• Title/Summary/Keyword: Defect Profile

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Vacancy Ordering and Physical Properties in Defect NaCl-type Solids; M-X (M = Yb, Y, X = S, Se) System

  • Lee Ji-Yun;Kim Sung-Jin
    • Bulletin of the Korean Chemical Society
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    • v.15 no.1
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    • pp.64-74
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    • 1994
  • The nonstoichiometric chalcogenides with NaCl-type structure were prepared and the physical and structural properties were studied. The homogeneous range and the structural change were studied based on X-ray powder diffractions using Rietveld-type full-profile fitting technique. Wide homogeneous ranges were observed in Y-S and Y-Se systems, and relatively narrow homogeneous ranges were observed in Yb-S and Yb-Se systems. Both in $Yb_{1-x}S\;and\;Yb_{1-x}Se$, a vacancy ordering transition occurred in (111) plane direction. The ordered superstructure had cubic symmetry(Fm$\bar{3}m) with doubled unit cell "a" parameter compared to the original NaCl-type. The superlattice developed in a continuous second-order transitiion was characterized by the reduced waved vector k= $(a^*+b^*+c^*)/2$. Y-S system had metallic, and YSe, YbSe system had semiconducting properties in their homogeneous ranges. It was observed that the change of electronic transport properties in extended homogeneous range did not depend on the relativeratio of metal to nonmetal, but on the quantities of vacancies.

Dissociative Recombination Rates of O₂+ Ion with Low Energy Electrons

  • 성정희;선호성
    • Bulletin of the Korean Chemical Society
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    • v.17 no.11
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    • pp.1065-1073
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    • 1996
  • The dissociative recombination of O2+(v+)+e-→O(1S)+O(1D) has been theoretically investigated using the multichannel quantum defect theory (MQDT). Cross sections and rate coefficients at various electron energies are calculated. The resonant structures in cross section profile, which are hardly measurable in experiments, are also determined and the existence of Rydberg states is found to affect the rates. The theoretical rate coefficients are computed to be smaller than experimental ones. The reasons for this difference are explained. The two-step MQDT procedure is found to be very useful and promising in calculating the state-to-state rates of the dissociative recombination reaction which is a very important and frequently found phenomenon in Earth's ionosphere.

A Study on Inter-leaf Transmission and Cross-leaf Transmission for Clinical Applications of the Multileaf Collimator (다엽 콜리메이터의 임상적용을 위한 엽측간 투과선량 및 엽종단간 투과선량 연구)

  • 이규찬;최진호
    • Progress in Medical Physics
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    • v.15 no.1
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    • pp.17-22
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    • 2004
  • Multileaf collimator (MLC) is now rapidly replacing the lead ahoy block to shape the radiation treatment field. In addition to its defect of rectangular field shaping and increased penumbra width, it has another possible problem, and that is of radiation transmission between leaves, which needs to be maintained at as low a level as is permissible. The authors measured and analyzed the inter-leaf and cross-leaf transmissions of MLC by Varian Associates Inc, before its clinical application. The inter-leaf and cross-leaf transmissions were calculated by comparing the measured point doses in the polystyrene phantom in the open field and in a total closure of MLC. The beam profile of the inter-leaf and cross-leaf transmissions were depicted by using a water phantom. A photon beam of 6 MV was used in the measurement. The inter-leaf transmission was 1.63∼1.67%, indicating that the shielding effect of MLC is excellent. However, the cross-leaf transmission in the central area was 18.4∼18.7% and this is well over the clinically acceptable limitation of 5%. The beam profile of cross-leaf transmission displayed 80∼90% transmission near the field edge, so that the cross-leaf transmission was 14∼17% in this area. The multileaf collimator has an excellent shi디ding effect and the inter-leaf transmission is negligible so that it can be used in clinic as a good replacement of the conventional lead alloy block. However, care must be taken to avoid the cross-leaf transmission in the radiation field.

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Evaluation of Abrasive Wear Face Using SAW (표면탄성파를 이용한 마모 표면부의 평가)

  • Kwon, Sung-D.;Yoon, Seok-S.;Song, Sung-J.;Lee, Young-Z.
    • Journal of the Korean Society for Nondestructive Testing
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    • v.22 no.2
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    • pp.193-197
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    • 2002
  • The frequency dependency of the Rayleigh surface wave was investigated indirectly by measuring the angular dependency of the backward radiation of the incident ultrasonic wave in the abrasion specimens, which was explained in view of the residual stress distribution. The peak intensity of the backward radiation profile decreased and the right half width of the profile increased with an increase of the variational rate of residual stress for the scuffing specimen. The peak intensity was also affected by the surface wave scattering during the propagation around the micro-damages. The peak angle might depend on not only the amount of residual stress but also the micro-structure. The result observed in this study demonstrates the high potential of the backward radiated ultrasound as a tool for the nondestructive evaluation of the subsurface gradients of materials.

Deuterium ion irradiation impact on the current-carrying capacity of DI-BSCCO superconducting tape

  • Rajput, M.;Swami, H.L.;Kumar, R.;Bano, A.;Vala, S.;Abhangi, M.;Prasad, Upendra;Kumar, Rajesh;Srinivasan, R.
    • Nuclear Engineering and Technology
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    • v.54 no.7
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    • pp.2586-2591
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    • 2022
  • In the present work, we have irradiated the DI-BSCCO superconducting tapes with the 100 keV deuterium ions to investigate the effect of ion irradiation on their critical current (Ic). The damage simulations are carried out using the binary collision approximation method to get the spatial distribution and depth profile of the damage events in the high temperature superconducting (HTS) tape. The point defects are formed near the surface of the HTS tape. These point defects change the vortex profile in the superconducting tape. Due to the long-range interaction of vortices with each other, the Ic of the tape degrades at the 77 K and self magnetic field. The radiation dose of 2.90 MGy degrades the 44% critical current of the tape. The results of the displacement per atom (dpa) and dose deposited by the deuterium ions are used to fit an empirical relation for predicting the degradation of the Ic of the tape. We include the dpa, dose and columnar defect terms produced by the incident particles in the empirical relation. The fitted empirical relation predicts that light ion irradiation degrades the Ic in the DI-BSCCO tape at the self field. This empirical relation can also be used in neutron irradiation to predict the lifetime of the DI-BSCCO tape. The change in the Ic of the DI-BSCCO tape due to deuterium irradiation is compared with the other second-generation HTS tape irradiated with energetic radiation.

Evaluation of Image Quality Change by Truncated Region in Brain PET/CT (Brain PET에서 Truncated Region에 의한 영상의 질 평가)

  • Lee, Hong-Jae;Do, Yong-Ho;Kim, Jin-Eui
    • The Korean Journal of Nuclear Medicine Technology
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    • v.19 no.2
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    • pp.68-73
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    • 2015
  • Purpose The purpose of this study was to evaluate image quality change by truncated region in field of view (FOV) of attenuation correction computed tomography (AC-CT) in brain PET/CT. Materials and Methods Biograph Truepoint 40 with TrueV (Siemens) was used as a scanner. $^{68}Ge$ phantom scan was performed with and without applying brain holder using brain PET/CT protocol. PET attenuation correction factor (ACF) was evaluated according to existence of pallet in FOV of AC-CT. FBP, OSEM-3D and PSF methods were applied for PET reconstruction. Parameters of iteration 4, subsets 21 and gaussian 2 mm filter were applied for iterative reconstruction methods. Window level 2900, width 6000 and level 4, 200, width 1000 were set for visual evaluation of PET AC images. Vertical profiles of 5 slices and 20 slices summation images applied gaussian 5 mm filter were produced for evaluating integral uniformity. Results Patient pallet was not covered in FOV of AC-CT when without applying brain holder because of small size of FOV. It resulted in defect of ACF sinogram by truncated region in ACF evaluation. When without applying brain holder, defect was appeared in lower part of transverse image on condition of window level 4200, width 1000 in PET AC image evaluation. With and without applying brain holder, integral uniformities of 5 slices and 20 slices summation images were 7.2%, 6.7% and 11.7%, 6.7%. Conclusion Truncated region by small FOV results in count defect in occipital lobe of brain in clinical or research studies. It is necessary to understand effect of truncated region and apply appropriate accessory for brain PET/CT.

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A Study on Structural Integrity Assessment of Pipeline using Weight Function Solution (가중함수법을 적용한 파이프라인 구조건전성평가에 관한 연구)

  • Noh, Ki-Sup;Oh, Dong-Jin;Kim, Myun-Hyun
    • Journal of Welding and Joining
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    • v.35 no.1
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    • pp.55-60
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    • 2017
  • There are many Industry Code and Standard (ICS) for Structural Integrity Assessment (SIA) on welded structure with defect. The general ICSs, such as R6, BS 7910 and API 579-1/ASME FFS-1, provide equations to determine the upper bound residual stress profiles based on collections from many literatures. However, these residual stress profiles used in the SIA cause the conservative design for welded structures. In this study, the structural integrity assessment for girth weld in pipeline has been conducted based on fracture mechanics. In addition, thermo-elastic plastic FE analysis was performed for evaluating the residual stress of girth weld in pipeline. The weight function solution is used to determine the stress intensity factor using the residual stress profile obtained by the FE analysis. This approach can account for redistribution and relaxation of residual stress as the defects grow. In order to the evaluate quantitative comparison between BS 7910 and weight function solution, structural integrity assessment determining allowable crack size on cracked pipe was performed with failure assessment diagram.

Study on the Radial Stress Considering Mechanical Characteristics of Substrate in Wound Rolls (롤투롤 와인딩 시스템에서 소재 특성을 고려한 반경 방향 응력에 대한 연구)

  • Kim, Seongyong;Lee, Changwoo
    • Journal of the Korean Society for Precision Engineering
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    • v.33 no.2
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    • pp.115-119
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    • 2016
  • Winding is one of the major processes in roll-to-roll systems. Taper tension profile in a winding determines the distribution of stress in the radial direction, i.e., the radial stress in the wound rolls. Maximum radial stress is major cause of material defect, and this study has been actively proceeded. Traditional models of radial stress model were focused on flexible and light substrate. In this study, we developed an advanced radial stress model including effects of both these parameters(weight and stiffness) on the radial stress. The accuracy of the developed model was verified through FEM(Finite Element Method) analysis. FEM result of maximum radial stress value corresponds to 99 % in comparison to result with the model. From this study, the material defects does not occur when the steel winding. And steel industry can be applied to improve the winding process.

Mechanical Properties and Smoothness of Semiconductive Materials(Shield) in Power Cable (전력케이블내 반도전 재료(층)의 기계적 특성 및 평활도에 관한 연구)

  • Yang Jong-Seok;Lee Yong-Sung;Park Dae-Hee;Lee Kyoung-Yong
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.54 no.4
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    • pp.154-160
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    • 2005
  • We have investigated thermal properties showed by changing the content of carbon black which is the component parts of semiconductive shield in underground power transmission cable. Specimens were made of sheet with the nine of those for measurement. Density of specimens was measured by density meter, and then stress-strain of specimens was measured by TENSOMETER 2000. A speed of measurement was 200[mm/min], ranges of stress and strain were 400(Kgf/$cm^2$) and 600[$\%$]. In addition, tests of stress-strain were progressed by aging specimens at air oven. Finally surface profile was shown in order to looking for protrusion of specimens by using smoothness tester. Density was highly measured according to increasing the content of carbon black from this experimental result, and stress was decreased, while strain was increased according to increasing the content of carbon black. And stress-strain were decreased some after aging because of oxidation reaction of chemical defect. Lastly surface of specimens smoothed generally.

Three-dimensional Modeling of Transient Enhanced Diffusion (과도 증속 확산(TED)의 3차원 모델링)

  • 이제희;원태영
    • Journal of the Korean Institute of Telematics and Electronics D
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    • v.35D no.6
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    • pp.37-45
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    • 1998
  • In this paper, we report the first three-dimensional simulation result of the transient enhanced diffusion(TED) of dopants in the ion-implanted silicon by employing our 3D semiconductor process simulator, INPROS system. In order to simulate three-dimensional TED redistribution of dopants in silicon, the dopant distributions after the ion implantation was calculated by Monte Carlo(MC) method, followed by finite element(FE) numerical solver for thermal annealing. Excellent agreement between the simulated 3D profile and the SIMS data has been obtained for ion-implanted arsenic and phosphorus after annealing the boron marker layer at 75$0^{\circ}C$ for 2 hours. Our three-dimensional TED simulation could successfully explain the reverse short channel effect(RSCE) by taking the 3D point defect distribution into account. A coupled TED simulation and device simulation allows reverse short channel effect on threshold to be accurately predicted.

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