• Tribology and Lubricants
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• v.16 no.2
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• pp.84-90
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• 2000

High Temperature wear behavior of plasma sprayed zirconia coatings containing up to 10 mol% of Fe$_2$O$_3$ were investigated. The wear test results showed that the addition of Fe$_2$O$_3$ particles to zirconia improved the wear resistance and lowered the coefficient of friction. Optimum concentration of Fe$_2$O$_3$ was about 5 mol%. Similar degradation behavior was observed at about 40$0^{\circ}C$ for both zirconia and Fe$_2$O$_3$ added zirconia coatings. The results indicated that stabilization of tetragonal phase and changes in mechanical properties such as hardness and toughness were responsible for tribological behavior of plasma sprayed zirconia contain Fe$_2$O$_3$.

• Structural Engineering and Mechanics
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• v.50 no.6
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• pp.741-754
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• 2014

The conventional PHC pile-footing connection is the weak part because the surface area and stiffness are sharply changed. The Composite PHC pile reinforced with the transverse shear reinforcing bars and infilled-concrete, hereafter ICP pile, has been developed for improving the flexural and shear performance. This paper investigates the cyclic behavior and performance of the ICP pile-footing connection. To investigate the behavior of the connection, one PHC and two ICP specimens were manufactured and then a series of cyclic loading tests were performed. From the test results, it was found that the ICP pile-footing connection exhibited higher cyclic behavior and connection performance compared to the conventional PHC pile-footing connection in terms of ductility ratio, stiffness degradation and energy dissipation capacity.

• Steel and Composite Structures
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• v.18 no.3
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• pp.641-657
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• 2015

Application of reduced web beam section (RWBS) as a sacrificial fuse element has become a popular research field in recent years. Weakening of beam web in these connections may cause local web buckling around the opening area which can affect cyclic behavior of connection including: maximum load carrying capacity, strength degradation rate, dissipated energy, rotation capacity, etc. In this research, effect of local web buckling on the cyclic behavior of RWBS connections is investigated using finite element modeling (FEM). For this purpose, a T-shaped moment connection which has been tested under cyclic loading by another author is used as the reference model. Fracture initiation in models is simulated using Cyclic Void Growth Model (CVGM) which is based on micro-void growth and coalescence. Included in the results are: effect of opening corner radii, opening dimensions, beam web thickness and opening reinforcement. Based on the results, local web buckling around the opening area plays a significant role on the cyclic behavior of connection and hence any parameter affecting the local web buckling will affect entire connection behavior.

• Journal of Environmental Science International
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• v.23 no.3
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• pp.473-481
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• 2014

Poly(lactide)s(PLA) is an attractive material to solve the problem of waste plastic accumulation in nature because of its biodegradability. The lactide exists in three stereoisomeric configurations: L-lactide, D-lactide, and meso-lactide. PLA stereocomplexes, formed by the mixing of two enantiomers, poly(L-lactide)(PLLA) and poly(D-lactide)(PDLA), have many favorable characteristics because the stereocomplex showed $50^{\circ}C$ higher melting point than each enantiomeric polymer and the resistance toward degradation increased. In this study, we investigated the influence of the composition and the optical purity of each component on the formation of stereocomplexes. Also, the nanofibers of stereochemical PLA and their blends were prepared by electrospinning method. The properties of the obtained fibers were analyzed by differential scanning calorimetry and scanning electron microscopy. The results showed that a degree of stereocomplex was controlled by change of optical purity of each component. The enzymatic degradation of the fibers were strongly dependent on the stereocomplex.

• Transactions of the Korean Society of Mechanical Engineers
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• v.16 no.10
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• pp.1869-1876
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• 1992

The effect of particle property on FOD(foreign object damage) and strength degradation in structural ceramics especially, silicon carbide was investigated by accelerating a spherical particle having different material and different size. The damage induced showed significant differences in their patterns with increase of impact velocity. Also percussion cone was formed at the back part of specimen when particle size became large and its impact velocity exceeded a critical value. The extent of ring cracks was linearly related to particle size, however the impact of steel particle produced larger ring cracks than that of SiC particle. Increasing impact velocity the residual strength showed different degradation behaviors according to particle and its size. In the region the impact site represents nearly elastic deformation behavior, the residual strength was dependent upon the depth of cone crack regardless of particle size. However in elastic- plastic deformation region, the radial cracks led to rapid drop in residual strength.

• Macromolecular Research
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• v.10 no.2
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• pp.85-90
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• 2002

Poly (ethylene oxide)/polylatide/poly(ethylene oxide) (PEO/PL/PEO) tri-block copolymers, which each block is connected by ester bond, were synthesized by coupling reaction of PL with PEO in the presence of pyridine. PL/PEO/PL tri-block copolymer was synthesized by ring opening polymerization of L-lactide initiated by PEO in the presence of stannous octoate. Degradation behavior of the copolymers was investigated in a pH 7.4 phosphate buffer saline (PBS) at 37$\pm$1 $^{\circ}C$. Gel permeation chromatography (GPC) and $^1$H-nuclear magnetic resonance (NMR) were used to monitor the change of mass loss, molecular weight and composition of copolymers. In hydrolytic degradation, the PEO/PL/PEO tri-block copolymer with high PEO contents affected the increase of its mass loss, and resulted in the decrease of its molecular weight as well as PEO composition. However, when PL/PEO/PL and PEO/PL/PEO tri-block copolymers had similar PEO contents, PEO/PL/PEO decreased faster in molecular weight and PEO composition than PL/PEO/PL.

• Proceedings of the Korean Geotechical Society Conference
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• 2005.03a
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• pp.1159-1166
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• 2005

In the present study, a series of laboratory tests with sands of different silt contents, are conducted and methods to assess non-linear behaviors based on in-situ test results are proposed. Modified hyperbolic stress-strain model is used to analyze non-linearity of silty sands in terms of non-linear degradation parameters f and g as a function of silt contents and relative density $D_R$. Stress-strain relationship results were obtained from a series of triaxial tests on sands containing different amounts of silt. Initial shear modulus which was applied to normalize modulus degradation of silty sands were determined based on the resonant column test results. From the laboratory test results, it was observed that, as the relative density increases, values of f decrease and those of g increase. Cone resistance $q_c$ for silty soil condition used in the triaxial tests were estimated based on the cavity expansion analysis. A suggestion to make an estimation of degradation parameters f and g as a function of fine contents is addressed in terms of cone resistance $q_c$ .

• Journal of the Korean Ceramic Society
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• v.45 no.10
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• pp.625-630
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• 2008

In the bone cement composed of dense granules of $\beta-Ca_3(PO_4){_2}(\beta-TCP)$ and $Ca(H_2PO_4){_2}H_2O$, the compressive strength, setting time and temperature rise were measured to observe the degradation of cement with respect to the stored days before setting. Decreases of compressive strength and temperature rise were observed, while setting time increased with respect to the stored days. The similar trends were repeated with the increase of temperature of storage. Such a change virtually meant the fading of the character of cement and it took place only when the two starting materials were mixed during storage. The degradation could be mitigated taking advantage of granular $\beta$-TCP instead of powdery one. The formation of $CaHPO_4$, which resulted from reaction with ambient humidity, was attributed to the degradation observed during storage. Dependence of the degradation behavior on mixing and temperature during storage was discussed in terms of the driving force for reaction of cement.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.24 no.7 s.178
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• pp.1673-1680
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• 2000

The degradation of a boiler header constructed by a material, 1Cr-0.5Mo steel in a fossil power plant is observed when the header is exposed for a long period to the high temperature and pressure. The present investigations are for evaluating the effect of the degradation on the material, such as its strength changes. Reheat-treated metal is used to compare the mechanical properties of the degraded and that of reheat-treated materials. Through the investigation, following results are obtained 1) the area ratio of ferrite in the reheat-treated material is larger than that of the degraded material, 2) the hardness and tensile strength of the degraded material are lower than that of the reheat-treated material, 3) the ductile-brittle transition temperature(DBTT) increased toward high temperature region, 4) the fatigue crack growth rate(FCGR) of the degraded material is higher than that of the reheat-treated material in the region of low ΔK value while FCGR of the both materials are similar in high ΔK region.

• Korean Journal of Environmental Agriculture
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• v.11 no.2
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• pp.125-132
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• 1992

This study was conducted to know degradation products of the synthetic pyrethroid insecticide bifenthrin under soil, aqueous solution and UV-light irradation, and know its movement by leaching in soil. The major degradation product of bifenthrin was identified with 2-methylbiphenyl -3-y1 methanol by HPLC, UV, Mass and NMR under soil, aqueous solution and UV-light irradiation, The main degradation route was hydrolysis of the ester linkage. On exposure to UV-light, bifenthrin was decomposed almost completely in concentrations of 10 and 100 ppm in 24 hr but decomposed about 80% in 1,000 ppm. Bifenthrin was immobile in soil column system and on soil thin-layer chromatography system. Mostly bifenthrin remained in the 0-2.0㎝ layer of soil column and soil TLC.