• 제목/요약/키워드: Detailed Chemistry

검색결과 325건 처리시간 0.027초

Multi-environment PDF 모델을 이용한 MILD 연소과정 해석 (Multi-environment PDF Modeling for MILD Combustion Processes)

  • 지형근;전상태;김용모
    • 한국연소학회지
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    • 제22권4호
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    • pp.43-50
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    • 2017
  • In this study, the multi-environment probability density function(MEPDF) approach has been applied to numerically investigate Delft-Jet-in-Hot-Coflow(DJHC) turbulent flames under Moderate or Intense Low-oxygen Dilution (MILD) combustion condition. Computations are made for two different jet velocities(Re = 4100 and 8800). In terms of mean axial velocity, temperature, and turbulent kinetic energy, numerical results are in reasonably good agreements with experimental data even if there exist the noticeable deviations in downstream region. Based on numerical results, the detailed discussions are made for the essential features of the non-visible flame structure and MILD combustion processes.

탄화수소/산소 혼합기체가 채워진 관 내부를 전파하는 데토네이션 파의 해석과 가시화

  • 최정열
    • 한국가시화정보학회:학술대회논문집
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    • 한국가시화정보학회 2004년도 춘계학술대회 논문집
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    • pp.29-36
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    • 2004
  • A numerical study is carried out on the detonation wave propagation through a T-shaped flame tube, which represents a crucial part of the combustion wave ignition (CWI) system aimed for simultaneous ignition of multiple combustion chambers by delivering detonation waves. The formulation includes the Euler equations and an induction-parameter model. The reaction rate is treated based on a chemical kinetics database obtained from a detailed chemistry mechanism. A second-order implicit time integration and a third-order TVD algorithm are Implemented to solve the theoretical model numerically. A total of more than two-million grid points are used to provide direct insight into the dynamics of the detonation wave. Several important phenomena including detonation wave propagation, degeneration, and re-initiation are carefully examined. Information obtained can be effectively used to facilitate the design and optimization of the flame tubes of CWI systems.

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HFP가 첨가된 수소/공기 혼합기의 자연점화에서의 화학반응 (Chemical Reaction of $H_2$/Air Mixture Inhibited by Heptafluoropropane(HFP) during Autoignition Process)

  • 이의주;오창보
    • 한국화재소방학회:학술대회논문집
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    • 한국화재소방학회 2008년도 춘계학술논문발표회 논문집
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    • pp.100-103
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    • 2008
  • Autoignition suppression of hydrogen/air premixed mixtures by $CF_3CHFCF_3$(HFP) was investigated computationally. Numerical simulation was performed in isobaric and homogeneous system to evaluate the induction times. The detailed chemistry of 93 species and 817 reaction mechanism was introduced for hydrogen/air/HFP mixtures. The results shows the similar concentrations for the major reactants such as hydrogen and oxygen during autoignition while water vapor produced at the ignition temperature was decomposed later, which leaded to the shoulder on the concentration of H, OH and O radical with time. The fluorine included from HFP was converted mainly to stable HF and the carbon was formed to various species, CF2, CF2O, CO etc. More details of chemical effects of HFP addition will be investigate with sensitivity analysis in the near future.

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Graphene Derivatives for Bioapplications: Cellular Response to Graphene and Behaviors of Mammalian Cells

  • Min, Dal-Hee
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2011년도 제40회 동계학술대회 초록집
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    • pp.7-7
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    • 2011
  • Graphene and graphene derivatives have attracted enormous attention from various research fields for applications in electronic devices, transparent electrodes, biosensors, drug delivery system and surface coatings. In the viewpoint of chemist, the chemical structure of graphene derivatives seems intriguing but detailed structures are being revealed only recently while engineering approaches for various applications are being executed very actively. In addition, cytotoxicity and mammalian cellular responses to graphene have not thoroughly investigated yet in spite of the importance in bio-applications and environment. In this talk, I'll introduce recent studies which report cytotoxicity and behaviors of mammalian cells when the cells are exposed to graphene (as well as some bio-applications of graphene), especially to get closer to answers to these questions, "how we understand and how/why we use graphene in biotechnology".

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Damkohler 수가 비예혼합 CO/$H_2$/$N_2$ 난류 화염장에서의 초과평형농도 및 화염구조에 미치는 영향 (Effect of Damkohler Number on Superequilibrium Concentration and Flame Structure in Turbulent Nonpremixed Jet Flames)

  • 김군홍;김용모;윤명원
    • 한국자동차공학회논문집
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    • 제10권6호
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    • pp.51-58
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    • 2002
  • The RPV(Reaction Progress Variable) combustion model has been applied to numerically investigate the effects of Damkohler number on the superequilibrium concentration and flame structure in the nonpremixed turbulent flames. Computations are performed for the two turbulent jet flames of CO/H$_2$/N$_2$(40/30/30 volume percent) having the same jet Reynolds number of 16,700 but different nozzle diameters(4.58mm and 7.72mm). The detailed discussions have been made for the interaction between fluid dynamics and chemistry in the flame field.

아세틸렌/공기 비예혼합 난류 제트화염의 Soot 생성에 대한 수치해석 (Numerical Analysis for the Soot Formation Processes in Acetylene-Air Nonpremixed Turbulent Jet Flame)

  • 김후중;김용모;윤명원
    • 한국자동차공학회논문집
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    • 제10권6호
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    • pp.80-89
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    • 2002
  • The flame structure and soot formation in Acetylene-Air nonpremixed jet flame are numerically analyzed. We employed two variable approach to investigate the soot formation and oxidation processes. The present soot reaction mechanism involves nucleation, surface growth, particle coagulation, and oxidation steps. The gas phase chemistry and the soot nucleation, surface growth reactions are coupled by assuming that the nucleation and soot mass growth has the certain relationship with the concentration of pyrene and acetylene. We also employed laminar flamelet model to calculate the thermo-chemical properties and the proper soot source terms from the information of detailed chemical kinetic model. The numerical and physical model used in this study successfully predict the essential features of the combustion processes and soot formation characteristics in the reaction flow field.

초임계 압력에서 기체수소/액체산소의 연소과정 해석 (Analysis of Gaseous Hydrogen/liquid Oxygen Combustion Processes at Supercritical State)

  • 김태훈;김성구;김용모
    • 한국분무공학회지
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    • 제15권4호
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    • pp.189-194
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    • 2010
  • This study has been mainly motivated to numerically model the transcritical mixing and reacting flow processes encountered in the liquid propellant rocket engines. In the present approach, turbulence is represented by the extended k-$\varepsilon$ turbulence model. To account for the real fluid effects, the propellant mixture properties are calculated by using SRK (Souve-Redlich-Kwong) equation of state model. In order to realistically represent the turbulence-chemistry interaction in the turbulent non-premixed flames, the flamelet approach based on the real fluid flamelet library has been adopted. Based on numerical results, the detailed discussions are made for the real fluid effects and the precise structure of the transcritical cryogenic liquid nitrogen jet and gaseous hydrogen/liquid oxygen coaxial jet flame.

Crystal structure of mismatch repair protein MutS and its complex with a substrate DNA

  • Ban, Changill
    • 한국결정학회:학술대회논문집
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    • 한국결정학회 2003년도 춘계학술연구발표회
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    • pp.16-16
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    • 2003
  • Mismatches in a DNA duplex are mainly due to DNA duplication errors that are generated by improper function of DNA polymerase. MutS, MutL and MutH are crucial proteins for the initiation of the methyl-directed mismatch repairing in bacteria. MutS has an ATPase activity md recognize the mismatched or unpaired bases on DNA. After binding to a mismatch, MutS recruits MutL to mediate the activation of MutH an endonuclease, which cleaves the 5' site of d(GATC) on the un-methylated strand. Both MutL and MutS also have essential roles in the subsequent removal and re-synthesis of the daughter strand. We have determined the crystal structures of either intact or active fragments of each of these proteins, both alone and complexed with ligands (DNA, ADP and ATP). The biochemical and mutagenesis studies based on the detailed 3-D structures led to new insights into the role of the ATPase activity of MutS in the mismatch recognition and directions for future investigation of mismatch repair.

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New Records of Two Agarics: Galerina sideroides and Gymnopus luxurians in South Korea

  • Jang, Seokyoon;Jang, Yeongseon;Kim, Jae-Jin
    • 한국균학회지
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    • 제43권2호
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    • pp.88-91
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    • 2015
  • Studies on the diversity of indigenous fungi were conducted in the central districts of South Korea from 2008 to 2013. During the studies, potentially unrecorded agarics were collected. All specimens collected in this study were examined morphologically and phylogenetic analysis was also performed. They were identified as Galerina sideroides and Gymnopus luxurians. These fungi have never been reported in South Korea. We report them here with detailed descriptions and figures.

수소 연료의 연소조건 변화에 따른 NOx 배출 특성에 관한 연구 (A Study on the NOx Emission Characteristics in Parametrically Varied Laminar Hydrogen-Air Coflow flames)

  • 김종현;이근오;이창언
    • 한국안전학회지
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    • 제16권4호
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    • pp.82-87
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    • 2001
  • The NOx emission characteristics of jet flames fueled with It was studied. Experimental and numerical investigations were carried out for various flames with varying equivalence ratio, fuel flow rate and nozzle diameter. The Emission indices of NOx(EINOx) were measured by chemiluminescent method and calculated by simulation using detailed chemistry. The results show that the numerical results represent well the trends of EINOx experimentally observed. EINOx of H$_2$ flame steeply increase at small equivalence ratio, gently increase and steady at more than equivalence ratio is 4.0. EINOx trends of H$_2$ flame can be describe in function of residence time in the high-temperature region weighted by the maximum flame temperature.

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