• 제목/요약/키워드: Degradation behavior

검색결과 909건 처리시간 0.024초

$CaNi_{5}$ 및 MG-$CaNi_{5}$ 전극의 퇴화거동에 미치는 불화처리의 영향 (The Effect of F-treatment on the Degradation Behavior of the $CaNi_{5}$ and MG-$CaNi_{5}$ Electrodes)

  • 이창래;오세진;강성군
    • 한국재료학회지
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    • 제9권6호
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    • pp.622-629
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    • 1999
  • Effects of the fluorination in the $K_2$TiF\ulcorner solution and in-situ KF+ KOH electrolyte on the electrochemical charge-discharge properties of CaNi\ulcorner and the Mg-CaNi\ulcorner electrodes were investigated. In-situ fluorination in the KF+ KOH electrolyte compared with pre-fluorination in the$ K_2$TiF\ulcorner solution could improve the electrochemical cycling durability of CaNi\ulcorner and MG-CaN\ulcorner electrodes. The fluorinated layer on the alloy surface by pre-fluorination to improve the activity and anti-corrosion of the electrodes was dissolved in the pure KOH electrolyte during the cycling. The fluorinated layer was formed continuously on the surface of the electrode by thee2N KF addition in the 6N KOH electrolyte. The excess F\ulcorner ion addition in KOH electrolyte could improve the electrochemical cycling durability of CaNi\ulcorner and Mg-CaNi\ulcorner electrode. But, in case of MG-CaNi\ulcorner electrode, the discharge capacity of the electrode was reduced and the poor cycling property was shown with increasing of the MG process times.

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초기재령 강섬유보강 철근콘크리트 보의 구조성능 평가 및 개선 (Improvement and Evaluation of Structural Performance of Steel Fiber Reinforced Concrete Beams Using Early Age Concrete)

  • 하기주;신종학;곽윤근;권칠성
    • 한국구조물진단유지관리공학회 논문집
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    • 제3권3호
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    • pp.129-137
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    • 1999
  • Reinforced concrete structures using early age concrete were result in the degradation of structural performance due to crack, overload, unexpected vibration and impact load. It demands urgently that reinforced concrete structure using early age concrete should be improved the serviceability and structural performance with the application of new fiber materials. Therefore specimens, designed by the test varibles, such as with or without stirrup and percent of steel fiber incorporated, were constructed and tested to evaluate and develop the structural performance of reinforced steel fiber concrete beam. Based on the test results reported in this study, the following conclusions are made. Specimens, designed by the over 0.75% of steel fiber incorporated, were showed the ductile behavior and failed slowly with flexure and flexure-shear. Comparing with the load-displacement relationship of specimen BSS, designed by the recommendations of the Ministry of Construction and Transportation, reinforced steel fiber concrete beam using early age concrete, over 0.75% of steel fiber incorporated, gets enough load carrying capacity and ductility. Increasing the percent of steel fiber incorporated(0.25~2.0%), the ultimate shear stress of each specimen were increased 12~40% than that of control specimen SSS.

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Plasma-Treated Poly(lactic-co-glycolic acid) Nanofibers for Tissue Engineering

  • Park, Hong-Hyun;Lee, Kuen-Yong;Lee, Seung-Jin;Park, Ko-Eun;Park, Won-Ho
    • Macromolecular Research
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    • 제15권3호
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    • pp.238-243
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    • 2007
  • Nanofibers were prepared by electrospinning a solution of poly(lactic-co-glycolic acid) (PLGA) and their mean diameter was 340 nm. The PLGA nanofibers were treated with a plasma in the presence of either oxygen or ammonia gas to change their surface characteristics. The hydrophilicity of the electrospun PLGA nanofibers was significantly increased by the gas plasma treatment, as confirmed by contact angle measurements. XPS analysis demonstrated that the chemical composition of the PLGA nanofiber surface was influenced by the plasma treatment, resulting in an increase in the number of polar groups, which contributed to the enhanced surface hydrophilicity. The degradation behavior of the PLGA nanofibers was accelerated by the plasma treatment, and the adhesion and proliferation of mouse fibroblasts on the plasma-treated nanofibers were significantly enhanced. This approach to controlling the surface characteristics of nanofibers prepared from biocompatible polymers could be useful in the development of novel polymeric scaffolds for tissue engineering.

The Necessity of Environmental Education for Employee Green Behavior

  • WOO, Eun-Jung
    • 동아시아경상학회지
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    • 제9권4호
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    • pp.29-41
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    • 2021
  • Purpose - The current study explores pro-environment human resource management attributes like an organization's leadership support, training, empowerment, and motivation practices to encourage employees to adopt an environmentally friendly lifestyle, leading to the success of the pro-environmental initiatives pursued by the organization. Research design, data, and methodology - The research subject is a considerable determinant that helps the research choose which qualitative textual analysis will suit that specific research. This study is suitable to conduct qualitative textual research because the justification for the qualitative content analysis used by a researcher is guided by the subject of the research, the available funds, the available time, and the research objectives. Result - Various solutions have been identified to ensure that all interventions taken by an organization, especially in educating and training their employees, are efficient, effective, and impactful. They revolve around the individual group, organizational, societal, and government policy approaches. Solutions will create a dedication to developing sustainability and ensuring that employees are positive when dealing with the surrounding. Conclusion - Consequently, combined efforts involving employees, society, organizations, and the government are necessary for formulating and implementing a practical course of action. This is to end the ongoing environmental degradation and foster positive behavioral change that involves activities and initiatives that will improve environmental performance for current and future generations.

Experimental and numerical study about seismic retrofitting of corrosion-damaged reinforced concrete columns of bridge using combination of FRP wrapping and steel profiles

  • Afshin, Hassan;Shirazi, Mohammad R. Nouri;Abedi, Karim
    • Steel and Composite Structures
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    • 제30권3호
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    • pp.231-251
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    • 2019
  • In the present study, a numerical and experimental investigation has been carried out on the seismic behavior of RC columns of a bridge which damaged under corrosive environments and retrofitted by various techniques including combined application of CFRP sheets and steel profiles. A novel hybrid retrofitting procedure, including the application of inner steel profiles and outer peripheral CFRP sheets, has been proposed for strengthening purpose. Seven large-scale RC columns of a Girder Bridge have been tested in the laboratory under the influence of simultaneous application of constant axial load and the lateral cyclic displacements. Having verified the finite element modeling, using ABAQUS software, the effects of important parameters such as the corrosion percentage of steel rebars and the number of CFRP layers have been evaluated. Based on the results, retrofitting of RC columns of the bridge with the proposed technique was effective in improving some measures of structural performance such as lateral strength degradation and higher energy absorption capability. However, the displacement ductility was not considerably improved whereas the elastic stiffness of the specimens has been increased.

HTPB 추진제 노화 특성 및 HFC 기반 수명 평가 기법 (HTPB Propellant Ageing Property and HFC Base Shelf-life Evaluation Method)

  • 조원호;;류백능;정규동;유지창
    • 한국추진공학회지
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    • 제22권5호
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    • pp.59-65
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    • 2018
  • hydroxyl-terminated polybutadiene(HTPB) 추진제는 자연 저장 기간 동안 내부 시효성 물질들에 의한 물리 화학적 반응으로 인해 서서히 노화가 진행된다. 각기 다른 시간-온도 조건에서 이들 시효성 물질의 가속 노화 시험을 통해 자연 상태에서의 노화 특성을 모사할 수 있다. 본 논문에서는 장기 저장 기간 동안 느리게 진행되는 HTPB 추진제의 물리 화학적 반응에 의한 노화 특성을 HFC(Heat Flow Calorimeter)로 분석 평가하여 수행한 HTPB 추진제의 신개념 수명 예측 기술에 대하여 고찰하였다.

부산 도심하천 하구의 Nonylphenol 거동 특성 (Behavior Characteristics of Nonylphenol in the Downstream of River in Busan, Korea)

  • 김선영;노경준;김동명
    • 한국수산과학회지
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    • 제52권1호
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    • pp.74-80
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    • 2019
  • Nonylphenol is an endocrine-disrupting chemical that is the degradation product of the nonionic surfactants nonylphenol ethoxylates. To understand the contamination and behavioral characteristics of nonylphenol, we measured the nonylphenol concentrations in surface water in the lower reaches of the Suyeong River, Korea. The results were used to estimate the material balance. The target area was divided into three regions to estimate the material balance of nonylphenol. In region 1, in flux of the dissolved nonylphenol was 282.3 g/day and the nonylphenol influx in particulate suspended solids was 1,582.8 g/day. The dissolved nonylphenol outflow discharged toward region 2 was 192.5 g/day, while the adsorption to particulate suspended solids was 89.8 g/day. Within the particulate suspended solids, the outflow to region 2 was 1,250.0 g/day, while the estimated amount settling in the sediments was 422.7 g/day. The adsorption of dissolved nonylphenol to the particulate suspended solids in regions 1 and 2 was 31.8% and 54.9%, respectively. In region 3, the desorption rate was 8.8%.

A Numerical Study on the Thermo-mechanical Response of a Composite Beam Exposed to Fire

  • Pak, Hongrak;Kang, Moon Soo;Kang, Jun Won;Kee, Seong-Hoon;Choi, Byong-Jeong
    • 국제강구조저널
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    • 제18권4호
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    • pp.1177-1190
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    • 2018
  • This study presents an analytical framework for estimating the thermo-mechanical behavior of a composite beam exposed to fire. The framework involves: a fire simulation from which the evolution of temperature on the structure surface is obtained; data transfer by an interface model, whereby the surface temperature is assigned to the finite element model of the structure for thermo-mechanical analysis; and nonlinear thermo-mechanical analysis for predicting the structural response under high temperatures. We use a plastic-damage model for calculating the response of concrete slabs, and propose a method to determine the stiffness degradation parameter of the plastic-damage model by a nonlinear regression of concrete cylinder test data. To validate simulation results, structural fire experiments have been performed on a real-scale steel-concrete composite beam using the fire load prescribed by ASTM E119 standard fire curve. The calculated evolution of deflection at the center of the beam shows good agreement with experimental results. The local test results as well as the effective plastic strain distribution and section rotation of the composite beam at elevated temperatures are also investigated.

Performance evaluation of differently structured RCE-DR GdBCO coated conductor tapes under uniaxial tension at 77 K

  • Diaz, Mark Angelo E.;Shin, Hyung-Seop;Jung, Ho-Sang;Lee, Jaehun
    • 한국초전도ㆍ저온공학회논문지
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    • 제24권1호
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    • pp.13-17
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    • 2022
  • The mechanical properties of REBCO coated conductor (CC) tapes under uniaxial tension are mainly determined by the thick layer Components like the substrate and the stabilizer. Depending on the applications of the CC tapes, it is also needed to externally reinforce thin metallic foils to one side or both sides of the CC tapes. This study investigated the effect of additional stabilizer layers or lamination on the electrical resistivity and electromechanical properties in RCE-DR processed GdBCO CC tapes with different structures. The strain/stress tolerance of Ic in differently processed 12 mm-wide REBCO CC tapes under uniaxial tension at 77 K and self-field could be determined by the loading-unloading scheme. As a result, Sn-Cu stabilized CC tape showed a significant decrease in mechanical properties due to its soft but thick stabilizing layer. However, similar electromechanical properties have been observed on both Sn-Cu and Sn-stabilized CC tapes, the Ic degradation behavior was independent of whether the CC tape has an external reinforcement or different stabilizing layers.

Experimental analysis of rocking shallow foundation on cohesive sand

  • Moosavian, S.M. Hadi;Ghalandarzadeh, Abbas;Hosseini, Abdollah
    • Earthquakes and Structures
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    • 제22권6호
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    • pp.597-608
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    • 2022
  • One of the most important parameters affecting nonlinearsoil-structure interaction, especially rocking foundation, is the vertical factor of safety (F.Sv). In this research, the effect of F.Sv on the behavior of rocking foundations was experimentally investigated. A set of slow, cyclic, horizontal loading tests was conducted on elastic SDOF structures with different shallow foundations. Vertical bearing capacity tests also were conducted to determine the F.Sv more precisely. Furthermore, 10% silt was mixed with the dry sand at a 5% moisture content to reach the minimum apparent cohesion. The results of the vertical bearing capacity tests showed that the bearing capacity coefficients (Nc and Nγ) were influenced by the scaling effect. The results of horizontal cyclic loading tests showed that the trend of increase in capacity was substantially related to the source of nonlinearity and it varied by changing F.Sv. Stiffness degradation was found to occur in the final cycles of loading. The results indicated that the moment capacity and damping ratio of the system in models with lower F.Sv values depended on soil specifications such cohesiveness or non-cohesiveness and were not just a function of F.Sv.