Journal of Industrial and Engineering Chemistry

  • Volume 68
  • /
  • Pages.380-386
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  • 2018
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  • 1226-086X(pISSN)
  • /
  • 1876-794X(eISSN)
The Korean Society of Industrial and Engineering Chemistry (한국공업화학회)
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Catalytic deoxygenation of vanillin over layered double hydroxide supported Pd catalyst

  • Liao, Chanjuan (College of Resources and Environment, Hunan Agricultural University) ;
  • Liu, Xixi (Key Laboratory of Catalysis and Materials Sciences of the Ministry of Education, South-Central University for Nationalities) ;
  • Ren, Yongshen (Key Laboratory of Catalysis and Materials Sciences of the Ministry of Education, South-Central University for Nationalities) ;
  • Gong, Daoxin (College of Resources and Environment, Hunan Agricultural University) ;
  • Zhang, Zehui (Key Laboratory of Catalysis and Materials Sciences of the Ministry of Education, South-Central University for Nationalities)
  • Received : 2018.05.02
  • Accepted : 2018.08.21
  • Published : 2018.12.25
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Abstract

A sustainable method was developed for the upgrade of biomass derived vanillin (a typical model compound of lignin) into the potential liquid biofuels over a layered double hydroxide supported Pd catalyst (abbreviated as CoAl-LDH/Pd). The CoAl-LDH/Pd catalyst showed high catalytic activity towards the hydrodeoxygenation of vanillin into 2-methoxy-4-methylphenol (MMP) under mild conditions in aqueous media. High MMP yield up to 86% was produced at $120^{\circ}C$ after 4 h. Kinetic studies revealed that the rate-determining step for the hydrodeoxygenation of vanillin was the hydrogenolysis of vanillyl alcohol. More importantly, the CoAl-LDH/Pd catalyst was highly stable without the loss of activity.

Keywords

Acknowledgement

Supported by : Central University for Nationalities

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