• Title/Summary/Keyword: Degree of conversion

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A Numerical Study on the Effect of Inlet Guide Vane Angle on the Performance of Francis Hydraulic Turbine

  • Kim Chul-Ho
    • Journal of Advanced Marine Engineering and Technology
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    • v.29 no.7
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    • pp.750-757
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    • 2005
  • The objective of this study is an understanding of the effect of inlet flow angle on the output power performance of a Francis hydraulic turbine, An optimum induced angle at the inlet of the turbine is one of the most important design parameters to have the best performance of the turbine at a given operating condition, In general. rotating speed of the turbine is varied with the change of water mass flowrate in a volute, The induced angle of the inlet water should be properly adjusted to the operating condition to have maximum energy conversion efficiency of the turbine, In this study. a numerical simulation was conducted to have detail understanding of the flow phenomenon in the flow path and output power of the model Francis turbine. The indicated power produced by the model turbine at a given operating condition was found numerically and compared to the brake power of the turbine measured by experiment at KIER. From comparison of two results, turbine efficiency or energy conversion efficiency of the model turbine was estimated. From the study, it was found that the rotating power of the turbine linearly increased with the rotating speed. It means that the higher volume flow rate supplied. the bigger torque on the turbine shaft generated. The maximum brake efficiency of the turbine is around 46$\%$ at 35 degree of induced angle. The difference between numerical and experimental output of the model turbine is defined as mechanical efficiency. The maximum mechanical efficiency of the turbine is around 93$\%$ at 25$\∼$30 degree of induced angle.

The effects of dentin bonding agent formulas on their polymerization quality, and together with tooth tissues on their microleakage and shear bond strength: an explorative 3-step experiment

  • Erfan, Mohmmad;Jafarzadeh-Kashi, Tahereh Sadat;Ghadiri, Malihe;Rakhshan, Vahid
    • The Journal of Advanced Prosthodontics
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    • v.6 no.5
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    • pp.333-345
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    • 2014
  • PURPOSE. Bonding agents (BA) are the crucial weak link of composite restorations. Since the commercial materials' compositions are not disclosed, studies to formulize the optimum ratios of different components are of value. The aim of this study was to find a proper formula of BAs. MATERIALS AND METHODS. This explorative experimental in vitro study was composed of 4 different sets of extensive experiments. A commercial BA and 7 experimental formulas were compared in terms of degree of conversion (5 experimental formulas), shear bond strength, mode of failure, and microleakage (3 experimental formulas). Statistical analyses were performed (${\alpha}$=.05). The DC of selected formula was tested one year later. RESULTS. The two-way ANOVA indicated a significant difference between the shear bond strength (SBS) of two tissues (dentin vs. enamel, P=.0001) in a way that dentinal bonds were weaker. However, there was no difference between the four materials (P=.283). The adhesive mode of failure was predominant in all groups. No differences between the microleakage of the four materials at occlusal (P=.788) or gingival (P=.508) sites were detected (Kruskal-Wallis). The Mann-Whitney U test showed a significant difference between the microleakage of all materials (3 experimental formulas and a commercial material) together at the occlusal site versus the gingival site (P=.041). CONCLUSION. A formula with 62% bisphenol A-glycidyl methacrylate (Bis-GMA), 37% hydroxy ethyl methacrylate (HEMA), 0.3% camphorquinone (CQ), and 0.7% dimethyl-para-toluidine (DMPT) seems a proper formula for mass production. The microleakage and SBS might be respectively higher and lower on dentin compared to enamel.

Effects of radiant exposure and wavelength spectrum of light-curing units on chemical and physical properties of resin cements

  • Lima, Adriano Fonseca;Formaggio, Stephanie Ellen Ferreira;Zambelli, Ligia Franca Aires;Palialol, Alan Rodrigo Muniz;Marchi, Giselle Maria;Saraceni, Cintia Helena Coury;de Oliveira, Marcelo Tavares
    • Restorative Dentistry and Endodontics
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    • v.41 no.4
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    • pp.271-277
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    • 2016
  • Objectives: In this study, we evaluated the influence of different radiant exposures provided by single-peak and polywave light-curing units (LCUs) on the degree of conversion (DC) and the mechanical properties of resin cements. Materials and Methods: Six experimental groups were established for each cement (RelyX ARC, 3M ESPE; LuxaCore Dual, Ivoclar Vivadent; Variolink, DMG), according to the different radiant exposures (5, 10, and $20J/cm^2$) and two LCUs (single-peak and polywave). The specimens were made (7 mm in length ${\times}$ 2 mm in width ${\times}$ 1 mm in height) using silicone molds. After 24 hours of preparation, DC measurement was performed using Fourier transform infrared spectrometry. The same specimens were used for the evaluation of mechanical properties (flexural strength, FS; elastic modulus, E) by a three-point bending test. Data were assessed for normality, after which two-way analysis of variance (ANOVA) and post hoc Tukey's test were performed. Results: No properties of the Variolink cement were influenced by any of the considered experimental conditions. In the case of the RelyX ARC cement, DC was higher when polywave LCU was used; FS and E were not influenced by the conditions evaluated. The LuxaCore cement showed greater sensitivity to the different protocols. Conclusions: On the basis of these results, both the spectrum of light emitted and the radiant exposure used could affect the properties of resin cements. However, the influence was material-dependent.

The effect of light sources and CAD/CAM monolithic blocks on degree of conversion of cement

  • Cetindemir, Aydan Boztuna;Sermet, Bulent;Ongul, Deger
    • The Journal of Advanced Prosthodontics
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    • v.10 no.4
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    • pp.291-299
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    • 2018
  • PURPOSE. To assess the degree of conversion (DC) and light irradiance delivered to light-cured and dual-cured cements by application of different light sources through various types of monolithic computer-aided design and computer-aided manufacturing (CAD/CAM) materials. MATERIALS AND METHODS. RelyX Ultimate Clicker light-cured and dual-cured resin cement specimens with 1.5-mm thicknesses (n=300, 10/group), were placed under four types of crystalline core structure (Vita Enamic, Vita Suprinity, GC Ceresmart, Degudent Prettau Anterior). The specimens were irradiated for 40 seconds with an LED Soft-Start or pulse-delay unit or 20 seconds with a QTH unit. DC ratios were determined by using Fourier transform infrared spectroscopy (FTIR) after curing the specimen at 1 day and 1 month. The data were analyzed using the Mann-Whitney U test (for paired comparison) and the Kruskal-Wallis H test (for multiple comparison), with a significance level of P<.05. RESULTS. DC values were the highest for RelyX Ultimate Clicker light-cure specimens polymerized with the LED Soft-Start unit. The combination of the Vita Suprinity disc and RelyX Ultimate Clicker dual-cure resin cement yielded significantly higher values at both timepoints with all light units (all, P<.05). CONCLUSION. Within the limitations of this study, we conclude that the DC of RelyX Ultimate Clicker dual-cure resin cement was improved significantly by the use of Vita Suprinity and the LED Soft-Start light unit. We strongly recommend the combined use of an LED light unit and dual-cure luting cement for monolithic ceramic restorations.

Synthesis of High Molecular Weight Poly(vinyl alcohol) by Low Temperature Polymerization of Vinyl Acetate in Tertiary Butyl Alcohol and the Following Saponification (아세트산비닐의 삼차부틸알코올계 저온 중합 및 비누화에 의한 고분자량 폴리비닐알코올의 합성)

  • 류원석;한성수;최진현;유상우;홍성일
    • Polymer(Korea)
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    • v.24 no.5
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    • pp.610-620
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    • 2000
  • Vinyl acetate (VAc) was polymerized at 30, 40, and 5$0^{\circ}C$ using 2,2'-azobis (2,4-dimethylvaleronitrile) (ADMVN) and tertiary butyl alcohol (TBA) as the initiator and the solvent, respectively. High molecular weight (HMW) atactic poly(vinyl alcohol) (PVA) was prepared by saponifying the poly(vinyl acetate) (PVAc) synthesized. The effect of polymerization conditions were investigated in terms of conversion, degree of branching for acetyl group of PVAc, and molecular weight of both PVAc and PVA. The polymerization rate of VAc in TBA was proportional to the 0.49th power of ADMVN concentration in good accordance with the theoretical value of 0.5. HMW-PVA with high yield could be obtained successfully, probably due to lower polymerization temperature and decreased chain transfer reaction rate which was achieved by adopting ADMVN and TBA. PYAc having average degree of polymerization (P$_{n}$) of 10000~13000 was obtained at the conversion of 35~70%. Saponification of so prepared PVAc yielded PVA having P$_{n}$ of 2400~6100. The syndiotactic diad content increased with decreasing polymerization temperature and increasing VAc concentration due to a steric hindrance effect of TBA during polymerization.

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The polymerization efficiency of a bulk-fill composite based on matrix-modification technology

  • Elshazly, Tarek M.;Bourauel, Christoph;Aboushelib, Moustafa N.;Sherief, Dalia I.;El-Korashy, Dalia I.
    • Restorative Dentistry and Endodontics
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    • v.45 no.3
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    • pp.32.1-32.12
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    • 2020
  • Objectives: To evaluate the polymerization efficiency of a matrix-modified bulk-fill composite, and compare it to a conventional composite which has a similar filler system. The degree of conversion (DC%) and monomer elution were measured over different storage periods. Additionally, fillers' content was examined. Materials and Methods: Cylindrical specimens were prepared, in bulk and incrementally, from Filtek Bulk Fill (B) and Filtek Supreme XTE (S) composites using a Teflon mold, for each test (n = 6). Using attenuated total reflection method of Fourier transformation infrared spectroscopy, DC% was measured after 24 hours, 7 days, and 30 days. Using high-performance liquid chromatography, elution of hydroxyethyl methacrylate, triethylene glycol dimethacrylate, urethane dimethacrylate, and bisphenol-A glycidyl dimethacrylate was measured after 24 hours, 7 days and 30 days. Filler content was examined by scanning electron microscopy (SEM). Data were analyzed using 2-way mixed-model analysis of variance (α = 0.05). Results: There was no significant difference in DC% over different storage periods between B-bulk and S-incremental. Higher monomer elution was detected significantly from S than B. The elution quantity and rate varied significantly over storage periods and between different monomers. SEM images showed differences in fillers' sizes and agglomeration between both materials. Conclusions: Matrix-modified bulk-fill composites could be packed and cured in bulk with polymerization efficiency similar to conventional composites.

A Study of Direction of VR Animation <Goodbye Mr Octopus> (VR애니메이션 <Goodbye Mr Octopus> 연출 연구)

  • Lee, TaeGu;Park, Sukyung
    • The Journal of the Convergence on Culture Technology
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    • v.9 no.1
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    • pp.135-140
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    • 2023
  • VR animation allows you to see 360-degree screen production that cannot be seen in existing animation production while being located in the space within the animation. <Goodbye Mr Octopus>, a VR animation produced in 2020, was selected at the 77th Venice Film Festival as an immersive short film. This is the story of an adolescent girl, Stella, who is celebrating her 16th birthday, and her conflict with her strict father is resolved through a letter from her mother. It is a narrative composed of a total of 11 scenes, and in each scene, new directing elements of VR video grammar, such as gaze induction, time flow, and space conversion directing, were analyzed. Gaze-inducing directing minimized the inconvenience of 360-degree gaze, and time and space conversion directing was analyzed as an effect of increasing the audience's immersion according to narrative events.

A Study on Synthesis and Hydrolysis of the Maleated Polyethylene Wax (무수말레인산으로 그라프트된 폴리에틸렌 왁스의 중합과 가수분해에 대한 연구)

  • Yu, Si-Won;Choi, Joong-So;Na, Jae-Sik
    • Clean Technology
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    • v.19 no.4
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    • pp.393-400
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    • 2013
  • In this study, Polyethylene wax, which was produced in manufacturing process of high density polyethylene was grafted with maleic anhydride (MAH). The influences of reaction parameters on the graft polymerization as well as the effect of hydrolysis of the anhydride functions were investigated. The results show that the grafting degree increased and conversion of maleic anhydride decreased with an increase in MAH monomer content. This means the highest grafting efficiency for the reaction can be met when MAH monomer content is about 15 wt%. DCP (dicumyl peroxide) and DTBP (di-tert-butyl peroxide) have been used as the initiator and the highest yield of grafting was obtained when the initiator content is about 0.5 wt%. However, It can be seen that the gel content values of this polyethylene wax grafted MAH were below 2%. It was also observed that the grafting degree increased with an increase in reaction temperature and the maximum value was reached 2 hours later. Although MAH functions grafted onto polyethylene wax were mainly in the carboxylic acid forms, some anhydride form of MAH appeared in over 5% of grafting degree. As a result of hydrolysis reaction, it was observed that the conversion of anhydride group into carboxylic acid group was reached up to 10%.

Performance Characteristics of R744 OTEC Power Cycle with Operation Parameters (운전조건에 따른 R744용 해양온도차 발전 사이클의 성능 특성)

  • Yoon, Jung-In;Son, Chang-Hyo;Baek, Seung-Moon;Kim, Hyeon-Ju;Lee, Ho-Saeng
    • Journal of Advanced Marine Engineering and Technology
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    • v.36 no.5
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    • pp.580-585
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    • 2012
  • In this paper, the cycle performance analysis for condensation and evaporation capacity, total work and efficiency of ocean thermal energy conversion power system using R744 ($CO_2$) is presented to offer the basic design data for the operating parameters of this system. The operating parameters considered in this study include superheating and subcooling degree, evaporation and condensation temperature, pump and turbine efficiency. The main results were summarized as follows : The evaporation capacity of R744 increases with superheating and subcooling degree, but decreases with the increasing condensation temperature. The total work increases with superheating and subcooling degree of R744, but decreases with the increasing evaporating temperature. And, the efficiency increases with subcooling and superheating degree, but decreases with the increasing condensation temperature. Therefore, superheating and subcooling degree, evaporation and condensation temperature and pump and turbine efficiency of R744 OTEC power system have an effect on the evaporation and condensation capacity, total work and efficiency of this system. With a thorough grasp of these effect, it is necessary to design the OTEC power cycle using R744.

Comparison of the Mechanical Properties between Bulk-fill and Conventional Composites (Bulk-fill 복합레진과 전통적 복합레진의 물성비교)

  • Noh, Taehwan;Song, Eunju;Park, Soyoung;Pyo, Aeri;Kwon, Yonghoon;Kim, Jiyeon;Kim, Shin;Jeong, Taesung
    • Journal of the korean academy of Pediatric Dentistry
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    • v.43 no.4
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    • pp.365-373
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    • 2016
  • Composites are the most useful restorative material. However, composites have some disadvantages such as polymerization shrinkage, long working time, and susceptibility to water and contamination, which are stood out more especially when treating children. To solve these problems, bulk-fill composites have been developed. The aim of this study is to compare mechanical properties of bulk-fill and conventional composites. Bulk-fill composites (SureFil SDR flow (SDR), Tetric N-Ceram bulk fill (TBF)) and conventional composites (Filtek Z-350 (Z-350), Unifil Flow (UF), Unifil Loflo Plus (UL)) were used. The Vickers hardness tester was used to measure the microhardness of materials, and Fourier transform infrared spectroscopy was used to measure the degree of conversion. Polymerization shrinkage was measured by using a linometer. Flexural and compressive properties were measured by using the universal testing machine. Data were statistically analyzed by ANOVA and Scheffe's post hoc test. The level of significance was set to p < 0.05. Most conventional composites showed higher microhardness than bulk-fill composites. However, bulk-fill composites showed a higher top/bottom microhardness ratio than conventional composites. Bulk-fill composites showed a higher top/bottom degree of conversion ratio than conventional composites. The polymerization shrinkage was highest in UL and lowest in Z-350. The polymerization shrinkage of flowable composites was higher than that of non flowable composites. The compressive properties were highest in Z-350 and lowest in SDR and UL. In terms of flexural properties, Z-350 was the highest. However, none of the bulk-fill composites exhibited mechanical properties as good as those of conventional composites. Nonetheless, the ratio of microhardness and degree of conversion, which are important properties of bulk filling, were higher in bulk-fill composites. Therefore, the bulk-fill composites might be considered suitable restorative materials in pediatric dentistry.