• Bulletin of the Korean Chemical Society
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• 제27권6호
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• pp.875-880
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• 2006

A new, simple and fast flow injection analysis (FIA) method has been developed for the indirect determination of nitrite. The proposed indirect automatic method is based on the oxidation of nitrite to nitrate using a lead(IV) dioxide oxidant microcolumn where the flow of the sample through the microcolumn reduces the $PbO_2$ solid phase reagent to Pb(II), which is measured by flame atomic absorption spectrometry. The absorbance of Pb(II) are proportional to the concentration of nitrite in the samples. The calibration curve was linear up to 30 mg $L ^{-1}$, with a detection limit of 0.11 mg $L ^{-1}$ for a 400 mL injected sample volume and a sampling rate of about 80 $h ^{-1}$. The results exhibit no interference from the presence of large amounts of ions. The developed procedure was found to be suitable for the determination of nitrite in foodstuffs and wastewaters. A relative standard deviation better than 0.9% was obtained in a repeatability study. The reliability of the method was established by parallel determination against the standard method.

• Near Infrared Analysis
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• 제1권1호
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• pp.31-35
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• 2000

Near-infrared reflectance spectroscopy(NIRS) was used to determine the humic acids in soil samples from the fields of different crops and land-use over Youngnam and Honam regions in Korea. An InfraAlyzer 500 scanning spectrophotometer was obtained near infrared relectance spectra of soil at 2-nm intervals from 1100 to 2500nm. Multiple linear regression(MLR) or partial least square regression (PLSR) was used to evaluate a NIRS method for the rapid and nondestructive determination of humic acid, fulvic acid and its total contents in soils. The raw spectral data(log 1/R) can be used for estimating humic acid, fulvic acid and its total contents in soil by MLR procedure between the content of a given constituent and the spectral response of several bands. In which the predicted results for fulvic acid is the best in the constituents. The new spectral data are converted from the raw spectra by PLSR method such as the first derivative of each spectrum can also be used to predict humic acid and fulvic acid of the soil samples. A low SEC, SEP and a high coefficient of correlation in the calibration and validation stages enable selection of the best manipulation. But a simple calibration and prediction method for determining humic acid and fulvic acid should be selected under similar accuracy and precision of prediction. NIRS technique may be an effective method for rapid and nondestructive determination for humic acid, fulvic acid and its total contents in soils.

• Spatial Information Research
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• 제8권1호
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• pp.117-130
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• 2000

본 연구는 교통시설사업의 기본계획에 지리정보시스템(GIS)을 활용한 공간분석(spatial analysis)을 이용하여 교통효율성과 환경영향, 장래 국토계획의 목표, 도시영향 그리고 건설가능성 및 경제성을 통합하여 고려할 수 있는 노선선정의 방법론을 개발하기위하여 시도되었다. 본 논문은 총 4장으로 구성되어 있으며 1 장 서론에서는 연구의 배경, 목적 그리고 연구범위와 방법을 정립하였으며, 2장에서는 교통시설사업의 노선선정 방법론의 개발을 위한 목표설정과 방법론의 수행과정을 설명하였다. 3장에서는 개발된 방법론을 독일의노이스(Neuss)와 그로벤브로히(Grenvenbroich)간의 도로건성을 위한 노선선정 프로젝트에 적용하였으며 본 방법론의 평가와 이용가능성을 결론으로 제시하였다.

• 생약학회지
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• 제33권3호통권130호
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• pp.182-186
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• 2002

The Coptidis rhizoma is known for containing protoberberine alkaloids. Berberine, coptisine and palmatine are the major constituents of protoberberine alkaloids. The alkaloids were isolated and determined by forming complex compounds from Coptidis rhizoma in preparation I(Sam-Hwang-Sa-Sim-Tang) and II(Hwang-Ryen-Tang). For the determination of these alkaloids, a new spectrophotometric method was developed with a simple and selective sample clean-up using thiocyanatocobaltate[II] complex compound ion. The absorbance of alkaloidal complex compounds in l.2-dichloroethane solution was measured at 625 nm. Calibration curve for the alkaloids isolated from Coptidis rhizoma was linear over the concentration range of 0.2-0.3 mg/ml. The method was proved to be rapid, simple and reliable for the isolation and the determination of the alkaloids in Coptidis rhizoma preparation I and II.

• 상하수도학회지
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• 제30권3호
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• pp.241-251
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• 2016

As the Enforcement Ordinance of Environmental Policy Act was revised in 2013, total organic carbon(TOC) was added as an indicative parameter for organic matter in Water and Aquatic Ecosystem Environmental Criteria. Under these imminent circumstances, a regulatory standard is needed to achieve the proposed TOC limitation control water quality from the public sewage treatment plants(PSTWs). This study purposes to present the determination method for TOC effluent limitation at the PSTWs. Therefore we investigate the TOC effluent limitation of foreign countries such as EU, Germany and USA, and analyse the effluent water qualities of PSTWs. In using these TOC data, we review apprehensively the statistics-based, the technology-based, and the region(water quality)-based determination method of TOC effluent limitation for PSTWs.

• 한국지반공학회:학술대회논문집
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• 한국지반공학회 2009년도 춘계 학술발표회
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• pp.23-29
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• 2009

A sand-cone method is commonly used to determine the density of the compacted soils. This method uses a calibration container to determine the bulk-density of the sand for use in the test. The density of the test or compacted soil is computed on the assumption that the calibration container has approximately the same size or volume and allows the sand to fall approximately the same height as a test hole in the field. However, in most cases the size or shape of test hole is not exactly the same as the calibration container. There is certain discrepancy between sand particle settlement or arrangement in the laboratory calibration and in the field testing, which may cause an erroneous determination of in-situ density. The sand filling process is simulated in the laboratory and its effect on the determination of density is investigated. Artificially-made holes with different heights and bottom shapes are prepared to simulate various shapes of the test hole in the field. The sands with different gradations are used in the testing to examine how sand grain size influences the determination of density in the field.

• Bulletin of the Korean Chemical Society
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• 제30권12호
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• pp.3034-3038
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• 2009

A simple, rapid, practical and sensitive spectofluorimetric method was developed for the determination of trace amount of heparin (Hep). Under the Optimum conditions, we studied the interaction between NFLX-Ce$^{3+}$-Hep complex by using absorption and fluorescence spectra. It was observed that Hep remarkably enhance the fluorescence intensity of the NFLX-Ce$^{3+}$ complex at ${\lambda}$= 356 nm in the buffer solution of pH = 7.60 and the enhancement effect is shown to relate with the concentration of Hep. The linear range and detection limit for the determination of Hep was obtained. By the Rosenthal graphic method, the association constant (K) and binding numbers (N) of Hep with probe were investigated. This method is relatively free of interference from coexisting substances and successfully applied for the determination of heparin in heparin sodium injection samples. A suitable mechanism of fluorescence enhancement between NFLX-Ce$^{3+}$ and the NFLX-Ce$^{3+}$-Hep systems were proposed and discussed.

• 대한전기학회논문지
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• 제40권3호
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• pp.299-307
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• 1991

This paper deals with the determination of a firing sequence of transitions in the reachability problem of Safe Petri Net. The determination problem of a firing sequence is very important from the point of practical view, especially in the control of the discrete systems modelled by Safe Petri Net. The determination method of a firing sequence of transitions by means of the matrix equation for the discrete systems modelled by Safe Petri Net is proposed. First, a construction method of the indicence matrix and the firing rule for Safe Petri Net with self-loop are presented by defining the permissive arc in place of self-loop. Next, we develop a method that can find the enable transitions of Safe Petri Net by means of the matrix equation of Safe Petri Net. Finally, by using this method, we propose an algorithm that determines the firing sequence of transitions of Safe Petri Net.

• 한국태양에너지학회:학술대회논문집
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• 한국태양에너지학회 2008년도 추계학술발표대회 논문집
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• pp.69-74
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• 2008

This study is to analyze and compare on the sky condition of cloud amount and measured solar horizontal irradiation in Seoul. Sky cover method is determination of sky condition used by cloud amount of the Meteorological Administration. And HCI method is determination of sky condition used by measured solar horizontal irradiation. The HCI methods of Erbs et al.(1982), Orgill and Hollands(1977) appear a lot of error because of the air pollution such as smog phenomenon or yellow sand phenomenon and so on. Therefore, The purpose of this study is to improve the method for determination of sky condition.

• Structural Engineering and Mechanics
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• 제17권2호
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• pp.267-279
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• 2004

This paper presents an improved Monte Carlo simulation for the probabilistic determination of initial cable forces of cable-stayed bridges under dead loads using the response surfaces method. A response surface (i.e. a quadratic response surface without cross-terms) is used to approximate structural response. The use of the response surface eliminates the need to perform a deterministic analysis in each simulation loop. In addition, use of the response surface requires fewer simulation loops than conventional Monte Carlo simulation. Thereby, the computation time is saved significantly. The statistics (e.g. mean value, standard deviation) of the structural response are calculated through conventional Monte Carlo simulation method. By using Monte Carlo simulation, it is possible to use the existing deterministic finite element code without modifying it. Probabilistic analysis of a truss demonstrates the proposed method' efficiency and accuracy; probabilistic determination of initial cable forces of a cable-stayed bridge under dead loads verifies the method's applicability.