• Title/Summary/Keyword: Delta-1

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Occurrence of cis-4-Tetradecenoic Acid in the Oils of Kernels of Lindera erythrocarpa Seeds, as a Major Component

  • Kim, Seong-Jin;Joh, Yong-Goe
    • Food Science and Biotechnology
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    • 제15권1호
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    • pp.107-111
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    • 2006
  • Kernel oils of Lindera erythrocarpa seeds had high level of unusual fatty acid. Picolinyl ester of this unknown fatty acid showed molecular ion at m/z = 317 with other diagnostic ions such as m/z = 151, 191 (40 amu between two peaks), 204, and 218 on GC-MS. Characteristic peak at $720\;cm^{-1}$ appeared in IR spectrum. In $^1H-NMR$ spectrum both methylene protons at C-3 and C-6 resonated at ${\delta}2.309$ and ${\delta}2.012$, and methine protons of double bond resonated in lower magnetic field centered at ${\delta}5.296$ (C-4) and ${\delta}5.387$ (C-5) as multiplet (J = 9.7Hz). In $^{13}C-NMR$, signals at ${\delta}22.669$ and ${\delta}27.048$ were due to C-3 and C-6 of ${\delta}^4$-monoenoic acid. Results obtained from spectroscopic measurements confirmed unknown fatty acid as cis-4-tetradecenoic acid (cis-4-$C_{14:1}$). Main fatty acid components of oils were cis-4-$C_{14:1}$ (44.5-45.1%), oleic acid ($C_{18:1}$), 20.4-21.3%), and lauric acid ($C_{12:0}$, 11.6-12.4%), along with trace amounts of cis-4-$C_{12:1}$ and cis-4-$C_{16:1}$.

가용매분해반응에 대한 압력의 영향(Ⅱ). Methyl-, Phenyl Chloroformate와 1-Adamantyl 유도체에 대한 반응 (The Effect of Pressure on the Rate of Solvolysis(Ⅱ). Reactions of Methyl-, Phenyl Chloroformate and 1-Adamantyl Derivatives)

  • 권오천;김정림;경진범;이영훈;김종철
    • 대한화학회지
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    • 제40권5호
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    • pp.327-332
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    • 1996
  • 이성분혼합용매내에서 Methyl-, Phenyl Chloroformate와 1-adamantyl 유도체들의 가용매분해반응속도를 여러 온도와 압력하에서 전도도방법에 의하여 측정하였다. 이들 속도상수로부터 활성화 부피(${\Delta}V_o^{\neq}$), 활성화 엔탈피(${Delta}H^{\neq}$), 활성화 엔크로피 (${\Delta}S^{\neq}$) 값을 구하였다. 이때 모든 혼합물내에서 ${\Delta}V_o^{\neq}$${\Delta}V_s^{\neq}$는 음의 값을 나타내었으며, ${\Delta}H^{\neq}$는 양의 값을 얻었다. 이 현상을 용매구조변화에 대하여 논의하였다. 또한 활성화 부피와 활성화 엔트로피 값들을 플로트하여 본 반응에 대한 반응 경향성을 조사하였다. 이들 결과로부터 Methyl-, Phenyl Chloroformate와 1-adamantyl fluoroformate(알코올수용액)는 이분자반응이, 1-adamantyl fluoromate(TFE수용액)와 1-adamantyl tosylate는 일분자반응이 일어나는 것으로 추정할 수 있었다.

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델타 도핑한 P형 SiC막의 평가 (Characterization of Delta-Doped P-Type SiC Films)

  • 김태성;정우성;남해곤
    • 태양에너지
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    • 제10권3호
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    • pp.46-52
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    • 1990
  • P층의 정공농도를 높이기 위하여 ${\delta}$-doped P층을 갖는 새로 구상된 a-Si 태양전지를 제작하였다. ${\delta}$-doped P층은 0.1-0.5 원자층의 박막 B층과 undoped a-Si의 여러층으로 구성되어 있다. B층은 광 CVD법과 열분해기법으로 증착시켰다. ${\delta}$-doped P층 박막에 대한 구조적, 광학적 및 전기적 특성을 FTIR, AES, SIMS등을 이용하여 평가하였다. 이 연구의 결과로서는 ${\delta}$-doped P층을 갖는 태양전지에 대하여 12.5%의 에너지변환효율을 달성하였다.

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중력렌즈 사건의 측성적 시차효과 검출에 대한 연구 (Astrometric Detectability of Parallax Effect in Gravitational Microlensing Events)

  • 한정호
    • 천문학논총
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    • 제15권1호
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    • pp.15-19
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    • 2000
  • The lens mass determined from the photometrically obtained Einstein time scale suffers from large uncertainty due to the lens parameter degeneracy. The uncertainty can be substantially reduced if the mass is determined from the lens proper motion obtained from astrometric measurements of the source image centroid shifts, ${\delta}{\theta}_c$, by using high precision interferometers from space-based platform such as the Space Interferometry Mission (SIM), and ground-based interferometers soon available on several 8-10m class telescopes. However, for the complete resolution of the lens parameter degeneracy it is required to determine the lens parallax by measuring the parallax-induced deviations in the centroid shifts trajectory, ${\Delta}{\delta}{\theta}_c$ aloe. In this paper, we investigate the detectabilities of ${\delta}{\theta}_c$ and ${\Delta}{\delta}{\theta}_c$ by determining the distributions of the maximum centroid shifts, $f({\delta}{\theta}_{c,max})$, and the average maximum deviations, $(<{\Delta}{\delta}_{c,max}>)$, for different types of Galactic microlensing events caused by various masses. From this investigation, we find that as long as source stars are bright enough for astrometric observations it is expected that $f({\delta}{\theta}_c)$ for most events caused by lenses with masses greater than 0.1 $M_\bigodot$ regardless of the event types can be easily detected from observations by using not only the SIM (with a detection threshold but also the ${\delta}{\theta}_{th}\;\~3{\mu}as)$ but also the ground-based interferometers $(with\;{\delta}{\theta}_{th}\;\~3{\mu}as)$. However, from ground-based observations, it will be difficult to detect ${\Delta}{\delta}{\theta}_c$ for most Galactic bulge self-lensing events, and the detection will be restricted only for small fractions of disk-bulge and halo-LMC events for which the deviations are relatively large. From observations by using the SIM, on the other hand, detecting ${\Delta}{\delta}{\theta}_c$ will be possible for majority of disk and halo events and for a substantial fraction of bulge self-lensing events. For the complete resolution of the lens parameter degeneracy, therefore, SIM observations will be essential.

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SOME EIGENFORMS OF THE LAPLACE-BELTRAMI OPERATORS IN A RIEMANNIAN SUBMERSION

  • MUTO, YOSIO
    • 대한수학회지
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    • 제15권1호
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    • pp.39-57
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    • 1978
  • It is given in the Lecture Note [1] of Berger, Gauduchon and Mazet that, if ${\pi}$n: (${\tilde{M}}$, ${\tilde{g}}$)${\rightarrow}$(${\tilde{M}}$, ${\tilde{g}}$) is a Riemannian submersion with totally geodesic fibers, ${\Delta}$ and ${\tilde{\Delta}}$ are Laplace operators on (${\tilde{M}}$, ${\tilde{g}}$) and (M, g) respectively and f is an eigenfunction of ${\Delta}$, then its lift $f^L$ is also an eigenfunction of ${\tilde{\Delta}}$ with the common eigenvalue. But such a simple relation does not hold for an eigenform of the Laplace-Beltrami operator ${\Delta}=d{\delta}+{\delta}d$. If ${\omega}$ is an eigenform of ${\Delta}$ and ${\omega}^L$ is the horizontal lift of ${\omega}$, ${\omega}^L$ is not in genera an eigenform of the Laplace-Beltrami operator ${\tilde{\Delta}}$ of (${\tilde{M}}$, ${\tilde{g}}$). The present author has obtained a set of formulas which gives the relation between ${\tilde{\Delta}}{\omega}^L$ and ${\Delta}{\omega}$ in another paper [7]. In the present paper a Sasakian submersion is treated. A Sasakian manifold (${\tilde{M}}$, ${\tilde{g}}$, ${\tilde{\xi}}$) considered in this paper is such a one which admits a Riemannian submersion where the base manifold is a Kaehler manifold (M, g, J) and the fibers are geodesics generated by the unit Killing vector field ${\tilde{\xi}}$. Then the submersion is called a Sasakian submersion. If ${\omega}$ is a eigenform of ${\Delta}$ on (M, g, J) and its lift ${\omega}^L$ is an eigenform of ${\tilde{\Delta}}$ on (${\tilde{M}}$, ${\tilde{g}}$, ${\tilde{\xi}}$), then ${\omega}$ is called an eigenform of the first kind. We define a relative eigenform of ${\tilde{\Delta}}$. If the lift ${\omega}^L$ of an eigenform ${\omega}$ of ${\Delta}$ is a relative eigenform of ${\tilde{\Delta}}$ we call ${\omega}$ an eigenform of the second kind. Such objects are studied.

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Clamping Voltage Characteristics and Accelerated Aging Behavior of CoCrTb-doped Zn/Pr-based Varistors with Sintering Temperature

  • Nahm, Ghoon-Woo
    • Transactions on Electrical and Electronic Materials
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    • 제10권4호
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    • pp.125-130
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    • 2009
  • The clamping voltage characteristics and accelerated aging behavior of CoCrTb-doped Zn/Pr-based varistors were investigated for different sintering temperatures. The best clamping voltage characteristics were obtained for the varistors sintered at $1330^{\circ}C$, with a clamping voltage ratio (K) of 1.63 at a surge current of 5 A and 1.75 at a surge current of 10 A. The varistors sintered at $1330^{\circ}C$ exhibited the highest stability, with -0.1% in $%{\Delta}E_{1\;mA}$, -0.2% in $%{\Delta}{\alpha}$, and +15.5% in $%{\Delta}J_L$ for E-J characteristics under a stress state of 0.90 $E_{1\;mA/120^{\circ}C$ /24 h. Furthermore, it exhibited $%{\Delta}{\varepsilon}_{APP}$' of -0.7% and $%{\Delta}tan{\delta}$ of +5.7% for dielectric characteristics under the same stress state.

Delta Moves and Arrow Polynomials of Virtual Knots

  • Jeong, Myeong-Ju;Park, Chan-Young
    • Kyungpook Mathematical Journal
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    • 제58권1호
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    • pp.183-202
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    • 2018
  • ${\Delta}-moves$ are closely related with a Vassiliev invariant of degree 2. For classical knots, M. Okada showed that the second coefficients of the Conway polynomials of two knots differ by 1 if the two knots are related by a single ${\Delta}-move$. The first author extended the Okada's result for virtual knots by using a Vassiliev invariant of virtual knots of type 2 which is induced from the Kauffman polynomial of a virtual knot. The arrow polynomial is a generalization of the Kauffman polynomial. We will generalize this result by using Vassiliev invariants of type 2 induced from the arrow polynomial of a virtual knot and give a lower bound for the number of ${\Delta}-moves$ transforming $K_1$ to $K_2$ if two virtual knots $K_1$ and $K_2$ are related by a finite sequence of ${\Delta}-moves$.

미세균열의 길이 및 간격 분포를 이용한 결의 평가(2) (Evaluation for Rock Cleavage Using Distribution of Microcrack Lengths and Spacings (2))

  • 박덕원
    • 암석학회지
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    • 제27권1호
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    • pp.1-15
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    • 2018
  • 미세균열의 길이와 간격의 분포를 이용하여 쥬라기 거창화강암의 결의 특성을 분석하였다. 여섯 방향의 결에 대한 길이 및 간격-누적빈도 도표를 미세균열의 길이의 밀도(${\rho}$)가 증가하는 순(($H2{\rightarrow}R1$)으로 배열하였다. 상기 두 유형의 도표의 결합을 통하여 다양한 파라미터를 추출하였다. 여섯 방향의 결에 대한 평가는 (I) 교차각(${\alpha}-{\beta}$), 지수차(${\lambda}_S-{\lambda}_L$), 선의 길이(ol 및 ll'), 길이 비(ol/os 및 ll'/sl'), 평균 길이((ss'+ll')/2), 직각삼각형의 면적(${\Delta}oaa_a^{\prime}$${\Delta}obb_a^{\prime}$) 그리고 면적차(${\Delta}obb^{\prime}-{\Delta}oaa^{\prime}$${\Delta}obb_a^{\prime}-{\Delta}oaa_a^{\prime}$), (II) 선의 길이(oa 및 os) 그리고 면적(${\Delta}oaa^{\prime}$), (III) 선의 길이(sl') 및 길이 비(ss'/ll') 그리고 (IV) 선의 길이(ob, ss' 및 ls') 및 면적(${\Delta}obb^{\prime}$, ${\Delta}ll^{\prime}s^{\prime}$, ${\Delta}ss^{\prime}l^{\prime}$ 및 ⏢ll'ss')과 같은 4개 그룹(I~IV)의 파라미터를 이용하여 수행하였다. 3개 결 및 3개 면에 대한 파라미터의 값 사이의 상관성 분석의 결과는 다음과 같다. 3개 결에 대한 파라미터의 값은 (I) H(3번 결, (H1 + H2)/2) < G(2번 결, (G1 + G2)/2) < R(1번 결, (R1 + R2)/2), (II) R < G < H, (III) G < H < R 및 (IV) H < G < R의 순서이다. 반면에, 3개 면에 대한 파라미터의 값은 (I) R' < G' < H', (II) H' < G' < R' 및 (III 및 IV) R' < H' < G'의 순서이다. 특히, 그룹 I 및 그룹 II에 속하는 파라미터의 값은 상호 역순을 보여준다. 결론적으로, 이러한 유형의 상관성 분석은 3개 채석면의 판별에 유용하다.

Cone Beam Computed Tomography의 두부계측분석을 통한 골격성 제3급 부정교합 환자에서 악교정 수술 후 입술과 주위 연조직의 수직적 변화 (The Vertical Changes of Lip and Perioral Soft Tissue Following Orthognathic Surgery in Skeletal Class III Patients by a Cephalometric Analysis of Cone Beam Computed Tomography)

  • 이종민;강주완;이종호;김창현;박재억
    • Maxillofacial Plastic and Reconstructive Surgery
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    • 제34권5호
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    • pp.311-319
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    • 2012
  • Purpose: The aim of this study is to evaluate the vertical changes of the lip and perioral soft tissue, following orthognathic surgery in skeletal class III patients by a cephalometric analysis of a cone beam computed tomography (CBCT). Methods: A total of 20 skeletal class III patients, who had bimaxillary surgery with Le Fort 1 osteotomy and bilateral sagittal split ramus osteotomy, were included in this study. The surgical plan for maxilla was posterosuperior impaction with the anterior nasal spine, as the rotation center. Further, the surgical plan for mandible was also posterosuperior movement. The soft tissue changes between lateral cephalogram and CBCT were compared. And the correlations between independent variables and dependent variables were evaluated. Results: There were no significant differences of the soft tissues changes between lateral cephalogram and CBCT. Upper lip philtrum length (SnLs), nasolabial angle increased and upper lip vermilion length (LsStms), lower lip length (StmiB'), lower lip vermilion length (StmiLi), lower lip philtrum length (LiB') and soft tissue lower facial height (SnMe') decreased after surgery. Change of SnLs (${\Delta}$SnLs) was influenced by vertical change of menton (${\Delta}$MeV), and change of LsStms (${\Delta}$LsStms) was influenced by upper lip thickness (ULT). Change of StmiLi' (${\Delta}$StmiLi') were influenced by preoperative overjet. Change of StmiB' (${\Delta}$StmiB') were influenced by preoperative overjet, vertical change of lower incisor (${\Delta}$L1V) and horizontal change of posterior nasal spine (${\Delta}$PNSH). Change of LiB' (${\Delta}$LiB') was influenced by ${\Delta}$L1V and ${\Delta}$PNSH. Change of SnMe' (${\Delta}$SnMe') was influenced by ${\Delta}$MeV, horizontal change of upper incisor (${\Delta}$U1H) and horizontal change of lower incisor (${\Delta}$L1H). ${\Delta}$Nasolabial angle was influenced by change of ULT (${\Delta}$ULT). Conclusion: Both soft tissues and hard tissues can be evaluated by CBCT. Posterosuperior rotation of maxillomandibular complex resulted in increase of upper lip philtrum length and nasolabial angle, while the upper lip vermilion length, lower lip philtrum length, lower lip vermilion length, and soft tissue lower facial height showed a decrease.

Band gap control by tri-block nanoribbon structure of graphene and h-BN

  • 이지우;정가운
    • EDISON SW 활용 경진대회 논문집
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    • 제4회(2015년)
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    • pp.324-329
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    • 2015
  • First-principles investigations on the hybrid one dementional hexagonal hybrboron-nitride nano ribbons (BNNRs) with a armchair graphene nano-ribbons(AGRNRs), are presented. Electronics properties of the mixed armchair BNC nano-ribbon (BNCNRs) structure show control of a band gap on all cases at the special K-point. And we have studied, the band gap is direct in all cases. The band gap of mixed ABNCNRs could be divided into three groups (${\Delta}3p$, ${\Delta}3p+1$ and ${\Delta}3p+2$) and decrease with the increase of the width. Also these results show similar to the AGNRs case. Different from the band gap value ordering of AGNRs (${\Delta}3p+1$ > ${\Delta}3p$ > ${\Delta}3p+2$), the ordering of ABNCNRs is ${\Delta}3p$ > ${\Delta}3p+1$ > ${\Delta}3p+2$. The discrepancy may come from the differences between the edges of AGRNRs and the boundaries of hybrid BNCNRs. In addition, the bandgap of ABNCNRs are much smaller than those of the corresponding AGNRs. Our results show that the origin of band gap for BNCNRs with armchair shaped edges arises from both quantum confinement effect of the edges. These results similar to thecase of AGNRs. These properties of hybrid BN/C nano-ribbon structure may offer suitable bandgap to develop nnanoscale electronics and solar cell beyond individual GNRs and BNNRs.

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