• 한국환경과학회지
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• 제17권8호
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• pp.833-840
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• 2008

Deoxygenation process in which CBOD(carbonaceous BOD) is biochemically oxidized to reduced inorganic compounds is of great significance in the oxygen demand of stream waters. The CBOD decay rate has traditionally been determined in a laboratory by CBOD bottle incubation method. But in this study, CBOD decay rates were obtained by laboratory incubation method and natural waters experiment. Average CBOD decay rate for the Nakdong river(upper zone) in natural waters were 0.553 $day^{-1}$ during April 2005 to January 2007. The values in the middle and down parts of the Nakdong river in natural waters were 0.384 $day^{-1}$ and 0.252 $day^{-1}$ at the same period of time, respectively. Average CBOD decay rates using by incubation method in the upper/middle/down parts of the main stream in the Nakdong river basin was 0.270 $day^{-1}$, and 0.289 $day^{-1}$, and 0.283 $day^{-1}$ during April 2005 to January 2007, respectively.

• Journal of Industrial and Engineering Chemistry
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• 제68권
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• pp.380-386
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• 2018

A sustainable method was developed for the upgrade of biomass derived vanillin (a typical model compound of lignin) into the potential liquid biofuels over a layered double hydroxide supported Pd catalyst (abbreviated as CoAl-LDH/Pd). The CoAl-LDH/Pd catalyst showed high catalytic activity towards the hydrodeoxygenation of vanillin into 2-methoxy-4-methylphenol (MMP) under mild conditions in aqueous media. High MMP yield up to 86% was produced at $120^{\circ}C$ after 4 h. Kinetic studies revealed that the rate-determining step for the hydrodeoxygenation of vanillin was the hydrogenolysis of vanillyl alcohol. More importantly, the CoAl-LDH/Pd catalyst was highly stable without the loss of activity.

• 한국물환경학회지
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• 제28권2호
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• pp.178-184
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• 2012

BOD decay rate is a key parameter of BOD-DO models in streams and lakes. In the calibration of water quality modeling appropriate range of coefficient is required for guidance of parameter selection. In this study BOD decay rate was measured at 48 stream sites and 10 reservoir sites in 8 different river systems. The decay rate ranged from 0.09 to 0.25 $day^{-1}$ with a mean of 0.16 $day^{-1}$. Among river systems the decay rates showed significantly different ranges, with the Han River system showing higher values than other river systems. In comparing different types of water bodies, the decay rate was slightly higher in tributaries than in reservoirs and mainstreams. Our results can provide guidance to the selection of proper coefficient for various water bodies in the calibration of water quality models.

• 한국수산과학회지
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• 제23권3호
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• pp.198-207
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• 1990

하천과 연안의 극심한 오염을 유발하고 있는 액상폐기물을 동해남부해역에 투기할 목적으로 용존산소분포에 기초하여 허용농도와 최적투기율을 결정하였다. 허용농도 산출은 Streeter-Phelps 모델을 이용하였으며 이 모델의 인자인 탈산소계수는 2개월 간격으로 1년동안 각 수심별 해수에 유기물을 주입한 후 산소소모양을 측정하여 Thomas slope method에 따라 구하였고, 재폭기계수는 Redfield의 폐쇄계모델을 적용, 1년간의 현장관측재료와 C. S. K 자료를 이용하여 산출하였다. 투기율은 Csanady의 초기희석 이론을 적용하였다. 연구결과 표층에서 각 수심까지의 탈산소계수는 하계 $0.24\~0.29/day$, 동계 $0.17\~0.20/day$였으며, 재폭기계수는 하계 $0.03\~0.39/day$, 동계 $0.04\~0.56/day$이었다. 이들 인자로써 초기희석수괴의 용존산소를 $5mg/{\iota}$ 이상으로 유지할 수 있는 각 수심까지의 허용농도는 하계 $2.83\~7.33mgBOD/\iota$, 동계 $4.37\~18.83mgBOD/\iota$이었다. 혼합수심(H)과의 관계를 이용하여 산출된 허용농도($mgBOD/\iota$)는 하계 $17.23\times(H)^{-0.37}$, 동계 $54.96\times(H)^{-0.62}$으로 표현할 수 있었다. 이 허용농도에 기초하여 최적투기율($m^3/sec$)은 이호의 폭(b, m), 흘수(h, m) 그리고 폐기물의 BOD($L_n$, $mg/\iota$)의 함수로 하계에는 $R=275{\times}bh^{0.63}/L_n$, 동계에는 $=745{\times}bh^{0.48}L_n$으로 산출되었다. 이러한 차리는 하계와 동계의 용존산소농도 분포와 이를 좌우하는 각 인자에 기인한 것이다.

• Nuclear Engineering and Technology
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• 제31권6호
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• pp.541-547
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• 1999

Corrosion control, in the end-shield cooling system of Wolsung Nuclear Power Plant, is directly related to the control of dissolved oxygen (DO). The current method, being used to deoxygenate the end-shield cooling water, is a chemical treatment by addition of reducing agent, hydrazine, to react with DO. This method has several limitations including high reaction temperature of hydrazine , unwanted explosive hydrogen gas production, and its intrinsic harmful property. A new approach to remove DO using a membrane-based oxygen removal system (MORS) was tried to overcome limitations of the hydrazine treatment. The DO removal efficiency of the MORS was found to be in the range 87% to 98%: The higher vacuum, the lower water flow rate and the higher water temperature tend to increase the DO removal efficiency.

• 한국수산과학회지
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• 제29권6호
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• pp.787-796
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• 1996

The biodegradation experiment, the TOD analysis and the element analysis for dispersant, Bunker-A oil and Bunker-B oil were conducted to study the biodegradation characteristics of a mixture of Bunker-A oil with dispersant and a mixture of Bunker-B oil with dispersant in the seawater. The results of biodegradation experiment showed 1mg of dispersant to be equivalent to 0.26 mg of $BOD_5$ and to 0.60 mg of $BOD_{20}$ in the natural seawater. The results of TOD analysis showed each 1 mg of dispersant, Bunker-A oil and Bunker-B oil to be equivalent to 2.37 mg, 2.94 mg and 2.74 mg of TOD, respectively. The results of element analysis showed carbon, hydrogen, nitrogen and phosphorus contents of dispersant to be $82.1\%,\;13.8\%,\;1.8\%\;and\;2.2\%$, respectively. Carbon and hydrogen contents of Bunker-A oil were found to be $73.3\%\;and\;13.5\%$, respectively, and carbon, hydrogen and nitrogen contents of Bunker-B oil to be $80.4\%,\;12.3\%\;and\;0.7\%$, respectively. Accordingly, the detection of nitrogen and phosphorus in dispersant shows that dispersants should be used with caution in coastal waters, with relation to eutrophication. The biodegradability of dispersant expressed as the ratio of $BOD_5/TOD$ was found to be $11.0\%$. As the mix ratios of dispersant to Bunker-A oil (3 mg/l) and a mixture of Bunker-B oil (3mg/l) were changed from 1 : 10 to 5 : 10, the biodegradabilities of a mixture of Bunker-A oil with dispersant and Bunker-B oil with dispersant increased from $2.1\%\;to\;7.2\%$ and from $1.0\%\;to\;4.4\%$, respectively. Accordingly, the dispersant belongs to the organic matter group of middle-biodegradability while mixtures in the mix ratio range of $1:10\~5:10$ belong to the organic matter group of low-biodegradability. The deoxygenation rate constant $(K_1)$ and ultimate biochemical oxygen demand $(L_0)$ obtained from the biodegradation experiment and Thomas slope method were found to be 0.125/day and 2.487 mg/l for dispersant (4 mg/l), respectively. $K_1\;and\;L_0$, were found to be $0.079\~0.131/day$ and $0.318\~2.052\;mg/l$ for a mixture of Bunker-A oil with dispersant and to be $0.106\~0.371/day$ and $0.262\~1.106\;mg/l$ for a mixture of Bunker-B oil with dispersant, respectively, having $1:10\~5:10$ mix ratios of dispersant to Bunker-A oil and Bunker-B oil. The ultimate biochemical oxygen demands of the mixtures increased as the mix ratio of dispersant to Bunker-A, B oils changed from 1 : 10 to 5 : 10. This suggests that the more dispersants are applied to the sea for the cleanup of Bunker-A oil or Bunker-B oil, the more decreases the dissolved oxygen level in the seawater.

• 한국지반환경공학회 논문집
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• 제4권3호
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• pp.69-77
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• 2003

대청호에서 WASP5 모델의 매개변수를 산정하고 민감도분석을 실시하였다. 모델의 계산치와 실측치는 값과 그 경향에 있어 근사한 것으로 나타나 이를 통해 대전취수탑 유역의 장래수질예측이 가능하였다. 매개변수의 민감도분석 결과 조류의 최대성장율, 조류의 호흡율, 광소멸계수, 온도 등이 Chlorophyll-a에 가장 큰 영향을 주는 것으로 나타났으며 T-N에 영향을 주는 주된 인자는 용존유기질소 분해율과 온도이며 T-P는 인부하량, 온도, 광소멸계수, 용존유기인 분해율, 조류의 최대성장율 등의 순으로 영향을 받는 것으로 나타났다. BOD에 큰 민감도를 보인 인자는 탈산소계수와 온도였으며, DO는 온도 외의 매개변수에 대한 영향은 거의 없는 것으로 나타났다. 모델의 민감도분석을 통하여 해당 수역에 적합한 입력변수의 민감도에 대한 평가를 하였으며 각 수질항목에 대한 입력변수의 영향에 대한 파악을 통해서 모델의 적용에 주의를 기해야할 해당 입력변수의 구분이 가능하였다.

• 한국물환경학회지
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• 제21권5호
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• pp.511-515
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• 2005

CBOD(carbonaceous BOD) decay rate was investigated for the execution of water quality model in Nakdong-Rive basin. Estimation of laboratory-derived CBOD decay rate, $k_l$ and CBOD decay rate in natural waters, $k_d$ were carried out. Hydraulic factors were applied for the calculation of $k_d$. Values of biochemical oxygen demand were investigated in Weagwan, Koreong, Jeokpo, Namgi and Mulgeom sites for the four times. The ranges of $k_l$ value were $0.04{\pm}0.01{\sim}0.14{\pm}0.03$. The values of $k_l$ in upstream sites were much larger than those in the downstream sites. The values of $k_d$ were 0.025, 0.036, 0.005 and 0.001 at Weagwan, Jeokpo, Namgi and Mulgeom, respectively, indicating that values of $k_d$ were generally larger than those of $k_l$.

• 대한화학회지
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• 제26권5호
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• pp.340-348
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• 1982

술폭시화물을 보란으로 환원할 때 붕산트리페닐을 촉매량(10몰 퍼센트) 가하면 대응하는 황화물로 환원이 현저히 촉진됨이 관찰되어 이 환원계에 의해 구조적으로 서로 다른 몇가지 술폭시화물의 환원반응이 조사되었다. 술폭시화 테트라메틸렌은 5분 이내(보란만으로는 24시간 걸림) 술폭시화 디에틸, 술폭시화 디벤질, 술폭시화 벤질페닐은 1시간내에 정량적으로 환원이 완결되었으며 술폭시화 디페닐은 반응이 느려서 24시간에 90% 수율(보란만으로는 24시간에 18% 수율)로 환원되었다. 삼플루오르화붕소 에틸에테르 및 붕산트리에틸의 촉매효과는 붕산트리페닐보다 덜하였다.

• 한국환경과학회지
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• 제16권5호
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• pp.623-632
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• 2007

The objective of this study is analysis of Andong-Dam lake water quality with water quality model. Model parameters of the WASP applied to Lake Andong-Dam were estimated. The methodology is based on grouping water quality constituents and relevant parameters and successively estimating parameters by a trial-and-error procedure. Water qualify system for modeling consisted of BOD, DO, T-N, T-P. The results of water quality modelling using WASP. T-N was maximum affected by K71C(Organic nitrogen mineralization rate) parameter. T-P was maximum affected by K83C(Dissolved organic phosphorus mineralization) parameter, and It did not show a difference almost from the parameter of others and it omitted. BOD was maximum affected by Temperature parameter, it was visible of the reaction due to the KDC(Deoxygenation rate) in afterwords, and it did not show a difference from the parameter of others and it omitted. DO was maximum affect by Temperature parameter, and It did not show a difference almost from the parameter of others and it omitted. The parameter which it presumes from the this study uses a water quality modeling and Actual value and the result with which it compares, error rate the parameter presumption which is appropriate with 1% interior and exterior is investigated, It will reach and it uses and it will be able to apply to the suitable parameter in water quality modelling of the objective area which can be feeded by it becomes.