• 제목/요약/키워드: Dependence of Spectrum

검색결과 194건 처리시간 0.022초

CaMoO4:Tb3+ 녹색 형광체 분말과 박막의 제조와 발광 특성 (Synthesis and Emission Properties of CaMoO4:Tb3+ Green Phosphor Powders and Thin Films)

  • 전용일;조신호
    • 한국전기전자재료학회논문지
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    • 제26권4호
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    • pp.264-270
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    • 2013
  • $CaMoO_4:Tb^{3+}$ green phosphor powders and thin films were successfully prepared by using the solid-state reaction method and the radio-frequency magnetron sputtering technique, respectively. The crystalline structure of all phosphor powders with different $Tb^{3+}$ ion concentrations was found to be a tetragonal system with the maximum diffraction intensity at $28.58^{\circ}$, while that of the phosphor thin films, irrespective of the type of substrate, was amorphous. As for the phosphor powders, the grain particles showed the chain-like patterns with inhomogeneous size distribution, the excitation spectra were composed of a broad band peaked at 307 nm and two small narrow bands centered at 381 and 492 nm, and the highest green emission spectrum was observed at 0.01 mol of $Tb^{3+}$ ions. As for the phosphor thin films, the average transmittance exceeding 85% was measured in the 400~1,100 nm range and the optical band gap showed a significant dependence on the type of substrate.

Electron Magnetic Resonance of Eu2+ in SrCl2:Eu Single Crystal

  • Lee, Soo Hyung;Yeom, Tae Ho;Kim, Sung-Hwan
    • Journal of Magnetics
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    • 제17권4호
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    • pp.251-254
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    • 2012
  • The electron paramagnetic resonance (EPR) of the $Eu^{2+}$ ion in $SrCl_2$:Eu single crystal has been investigated using an X-band spectrometer. The angular dependence of magnetic resonance positions for the $Eu^{2+}$ impurity ion in the crystallographic aa-plane is analyzed with effective spin-Hamiltonian. The EPR spectra of the isolated $Eu^{2+}$ center merged to each other. The hyperfine splitting of the isolated $Eu^{2+}$ center due to the $^{151}Eu$ nucleus is approximately 35 G. Three kinds of $Eu^{2+}$ centers except the isolated $Eu^{2+}$ center, $Eu^{2+}$ pairs, $Eu^{2+}$ triples, and other $Eu^{2+}$ clusters, are split from the fitting of the integrated experimental spectrum with the Gaussian curve. The calculated spectroscopic splitting parameters of the $Eu^{2+}$ pairs, $Eu^{2+}$ triples, and other $Eu^{2+}$ clusters in $SrCl_2$:Eu crystal are $g_1$ = 2.06, $g_2$ = 1.94, and $g_3$ = 1.93, respectively.

대기안정도(大氣安定度)와 지형조건(地形條件)에 따른 풍향변동폭(風向變動幅)의 특성(特性) (Influence of Atmospheric Stability and Topography on the Wind Direction Fluctuations)

  • 김용국;이종범
    • 한국대기환경학회지
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    • 제8권2호
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    • pp.138-145
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    • 1992
  • Dependence of the standard deviation of wind direction fluctuations, ${\sigma}_{\theta}$, on atmospheric stability, averaging time and topography were analysed with the data measured at three sites, Youngjongdo beach of the Yellow Sea, Chuncheon basin and Doam-Dam valley. The results show that the mean value of ${\sigma}_{\theta}$ is large in complex terrain, the Doam-Dam site. It is notable that the large value of ${\sigma}_{\theta}$ at night is associated with the low wind speed and the strong stable condition. In order to study the long-period fluctuations of the wind direction, ${\sigma}_{\theta}$ for longer than 10 minutes averaging time was further analysed using the data obtained at the Chuncheon basin. At the averaging time shorter than 60 minutes, larger ${\sigma}_{\theta}$ is associated with longer averaging time in the strong stable condition. However, ${\sigma}_{\theta}$ was not affected significantly by wind speed and averaging time in neutral conditions. The results of the spectrum analysis for the time series data of wind direction showed that low-frequency fluctuations ranging from 10 to 60 minutes were dominated at the Chuncheon basin in strong stable condition.

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Modeling the tidal connection between in and around galaxy clusters

  • 송현미;이정훈
    • 천문학회보
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    • 제36권2호
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    • pp.53.1-53.1
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    • 2011
  • We analyze the halo and galaxy catalogs from the Millennium simulations at redshifts z=0, 0.5, 1 to determine the alignment profiles of cluster galaxies in terms of the matter density correlation coefficient and discuss a cosmological implication our result has for breaking parameter degeneracies. For each selected cluster, we measure the alignment between the major axes of the pseudo inertia tensors from all satellites within cluster's virial radius and from only those satellites within some smaller radius. Then we average the measured values over the similar-mass sample to determine the cluster galaxy alignment profile as a function of top-hat scale difference at each redshift. It is shown that the alignment profile of cluster galaxies is well approximated by a power-law of the nonlinear density correlation coefficient that is independent of the power spectrum normalization and bias factor. The alignment profile of cluster galaxies is found to have higher amplitude and lower power-law index when averaged over the larger-mass sample and to have rather weak redshift-dependence. This result is consistent with the picture that the satellite galaxies retain the memory of the external tidal fields right after merging and infalling into the clusters but they gradually lose the initial alignment tendency as the cluster's relaxation proceeds. Demonstrating that the nonlinear density correlation coefficient varies sensitively with the density parameter and neutrino mass fraction, we discuss a potential power of the cluster galaxy alignment profile as an independent probe of cosmology.

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액체분자의 재배치 운동에 관한 라만 분광법적 연구 (제3보) 순수한 $C_6F_6$ 액체분자의 회전운동에 대한 온도의 영향 (Study of Molecular Reorientation in Liquid with Raman Spectroscopy(III). Temperature Dependence of Molecular Rotation of $C_6F_6$ in Neat Liquid)

  • 김명수
    • 대한화학회지
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    • 제28권1호
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    • pp.34-40
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    • 1984
  • 라만 분광법을 사용하여 순수한 액체 상태의 $C_6F_6$의 재배치 운동을 연구하였다. 라만 스펙트럼 중 ${\nu}_2$${\nu}_16$ 밴드를 선정하여 그 모습을 293~333K온도 범위에서 측정하였다. 분자의 주대칭축($C_{6-}$축)의 회전 및 스핀운동에 관한 회전 확산 상수 ($D_{\bo}$, $D_{\parallel}$)가 온도의 함수로써 결정되었으며 이로부터 $C-6F_6$의 재배치운동은 명백히 비등방적임을 알게 되었다. 실험 결과를 유체역학적 모델로 분석하여 본 결과 주대칭축의 회전운동은 확산적이며 스핀운동은 관성적이라는 것이 밝혀졌다.

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Sulfur를 첨가한 $In_{1-x}Ga_xP$의 발광 다이오드 특성 (The characteristics of the sulfur-doped $In_{1-x}Ga_xP$ Light emitting diode)

  • 조명환;문동찬;김선태
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 1988년도 추계학술대회 논문집 학회본부
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    • pp.168-171
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    • 1988
  • The p-n homo junction diode of the III-V ternary alloy semiconductor $In_{1-x}Ga_xP$ : S grown by the temperature gradient solution (TGS) was fabricated by Zn-diffusion, and it's characteristics was investigated. The carrier concentration of $In_{1-x}Ga_xP$ doped with sulfur, 0.5 mol %, was $1{\times}10^{17}cm^{-3}$ and the mobility was varied with the composition. In the case that the diffusion time was constant as 30 minutes. The temperature dependence of diffusion coefficient was decreased from D= $4.2{\times}10^{-5}$ exp (-1.74/$k_{B}T$) to D= $2.5{\times}10^{-5}$ exp (-3.272/$k_{B}T$) with increasing of composition $\times$ from 0.43 to 0.98. The major peak of E.L spectrum was due to D-A pair recombination and the peak intensity was increased with the increasing of input current. And the E.L intensity was decreased with the increasing temperature, and shift to the long wavelength. The luminescence efficiencies measured at $5^{\circ}C$, atmosphere temperature, was decreased from $2.6{\times}10^{-4}$% to $9.49{\times}10^{-6}$ % with increasing of composition it from 0.39, direct transition region, to 0.98, indirect transition region.

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둥근형 무전극 램프의 페라이트 코어와 냉점의 온도 의존성 (Dependence of Round Type Electrodeless Lamp According to Ferrite Core and Cold Spot Temperature)

  • 김남군;양종경;이종찬;한후석;박지식;박대희
    • 전기학회논문지
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    • 제57권5호
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    • pp.833-838
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    • 2008
  • Generally Lighting system consists of lamp and luminaire. When a fluorescent lamp is installed in luminaire, power and light output is changed by ambient temperature. Particularly electrodeless lamp depends on the changes that are mercury pressure with amalgam temperature and magnetic properties with ferrite temperature. It has finally influence on optical efficiency. In this study, the temperature change of ferrite and cold spot, vessel are measured at transitional state and then same characteristics are measured with increase of ambient temperature. At transitional state, luminous flux is related to temperature change of cold spot that compare with behavior of mercury pressure and light output. At increase of ambient temperature, we analyzed change that efficiency and electrical, optical characteristics of elecrodeless lamp are related to ferrite core and cold spot temperature. Additionally, spectrum, color temperature and coordination are measured to check that is relation with ambient temperature.

Hot wall epitaxy법에 의해 성장된 $AgInS_2$ 박막의 광전기적 특성 (Opto-electric properties for the $AgInS_2$ epilayers grown by hot wall epitaxy)

  • 이관교;홍광준
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2004년도 하계학술대회 논문집 Vol.5 No.1
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    • pp.267-270
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    • 2004
  • A silver indium sulfide($AgInS_2$) epilayer was grown by the hot wall epitaxy method, which has not been reported in the literature. The grown $AgInS_2$ epilayer has found to be a chalcopyrite structure and evaluated to be high qualify crystal. From the photocurrent measurement in the temperature range from 30 K to 300 K, the two peaks of A and B were only observed, whereas the three peaks of A, B, and C were seen in the PC spectrum of 10 K. These peaks. are ascribed to the band-to-band transition. The valence band splitting of $AgInS_2$ was investigated by means of the photocurrent measurement. The crystal field splitting, $\ddot{A}cr$, and the spin orbit splitting, $\ddot{A}so$, have been obtained to be 0.150 eV and 0.009 eV at 10 K, respectively. And, the energy band gap at room temperature has been determined to be 1.868 eV. Also, the temperature dependence of the energy band gap, $E_g(T)$, was determined.

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포항지진의 피해 결과를 반영한 기존 저층 필로티 건물의 지진취약도함수 (Seismic Fragility Function for Existing Low-Rise Piloti-Type Buildings Reflecting Damage From Pohang Earthquake)

  • 김진영;김태완
    • 한국지진공학회논문집
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    • 제25권6호
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    • pp.251-259
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    • 2021
  • Current seismic fragility functions for buildings were developed by defining damage state threshold based on story drift concerning foreign references and using the capacity spectrum method based on spectral displacement. In this study, insufficient details and dependence on the core location of piloti-type buildings were not reflected in the fragility function because it was developed before the Pohang earthquake. In order to develop an improved one for piloti-type buildings, several types of core were selected, damage state threshold was determined based on the capacity of structural members, and three-dimensional analyses were utilized. As a result, seismic fragility functions based on spectral acceleration were developed for various core locations and different shear strengths of the column stirrup. The fragility of piloti-type buildings significantly varied according to core location, an additional single wall, and whether the contribution of column stirrup was included or not. To estimate fragility more reasonably, it is necessary to prepare the parameters to reflect actual state well.

Photoisomerization of Symmetric Carbocyanines

  • 민형식;강유남;박정희
    • Bulletin of the Korean Chemical Society
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    • 제19권7호
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    • pp.747-753
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    • 1998
  • The phoisomerization process of symmetric carbocyanine dyes such as 3,3'-diethyloxadicarbocyanine iodide (DODCI), 3,3'-diethylthiadicarbocyanine iodide (DfDCI), 1,1'-diethyl-2,2'-dicarbocyanine iodide (DDI), 1,1'-diethyl-2,2'-carbocyanine iodide (DCI), and cryptocyanine (1,1'-diethyl-4,4'-carbocyanine) iodide (CCI) have been studied by measuring the steady state and time resolved fluorescence spectra and the ground-state recovery profiles. The steady-state fluorescence spectrum of photoisomer as a function of concentration and excitation wavelength provides the evidence that the fluorescence of photoisomer is formed by the radiative energy transfer from the normal form and the quantum yield for the formation of photoisomer is increased by decreasing the excitation wavelength. The fluorescence decay profiles have been measured by using the time correlated single photon counting (TCSPC) technique, showing a strong dependence on the concentration and the detection wavelength, which is due to the formation of excited photoisomers produced either by the radiative energy transfer from the non-nal form or by absorbing the 590 nm laser pulse. We first report the fluorescence decay time of photoisomers for these cyanine dyes. The experimental results are explained by introducing the semiempirical calculations. The ground state recovery profiles of DTDCI, DDI, and CCI normal forms have been measured, showing that the recovery time from the singlet excited state is similar with the fluorescence decay time.