• Title/Summary/Keyword: Decomposition of Odor

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Treatment of Odorous air pollutants by Plasma and Photocatalytic Process. (플라즈마 광촉매 복합 긍정을 이용한 악취물질 중 TEA, MEK의 분해처리)

  • 최금찬;정창훈
    • Journal of Environmental Science International
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    • v.12 no.12
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    • pp.1255-1260
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    • 2003
  • Plasma-photocatalytic oxidation process was applied in the decomposition of Triethylamine(TEA) and Methyl ethyl ketone(MEK). Plasma reactor was made entirely of pyrex glass and consists of 24mm inner diameter, 1,800mm length and discharge electrode of 0.4mm stainless steel. And initial concentrations of TEA and MEK for plasma-photocatalytic oxidation are 100 ppm. Odor gas samples were taken by gas-tight syringe from a glass sampling bulb which was located at reactor inlet and outlet, and TEA and MEK were determined by GC-FID. For plasma process, the decomposition efficiency of TEA and MEK were evaluated by varying different flowrates and decomposition efficiency of TEA and MEK increased considerably with decreasing treatment flowrates. For photocatalytic oxidation process, also the decomposition efficiency of TEA and MEK increased considerably with decreasing treatment flowrates. The decomposition efficiency of MEK was 57.8%, 34.2%, 18.8% respectively and the decomposition efficiency of TEA was reached all 100%. This result is higher than that of plasma process only, From this study, the results indicate that plasma-photocatalytic oxidation process is ideal for treatment of TEA and MEK.

Effect of Reducing the Odor of Food Wastes Using Effective Microorganism (EM) (유용미생물을 활용한 음식물쓰레기의 악취저감 효과)

  • Kim, Ha-Na;Yim, Bongbeen;Kim, Sun-Tae
    • Journal of Korean Society of Environmental Engineers
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    • v.38 no.4
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    • pp.162-168
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    • 2016
  • The aim was to investigate the effect of reducing the odorous and complex odor released during the decomposition of food wastes using effective microorganism (EM) as a function of time at $20^{\circ}C$ and $35^{\circ}C$. The variation of total microbial counts and dominant species counts in EM and leachate produced during food wastes decomposition was also observed. In general, the cumulative concentration of sulfur compounds ($H_2S$, $CH_3SH$) and complex odor released during food wastes decomposition increased with increasing elapsed time. The nitrogen compounds ($NH_3$, trimethyl amine), however, was not observed in all samples. The addition of EM in food wastes resulted in the reduction of concentration of sulfur compounds and complex odor, in spite of the increase of $CH_3CHO$ concentration. The dominant microbial species detected in EM were Lactobacillus species(Lactobacillus rhamnosus and Lactobacillus casei). In the leachate produced during food wastes decomposition, however, the various microbial community alternative to that detected in EM was observed. The EM could be potentially useful as a tools for reducing odor induced from the food waste decomposition process.

Decomposition of odor using atmospheric-pressure plasma (플라즈마를 이용한 악취물질 분해 특성)

  • Kang, Seok-Won;Lee, Jae-Sik;Lee, Kang-San;Lim, Hee-Ah;Kim, Ji-Seong;Lee, Jeong-Dae;Park, Wol-Su;Park, Young-Koo
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.21 no.7
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    • pp.708-718
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    • 2020
  • Offensive odor is recognized as a social environmental problem due to its olfactory effects. Ammonia(NH3), hydrogen sulfide(H2S) and benzene(C6H6) are produced from various petrochemical plants, public sewage treatment plants, public livestock wastes, and food waste disposal facilities in large quantities. Therefore efficient decomposition of offensive odor is needed. In this study, the removal efficiency of atmospheric-pressure plasma operating at an ambient condition was investigated by evaluating the concentrations at upflow and downflow between the plasma reactor. The decomposition of offensive odor using plasma is based on the mechanism of photochemical oxidation of offensive odor using free radical and ozone(O3) generated when discharging plasma, which enables the decomposition of offensive odor at ordinary temperature and has the advantage of no secondary pollutants. As a result, all three odor substances were completely decontaminated within 1 minute as soon as discharging the plasma up to 500 W. This result confirms that high concentration odors or mixed odor materials can be reduced using atmospheric-pressure plasma.

Effect of Inorganic Nanocomposite Based Liners on Deodorization of Kimchi

  • Chung, Kwon;Park, Hyun Jin;Shin, Yang Jai
    • KOREAN JOURNAL OF PACKAGING SCIENCE & TECHNOLOGY
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    • v.27 no.2
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    • pp.55-62
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    • 2021
  • This study aims to reduce the rancid odor generated during the fermentation process of kimchi by inserting zinc oxide (ZnO) into an inorganic porous material with a high surface area to decompose or adsorb the fermentation odor. ZnO activated by the presence of moisture exhibits decomposition of rancid odors. Mixed with Titanium dioxide (TiO2), a photocatalyst. To manufacture the packaging liner used in this study, NaOH, ZnCl2, and TiO2 powder were placed in a tank with diatomite and water. The sludge obtained via a hydrothermal ultrasonication synthesis was sintered in an oven. After being pin-milled and melt-blended, the powders were mixed with linear low-density polyethylene (L-LDPE) to make a masterbatch (M/B), which was further used to manufacture liners. A gas detector (GasTiger 2000) was used to investigate the total amount of sulfur compounds during fermentation and determine the reduction rate of the odor-causing compounds. The packaging liner cross-section and surface were investigated using a scanning electron microscope-energy dispersive X-ray spectrometer (SEM-EDS) to observe the adsorption of sulfur compounds. A variety of sulfur compounds associated with the perceived unpleasant odor of kimchi were analyzed using gas chromatography-mass spectrometry (GC-MS). For the analyses, kimchi was homogenized at room temperature and divided into several sample dishes. The performance of the liner was evaluated by comparing the total area of the GC-MS signals of major off-flavor sulfur compounds during the five days of fermentation at 20℃. As a result, Nano-grade inorganic compound liners reduced the sulfur content by 67 % on average, compared to ordinary polyethylene (PE) foam liners. Afterwards SEM-EDS was used to analyze the sulfur content adsorbed by the liners. The findings of this study strongly suggest that decomposition and adsorption of the odor-generating compounds occur more effectively in the newly-developed inorganic nanocomposite liners.

Post-processing Technique for Improving the Odor-identification Performance based on E-Nose System

  • Byun, Hyung-Gi
    • Journal of Sensor Science and Technology
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    • v.24 no.6
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    • pp.368-372
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    • 2015
  • In this paper, we proposed a post-processing technique for improving classification performance of electronic nose (E-Nose) system which may be occurred drift signals from sensor array. An adaptive radial basis function network using stochastic gradient (SG) and singular value decomposition (SVD) is applied to process signals from sensor array. Due to drift from sensor's aging and poisoning problems, the final classification results may be showed bias and fluctuations. The predicted classification results with drift are quantized to determine which identification level each class is on. To mitigate sharp fluctuations moving-averaging (MA) technique is applied to quantized identification results. Finally, quantization and some edge correction process are used to decide levels of the fluctuation-smoothed identification results. The proposed technique has been indicated that E-Nose system was shown correct odor identification results even if drift occurred in sensor array. It has been confirmed throughout the experimental works. The enhancements have produced a very robust odor identification capability which can compensate for decision errors induced from drift effects with sensor array in electronic nose system.

An Identification Technique Based on Adaptive Radial Basis Function Network for an Electronic Odor Sensing System

  • Byun, Hyung-Gi
    • Journal of Sensor Science and Technology
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    • v.20 no.3
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    • pp.151-155
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    • 2011
  • A variety of pattern recognition algorithms including neural networks may be applicable to the identification of odors. In this paper, an identification technique for an electronic odor sensing system applicable to wound state monitoring is presented. The performance of the radial basis function(RBF) network is highly dependent on the choice of centers and widths in basis function. For the fine tuning of centers and widths, those parameters are initialized by an ill-conditioned genetic fuzzy c-means algorithm, and the distribution of input patterns in the very first stage, the stochastic gradient(SG), is adapted. The adaptive RBF network with singular value decomposition(SVD), which provides additional adaptation capabilities to the RBF network, is used to process data from array-based gas sensors for early detection of wound infection in burn patients. The primary results indicate that infected patients can be distinguished from uninfected patients.

Odor emission characteristics in anaerobic high temperature burial composting of swine carcasses (돼지 사체의 혐기적 고온 매몰퇴비화법에서의 악취발생 특성)

  • Yang, Woo-Young;Lee, Jin-Young;Choi, Yeon-Ju;Ryu, Hee-Wook;Chae, Jeong-Seok;Jeon, Jun-Min
    • Journal of odor and indoor environment
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    • v.16 no.2
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    • pp.187-198
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    • 2017
  • It is very important to treat infected livestock carcasses safely and quickly. In this study, the degradation characteristics and odor generation characteristics of carcasses were investigated during the treatment of swine carcasses using the anaerobic burial composting method. While the carcasses were decomposed, the temperature remained high, at $40{\sim}55^{\circ}C$ on average, and most of the carcasses were decomposed rapidly. The major odor-contributing substances in the buried composting method are sulfuric odor substances such as $H_2S$, $CH_3SH$, dimethyl sulfide (DMS) and dimethyl disulfide (DMDS), and the odor contribution of these substances is 93~99%. Among them, $CH_3SH$, which accounts for about 56~89% of odor contribution, was the most representative indicator substance. Despite the anaerobic digestion process, the methane concentration in the digestion process was as low as 0.5~0.8% at the burial point of the carcass. The odor and methane produced during the decomposition of the carcasses decreased considerably during the discharge to the surface layer through the buried layer consisting of compost. These results suggest that anaerobic high temperature burial composting is one of the most useful methods to treat carcasses of infected livestock.

A study on the Effect of SOB(Sulfur-Oxidizing Bacteria) Media on the Removal of Hydrogen Sulfide in Water of Septic Tank (SOB(Sulfur Oxidizing Bacteria) Media가 정화조의 수중황화수소 제거에 미치는 영향에 관한 연구)

  • Song, Homyeon;Cho, Jeongil;Kim, Taeksoo;Kwon, Sucheol;Yu, Hyeongsik
    • Journal of Korean Society of Water and Wastewater
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    • v.27 no.1
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    • pp.59-67
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    • 2013
  • The odor occurring in the sewage system induces the displeasure, the disgust such as the headache, the vomit, etc. and increases the spiritual stress and disturbs the pleasant life of residents. These odors occur mainly in the area of combined sewage system treatment, being created in the personal sewage treatment plant such as septic tank and are incoming to sewage pipes and emitted to the outside through the manhole and the receiver, etc.; and this causes odors to the people. The Hydrogen Sulfide, the Methyl Mercaptan, the Ammonia, etc. are materials causing the odor, the more serious issue of odor is occurring since the septic tank of degradation process is being applied. The primary cause of odor is the decomposition of human feces in the septic tanks and sewage disposal facilities. The purpose of this study is reduction of hydrogen sulfide using air supplying and SOB(Sulfur-Oxidizing Bacteria). As a result of this study of the air supply system and the SOB media equipment by air supply, in case the air is injected to SOB media compared to the injection of air only, the removal efficiency the hydrogen sulfide was average 3.4 times higher.

Learning Behaviors of Stochastic Gradient Radial Basis Function Network Algorithms for Odor Sensing Systems

  • Kim, Nam-Yong;Byun, Hyung-Gi;Kwon, Ki-Hyeon
    • ETRI Journal
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    • v.28 no.1
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    • pp.59-66
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    • 2006
  • Learning behaviors of a radial basis function network (RBFN) using a singular value decomposition (SVD) and stochastic gradient (SG) algorithm, together named RBF-SVD-SG, for odor sensing systems are analyzed, and a fast training method is proposed. RBF input data is from a conducting polymer sensor array. It is revealed in this paper that the SG algorithm for the fine-tuning of centers and widths still shows ill-behaving learning results when a sufficiently small convergence coefficient is not used. Since the tuning of centers in RBFN plays a dominant role in the performance of RBFN odor sensing systems, our analysis is focused on the center-gradient variance of the RBFN-SVD-SG algorithm. We found analytically that the steadystate weight fluctuation and large values of a convergence coefficient can lead to an increase in variance of the center-gradient estimate. Based on this analysis, we propose to use the least mean square algorithm instead of SVD in adjusting the weight for stable steady-state weight behavior. Experimental results of the proposed algorithm have shown faster learning speed and better classification performance.

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A Study on Removal Performance of $NH_3$ Odor Gas Using High Frequency Surface Discharge Body (고주파 연면방전체를 이용한 $NH_3$ 처리성능에 관한 연구)

  • 이주상
    • Journal of environmental and Sanitary engineering
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    • v.11 no.1
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    • pp.9-15
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    • 1996
  • The purpose of this study was to evaluate the decomposition efficiency of $NH_3$ odor gas using high frequency surface discharge body. The results from this study are as follows; 1, Voltage and frequency of electric elements have effects on removal of $NH_3$ odor. The higher these two elements were set up, the more efficiently deodorizing processing worked. In this experiment, the optimum voltage and frequency applicable were observed around AC 6.0 kVp-p and 24.0 kHz respectively. 2. The temperature, humidity and residence time were observed strong variables for NH$_3$ removal process. Its performance had limits at high temperature and humidity conditions. The longer the residence time continued, the more efficiently deodorization process worked. The experimental results showed that the deodorization was efficiently processed under such conditions as $30.0^{\circ}C$ in temperature, 60rh% in humidity and 0.3 sec in residence time. 3. It was observed that in deodorization experiment, $NH_3$ odor gas was perfectly decomposed under the concentration condition below 15.0ppm. Moreover it was considered as economic and practical in terms of maintenance cost when compared with other deodorization methods.

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