sulphated phenolics, isoferulic acid $3-O-KSO_3$ and ellagic acid 4,4'-dimethyl ether $3-O-KSO_3$ were also separated and identified. The structures were established by conventional methods of analysis and confirmed by $^1H-,\;^{13}C-NMR$ and negative ESI-mass spectrometry. 2D-homonuclear chemical shift correlation NMR experiment was applied for the new natural galloylglucose.

• 한국연소학회:학술대회논문집
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• 한국연소학회 2012년도 제45회 KOSCO SYMPOSIUM 초록집
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• pp.305-307
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• 2012

This study was computationally explored how the fuel autoignition reactivity was affected by operating parameters such as fuel, pressure, intake temperatures, engine speed and EGR compositions for HCCI combustion. This is done for DME and CHEMKIN-PRO was used as a solver. At first, influence of the operating parameters and EGR compositions were showed. And then, in order to clarify the mechanism of them on autoignition reactivity, data-sets of kinetic were analyzed to investigate the elementary reaction path for heat release at transient tempeatures by using contribution matrix.