• Korean Journal of Materials Research
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• v.22 no.11
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• pp.620-625
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• 2012

A general synthetic method to make $Fe_3O_{4-{\delta}}$ (activated magnetite) is the reduction of $Fe_3O_4$ by $H_2$ atmosphere. However, this process has an explosion risk. Therefore, we studied the process of synthesis of $Fe_3O_{4-{\delta}}$ depending on heat-treatment conditions using $FeC_2O_4{\cdot}2H_2O$ in Ar atmosphere. The thermal decomposition characteristics of $FeC_2O_4{\cdot}2H_2O$ and the ${\delta}$-value of $Fe_3O_{4-{\delta}}$ were analyzed with TG/DTA in Ar atmosphere. ${\beta}-FeC_2O_4{\cdot}2H_2O$ was synthesized by precipitation method using $FeSO_4{\cdot}7H_2O$ and $(NH_4)_2C_2O_4{\cdot}H_2O$. The concentration of the solution was 0.1 M and the equivalent ratio was 1.0. ${\beta}-FeC_2O_4{\cdot}2H_2O$ was decomposed to $H_2O$ and $FeC_2O$4 from $150^{\circ}C$ to $200^{\circ}C$. $FeC_2O4$ was decomposed to CO, $CO_2$, and $Fe_3O_4$ from $200^{\circ}C$ to $250^{\circ}C$. Single phase $Fe_3O_4$ was formed by the decomposition of ${\beta}-FeC_2O_4{\cdot}2H_2O$ in Ar atmosphere. However, $Fe_3C$, Fe and $Fe_4N$ were formed as minor phases when ${\beta}-FeC_2O_4{\cdot}2H_2O$ was decomposed in $N_2$ atmosphere. Then, $Fe_3O_4$ was reduced to $Fe_3O_{4-{\delta}}$ by decomposion of CO. The reduction of $Fe_3O_4$ to $Fe_3O_{4-{\delta}}$ progressed from $320^{\circ}C$ to $400^{\circ}C$; the reaction was exothermic. The degree of exothermal reaction was varied with heat treatment temperature, heating rate, Ar flow rate, and holding time. The ${\delta}$-value of $Fe_3O_{4-{\delta}}$ was greatly influenced by the heat treatment temperature and the heating rate. However, Ar flow rate and holding time had a minor effect on ${\delta}$-value.

• Journal of the Korean Geotechnical Society
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• v.22 no.8
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• pp.77-88
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• 2006

In this study, the lateral behavior of Pile-Bent structures subjected to lateral loading was evaluated by a load-transfer approach. An analytical method based on the Beam-Column model and nonlinear load transfer curve method was proposed to consider material non-linearity (elastic and yielding) and $P-{\Delta}$ effect. Special attention was given to the lateral deflection of Pile-Bent structures depending on different soil properties, lateral load, slenderness ratio based on pier length and reinforcing effect of casing. From the results of the parametric study, it is shown that the increase of lateral displacement in a pile is much less favorable for an inelastic analysis than for an elastic analysis. It is found that for inelastic analysis, the maximum bending moment is located within a depth approximately 3.5D(D: pile diameter) below ground surface, but within 1.5D when $P-{\Delta}$ effect is considered. It is also found that the magnitude and distribution of the lateral deflections and bending moments on a pile are highly influenced by the inelastic analysis and $P-{\Delta}$ effect, let alone soil properties around an embedded pile.

• Journal of Welding and Joining
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• v.15 no.4
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• pp.178-186
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• 1997

The purpose of this study is to evaluate the J-R curve characteristics for the 5083 aluminum alloy weldment by the load ratio analysis. The results of the load ratio analysis are compared with those of the J-R curve which are obtained by the ASTM unloading compliance method. The crack length calculated by the load ratio analysis is agrees well with the measured final crack length. The slope of the exponential J-R curve estimated by the load ratio analysis is slightly smaller than that by the ASTM unloading compliance method. The exponential correlation of the J-R curve for the 5083 aluminum alloy base metal by the load ratio analysis is J = 93.88 ${\Delta}{\alpha}^{0.375}$. That for the weld metal and HAZ is J = 69.87 ${\Delta}{\alpha}^{0.389}$ and J = 70.59 ${\Delta}{\alpha}^{0.359}$ respectively. The J-R curve obtained by the ASTM unloading compliance method is overpredicted and should be offsetted due to the initial negative crack. On the other hand, the load ratio analysis method can evaluate the J-R curve by only load displacement curve without particular crack measurement equipment.

• Phonetics and Speech Sciences
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• v.1 no.4
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• pp.127-132
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• 2009

The feature vectors which are used in conventional speaker recognition (SR) systems may have many correlations between their neighbors. To improve the performance of the SR, many researchers adopted linear transformation method like principal component analysis (PCA). In general, the linear transformation of the feature vectors is based on concatenated form of the static features and their dynamic features. However, the linear transformation which based on both the static features and their dynamic features is more complex than that based on the static features alone due to the high order of the features. To overcome these problems, we propose an efficient method that applies linear transformation and temporal information of the features to reduce complexity and improve the performance in speaker verification (SV). The proposed method first performs a linear transformation by PCA coefficients. The delta parameters for temporal information are then obtained from the transformed features. The proposed method only requires 1/4 in the size of the covariance matrix compared with adding the static and their dynamic features for PCA coefficients. Also, the delta parameters are extracted from the linearly transformed features after the reduction of dimension in the static features. Compared with the PCA and conventional methods in terms of equal error rate (EER) in SV, the proposed method shows better performance while requiring less storage space and complexity.

• Journal of the Institute of Convergence Signal Processing
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• v.8 no.3
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• pp.222-226
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• 2007

In this paper we composed the dual fuzzy rules using each region of specific points and $e-{\Delta}e$ phase plane In order to make dual fuzzy rule base. We composed the fuzzy control rules which can decrease rise time, delay time, maximum overshoot than basic fuzzy control rules. proposed method is alternately use at specific points of $e-{\Delta}e$ phase plane with two fuzzy control rules that is one control rule occruing the steady state error in transient region and another fuzzy control rule use to decrease the steady state error and rapidly converge at the convergence region. Also, two fuzzy control rules in the $e-{\Delta}e$ phase plane decide the change time according to response characteristics of plants. In order to confirm thef proposed algorithm. As the results of experiments through the hydraulic servo motor control system with a DSP processor, We verified that proposed dual fuzzy control rules get the good response compare with the basic fuzzy control rule.

• Journal of the Korean Chemical Society
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• v.40 no.5
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• pp.327-332
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• 1996

The rates of solvolylsis of methyl chloroformate, phenyl chloroformate and 1-adamantyl derivatives in binary solvent mixtures have been measured by conductometric method at various temperatures and pressures. The activation parameters were estimated from the rate constants. The activation volume (${\Delta}V_o^{\neq}$) and the activation entropy (${\Delta}S^{\neq}$) are both negative, but the activation enthalpy (${\Delta}H^{\neq}$) is positive. This behavior is discussed in terms of electrostriction of solvation. The reactivities of these reactions were also estimated from the correlation of the activation volumes with the activation entropies. From these results, it could be estimated that the solvolyses of 1-adamantyl fluoroformate (in aqueous TFE) and 1-adamantyl tosylate have pathway involving unimolecular reaction, while the reaction of methyl chloroformate, phenyl chloroformate and 1-adamantyl fluoroformate (in aqueous alcohol) proceed through a bimolecular reaction.

• Journal of the Earthquake Engineering Society of Korea
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• v.5 no.4
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• pp.17-26
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• 2001

In order to estimate peak ground motions and frequency characteristics of strong ground motions in southern korea, we employed the stochastic simulation method with the moment magnitude(M$_{w}$) and the hypocentral distance(R). We estimated same input parameters that account for specific properties of source and propagation processes, and applied them to the stochastic simulation method. The stress drop($\Delta$$\sigma$) of 100-bar was estimated considering results of research in ENA, China, and southern korea. The attenuation parameter x was calculated by analyzing 57 seismograms recorded from September 1996 to October 1997 and the estimation result of the attenuation parameter x is 0.00112+0.000224 R where R is hypocenter distance. We estimated strong ground motion relations using the stochastic simulation method with suitable input parameters(e.g. $\Delta$$\sigma$, x, and so on). At last, we derived relations between hypocentral distances and ground motions(seismic attenuation equation) using results of the stochastic prediction.esults of the stochastic prediction.n.

• Proceedings of the KSME Conference
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• 2000.04a
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• pp.43-48
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• 2000

In this study, a small punch creep(SP-Creep) test using miniaturized specimen$(10{\times}10{\times}0.5mm)$ has been described for the development of the newly semi-destructive creep test method for high temperature structural components such as headers and tubes of boiler turbine casino and rotor and reactor vessel. The SP-Creep testing technique has been applied to 2.25Cr-1Mo(STBA24) steel used widely as boiler tube material and the creep test temperature are varied at $550^{\circ}C{\sim}600^{\circ}C$. The overall deformations of SP-Creep curves are definitely depended with applied load and creep test temperature and show the creep behaviors of three steps like conventional uniaxial creep curves. The steady state creep rate${\delta}_{ss}$ of SP-Creep curve for miniaturized specimen increases with increasing creep temperature, but the exponential value with creep loading is decreased. The activation energy$(Q_{spc})$ during SP-Creep deformation with various test temperatures shows 605.7kJ/mol that is g.eater than 467.4kJ/mol reported in uniaxial creep test. This may be caused by the difference of stress states during creep deformation In two creep test. But from the experimental results, e.g. SP-Creep curve behaviors, the steady state creep rate${\delta}_{ss}$ with creep temperature, and the exponential value(n) with creep loading, it can be summarized that the SP-Creep test may be a useful test method to evaluate the creep properties of the heat resisting material.

• Journal of the Korean Mathematical Society
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• v.35 no.2
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• pp.465-490
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• 1998

In this paper, we consider the existence and asymptotic behavior of solutions of the following problem: $u_{tt}$ -(t, x) - (∥∇u(t, x)∥(equation omitted) ＋ ∥∇v(t, x) (equation omitted)$^{\gamma}$ $\Delta$u(t, x)＋$\delta$│ $u_{t}$ (t, x)│sup p-1/ $u_{t}$ (t, x) = $\mu$│u(t, x) $^{q-1}$u(t, x), x$\in$$\Omega$, t$\in$[0, T], $v_{tt}$ (t, x) - (∥∇uu(t, x) (equation omitted) ＋ ∥∇v(t, x) (equation omitted)sup ${\gamma}$/ $\Delta$v(t, x)＋$\delta$ │ $v_{t}$ (t, x)│sup p-1/ $u_{t}$ (t, x) = $\mu$ u(t, x) $^{q-1}$u(t, x), x$\in$$\Omega$, t$\in$[0, T], u(0, x) = $u_{0}$ (x), $u_{t}$ (0, x) = $u_1$(x), x$\in$$\Omega$, u(0, x) = $v_{0}$ (x), $v_{t}$ (0, x) = $v_1$(x), x$\in$$\Omega$, u│∂$\Omega$=v│∂$\Omega$=0 T > 0, q > 1, p $\geq$1, $\delta$ > 0, $\mu$ $\in$ R, ${\gamma}$ $\geq$ 1 and $\Delta$ is the Laplacian in $R^{N}$.X> N/.

• Proceedings of the Korean Institute of Intelligent Systems Conference
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• 2003.09b
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• pp.71-75
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• 2003

오류 역전파 학습 알고리즘을 이용하여 영상 인식에 적용 할 경우에는 은닉층의 노드 수를 경험적으로 설정하므로, 학습시간과 지역최소화 및 정체현상이 발생한다. 그리고 ARTI 알고리즘은 입력 패턴과 저장 패턴간의 측정 방법인 유사성 검증 방법과 경계 변수의 설정에 따라 인식률이 좌우된다. 경계 변수의 값이 크면 입력 패턴과 저장 패턴사이에 약간의 차이만 있어도 새로운 카테고리(Category)로 분류하고, 반대로 경계 변수의 값이 적으면 입력 패턴과 저장 패턴 사이에 많은 차이가 있더라도 유사성이 인정되어 입력 패턴들을 대략적으로 분류한다. 따라서 ART1 알고리즘을 영상 인식에 적용하기 위해서는 경계 변수를 경험적으로 설정하므로 인식률에 부정적인 영향을 갖는 문제점이 있다. 따라서 본 논문에서는 개선된 ART1 알고리즘과 지도 학습 방법을 결합하여 신경망의 은닉층 노드를 동적으로 변화시키는 자가 생성지도 학습 알고리즘을 제안한다. 제안된 신경망에서 입력층과 은닉층의 학습 구조에는 ART1 알고리즘을 개선하여 적용하고, 은닉층과 출력층의 학습 구조에는 은닉층에서 승자로 선택된 노드와 출력층 노드와 연결된 가중치만을 조정하고 Delta-Bar-Delta 알고리즘을 적용한다. 제안된 방법의 학습 성능을 분석하기 위하여 학생증 영상에서 추출한 학번 패턴 분류에 적용한 결과, 기존의 신경망 학습 알고리즘보다 학습 성능이 개선됨을 확인하였다.