• Title/Summary/Keyword: Degradation behavior

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Evaluation of Anastomotic Strength and in-vitro Degradability with Microvascular Anastomosis Coupler Based on Injection Molding Condition made by Biodegradable Polycaprolactone(PCL) (생체분해성 폴리카프로락톤(PCL) 미세혈관 문합커플러의 사출성형조건에 따른 문합강도 및 in-vitro 분해능 평가)

  • Ahn, Geun-Seon;Han, Gig-Bong;Oh, Seung-Hyun;Park, Jong-Woong;Kim, Cheol-Woong
    • Transactions of the KSME C: Technology and Education
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    • v.1 no.2
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    • pp.167-177
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    • 2013
  • The use of mechanical anastomosis coupler instead of sutures has been increasing in microvascular anastomosis surgery. However, non-biodegradable anastomosis coupler has problems such as not only inflammatory reaction but also remaining permanently in operation wound. Therefore, we fabricated biodegradable anastomosis coupler using injection molding process to overcome the limitation of non-biodegradable anastomosis coupler. In various injection molding process conditions, the shrinkage was calculated with different cylinder temperatures and injection molding pressures and anastomotic strength was measured. As a result, changes in shrinkage hole part larger than the pin part. In addition, the shrinkage in the cylinder at higher temperatures increase. However, the higher the injection pressure, shrinkage tends to decrease, respectively. In-vitro degradation behavior of PCL anastomotic coupler evaluated for 12 weeks, water uptake was increased and molecular weight was accompanied by a reduction in mass of the biological degradation and reduction of anastomotic strength was confirmed. However, decreased levels of anastomotic strength enough to exceed the requirements of preclinical surgery, PCL microvascular anastomosis coupler suitable candidate materials that could identify.

Time-dependent Reduction of Sliding Cohesion due to Rock Bridges along Discontinuities (암석 브리지에 의한 불연속면 점착강도의 시간의존성에 관한 연구)

  • 박철환;전석원
    • Tunnel and Underground Space
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    • v.14 no.3
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    • pp.167-174
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    • 2004
  • This paper is to introduce an article published in Rock Mechanics and Rock Engineering, 2003. In this research, a fracture mechanics model is developed to illustrate the importance of time-dependence far brittle fractured rock. In particular a model is developed fer the time-dependent degradation of rock joint cohesion. Degradation of joint cohesion is modeled as the time-dependent breaking of intact patches or rock bridges along the joint surface. A fracture mechanics model is developed utilizing subcritical crack growth, which results in a closed-form solution for joint cohesion as a function of time. As an example, a rock block containing rock bridges subjected to plane sliding is analyzed. The cohesion is found to continually decrease, at first slowly and then more rapidly. At a particular value of time the cohesion reduces to value that results in slope instability. A second example is given where variations in some of the material parameters are assumed. A probabilistic slope analysis is conducted, and the probability of failure as a function of time is predicted. The probability of failure is found to increase with time, from an initial value of 5% to a value at 100 years of over 40%. These examples show the importance of being able to predict the time-dependent behavior of a rock mass containing discontinuities, even for relatively short-term rock structures.

Determination of radiolysis products in Tri-Octyl Amine by high performance liquid chromatography-mass spectrometer (HPLC-MS에 의한 Tri-Octyl Amine(TOA)의 방사선 분해산물 정량)

  • Yang, Han-Beom;Lee, Eil-Hee;Moon, Hyung-Sil
    • Analytical Science and Technology
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    • v.18 no.3
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    • pp.201-205
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    • 2005
  • Tri-octyl amine (TOA) is used in solvent extraction process for radioactive waste. This compound may be degraded to di-octyl amine (DOA), mono-octyl amine (MOA) by radioactive materials. Amount of TOA, DOA and MOA in TOA must be monitored because they production of these compounds means degradation of which leads to a decrease in the extraction yield. Retention behavior for TOA, DOA and MOA are studied with Phenomenex LUNA-$C_{18}$ ($4.6mm{\times}25cm$) analytical column and $CH_3OH:H_2O$ (50 mmol $CH_3COONH_4$) eluent by liquid chromatography. Optimum condition for these compounds is $CH_3OH:H_2O$ (50 mmol $CH_3COONH_4$) = 85 : 15 ratio. TOA, DOA and MOA compounds is well separated within 20 minute. Dynamic range is $30{\sim}160{\mu}g/mL$ for TOA, $5{\sim}100{\mu}g/mL$ for DOA and $0.1{\sim}5{\mu}g/mL$ for MOA, respectively. The detection limit are $0.1{\mu}g/mL$ for TOA, $1{\mu}g/mL$ for DOA (in SCAN mode) and $0.1{\mu}g/mL$ for MOA (in SIM mode) in this system with $20{\mu}L$ sample loop.

The Effects of Thermal Degradation and Creep Damage on the Microstructure and Composition of the Carbides in the CrMo Steels for Power Plant (발전 설비용 CrMo강의 탄화물 구조와 조성 변화에 미치는 열화 및 크리프 손상의 영향)

  • Ju, Yeon-Jun;Hong, Gyeong-Tae;Lee, Hyeon-Ung;Sin, Dong-Hyeok;Kim, Je-Won
    • Korean Journal of Materials Research
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    • v.9 no.10
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    • pp.1018-1024
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    • 1999
  • The effects of operating temperature and stress on degradation of components in high temperature steam generator were investigated. Several 2.25CrlMo tubes which had operated over 20 years and an unused 9CrlMoVNb tube were tested. For the former samples, the amount of $\textrm{M}_{6}\textrm{C}$ carbide and its size are increased with the aging or operating time. The precipitation behavior of carbides ($\textrm{M}_{2}\textrm{O}$, $\textrm{M}_{6}\textrm{C}$) is changed with the operating temperature of the tubes. However, unused 9CrlMoVNb samples show a different carbide precipitation process due to high chromium, vanadium, and niobium contents. The amount of Cr-rich $\textrm{M}_{23}\textrm{C}_{6}$ carbide is significantly increased with aging time, but that of $\textrm{M}_{6}\textrm{C}$ type carbide is rarely changed with aging time at elevated temperatures.

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Effects of the High Shear Rate Processing on the Thermal Properties of PC/ABS Blends (고속 전단 가공에 의한 PC/ABS 블렌드의 열적 물성 변화 연구)

  • Lee, Hyeong Il;Lee, Han Ki;Kim, Dea Sik;Choi, Seok Jin;Kim, Seon Hong;Yoo, Jea Jung;Yong, Da Kyoung;Lee, Seung Goo;Lee, Kee Yoon
    • Polymer(Korea)
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    • v.38 no.3
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    • pp.320-326
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    • 2014
  • The effects of high shear rate processing on the thermal properties of PC/ABS blends were studied. It was executed by the high shear processing machine (NHSS2-28) at the varied conditions of screw speeds and loaded duration. After the samples were processed with NHSS2-28, the $T_gs$ were shifted from 143 to $133^{\circ}C$, and the behavior of degradation determined by TGA showed two distinct steps before high shear rate processing, while it showed a straight line after the processing. In order to provide the reasons of the properties, it was showen by SEM and UTM that the droplet sizes morphologically decreased after the processing, and the elongations decreased slightly until 1000 rpm of screw speed and then sharply decreased, according to the conditions of high shear rate processing. Therefore, it can be confirmed that $T_g,s$ of PC/ABS blends were considerably shifted under an appropriate high shear rate condition, and rapidly dropped, so that blends degraded above the condition, due to stress-induced degradation.

Experimental study on seismic behavior of two-storey modular structure

  • Liu, Yang;Chen, Zhihua;Liu, Jiadi;Zhong, Xu
    • Steel and Composite Structures
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    • v.37 no.3
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    • pp.273-289
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    • 2020
  • Due to the unique construction method of modular steel buildings (MSBs) with units prefabricated fully off the site and assembled quickly on the site, the inter-module connection for easy operation and overall performance of the system were key issues. However, it was a lack of relevant research on the system-level performance of MSBs. This study investigated the seismic performance of two-storey modular steel structure with a proposed vertical rotary inter-module connection. Three full-scale quasi-static tests, with and without corrugated steel plate and its combination, were carried out to evaluate and compare their seismic behaviour. The hysteretic performance, skeleton curves, ductile performance, stiffness degradation, energy dissipation capacity, and deformation pattern were clarified. The results showed that good ductility and plastic deformation ability of such modular steel structures. Two lateral-force resistance mechanisms with different layout combinations were also discussed in detail. The corrugated steel plate could significantly improve the lateral stiffness and bearing capacity of the modular steel structure. The cooperative working mechanism of modules and inter-module connections was further analyzed. When the lateral stiffness of upper and lower modular structures was close, limited bending moment transfer may be considered for the inter-module connection. While a large lateral stiffness difference existed initially between the upper and lower structures, an obvious gap occurred at the inter-module connection, and this gap may significantly influence the bending moments transferred by the inter-module connections. Meanwhile, several design recommendations of inter-module connections were also given for the application of MSBs.

Role of Ca in Modifying Corrosion Resistance and Bioactivity of Plasma Anodized AM60 Magnesium Alloys

  • Anawati, Anawati;Asoh, Hidetaka;Ono, Sachiko
    • Corrosion Science and Technology
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    • v.15 no.3
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    • pp.120-124
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    • 2016
  • The effect of alloying element Ca (0, 1, and 2 wt%) on corrosion resistance and bioactivity of the as-received and anodized surface of rolled plate AM60 alloys was investigated. A plasma electrolytic oxidation (PEO) was carried out to form anodic oxide film in $0.5mol\;dm^{-3}\;Na_3PO_4$ solution. The corrosion behavior was studied by polarization measurements while the in vitro bioactivity was tested by soaking the specimens in Simulated Body Fluid (1.5xSBF). Optical micrograph and elemental analysis of the substrate surfaces indicated that the number of intermetallic particles increased with Ca content in the alloys owing to the formation of a new phase $Al_2Ca$. The corrosion resistance of AM60 specimens improved only slightly by alloying with 2 wt% Ca which was attributed to the reticular distribution of $Al_2Ca$ phase existed in the alloy that might became barrier for corrosion propagation across grain boundaries. Corrosion resistance of the three alloys was significantly improved by coating the substrates with anodic oxide film formed by PEO. The film mainly composed of magnesium phosphate with thickness in the range $30-40{\mu}m$. The heat resistant phase of $Al_2Ca$ was believed to retard the plasma discharge during anodization and, hence, decreased the film thickness of Ca-containing alloys. The highest apatite forming ability in 1.5xSBF was observed for AM60-1Ca specimens (both substrate and anodized) that exhibited more degradation than the other two alloys as indicated by surface observation. The increase of surface roughness and the degree of supersaturation of 1.5xSBF due to dissolution of Mg ions from the substrate surface or the release of film compounds from the anodized surface are important factors to enhance deposition of Ca-P compound on the specimen surfaces.

Reverse link rate control for high-speed wireless systems based on traffic load prediction (고속 무선통신 시스템에서 트래픽 부하 예측에 의한 역방향 전송속도 제어)

  • Yeo, Woon-Young
    • Journal of the Institute of Electronics Engineers of Korea TC
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    • v.45 no.11
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    • pp.15-22
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    • 2008
  • The cdma2000 1xEV-DO system controls the data rates of mobile terminals based on a binary overload indicator from the base station and a simple probabilistic model. However, this control scheme has difficulty in predicting the future behavior of mobile terminals due to a probabilistic uncertainty and has no reliable means of suppressing the traffic overload, which may result in performance degradation of CDMA systems that have interference-limited capacity. This Paper proposes a new traffic control scheme that controls the data rates of mobile terminals effectively by predicting the future traffic load and adjusting the forward-link control channel. The proposed scheme is analyzed by modeling it as a multi-dimensional Markov process and compared with conventional schemes. The numerical results show that the maximum cell throughput of the proposed scheme is much higher than those of the conventional schemes.

Comparative investigation of endurance and bias temperature instability characteristics in metal-Al2O3-nitride-oxide-semiconductor (MANOS) and semiconductor-oxide-nitride-oxide-semiconductor (SONOS) charge trap flash memory

  • Kim, Dae Hwan;Park, Sungwook;Seo, Yujeong;Kim, Tae Geun;Kim, Dong Myong;Cho, Il Hwan
    • JSTS:Journal of Semiconductor Technology and Science
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    • v.12 no.4
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    • pp.449-457
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    • 2012
  • The program/erase (P/E) cyclic endurances including bias temperature instability (BTI) behaviors of Metal-$Al_2O_3$-Nitride-Oxide-Semiconductor (MANOS) memories are investigated in comparison with those of Semiconductor-Oxide-Nitride-Oxide-Semiconductor (SONOS) memories. In terms of BTI behaviors, the SONOS power-law exponent n is ~0.3 independent of the P/E cycle and the temperature in the case of programmed cell, and 0.36~0.66 sensitive to the temperature in case of erased cell. Physical mechanisms are observed with thermally activated $h^*$ diffusion-induced Si/$SiO_2$ interface trap ($N_{IT}$) curing and Poole-Frenkel emission of holes trapped in border trap in the bottom oxide ($N_{OT}$). In terms of the BTI behavior in MANOS memory cells, the power-law exponent is n=0.4~0.9 in the programmed cell and n=0.65~1.2 in the erased cell, which means that the power law is strong function of the number of P/E cycles, not of the temperature. Related mechanism is can be explained by the competition between the cycle-induced degradation of P/E efficiency and the temperature-controlled $h^*$ diffusion followed by $N_{IT}$ passivation.

Experimental study on all-bolted joint in modularized prefabricated steel structure

  • Wu, Zhanjing;Tao, Zhong;Liu, Bei;Zuo, Heng
    • Structural Engineering and Mechanics
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    • v.73 no.6
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    • pp.613-620
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    • 2020
  • The research study is focuses on a form of all-bolted joint with the external ring stiffening plate in the prefabricated steel structure. The components are bolted at site after being fabricated in the factory. Six specimens were tested under cyclic loading, and the effects of column axial compression ratio, concrete-filled column, beam flange sub plate, beam web angle cleats, and spliced column on the failure mode, hysteretic behavior and ductility of the joints were analyzed. The results shown that the proposed all-bolted joint with external ring stiffening plate performed high bearing capability, stable inflexibility degradation, high ductility and plump hysteretic curve. The primary failure modes were bucking at beam end, cracking at the variable section of the external ring stiffening plate, and finally welds fracturing between external ring stiffening plate and column wall. The bearing capability of the joints reduced with the axial compression ratio increased. The use of concrete-filled steel tube column can increase the bearing capability of joints. The existence of the beam flange sub plate, and beam web angle cleat improves the energy dissipation, ductility, bearing capacity and original rigidity of the joint, but also increase the stress concentration at the variable section of the external reinforcing ring plate. The proposed joints with spliced column also performed desirable integrity, large bearing capacity, initial stiffness and energy dissipation capacity for engineering application by reasonable design.