• Journal of Environmental Science International
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• v.23 no.12
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• pp.1971-1976
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• 2014

In this study, the photocatalytic decomposition characteristics of single toluene, toluene mixed with benzene, toluene mixed with acetone, and toluene mixed methyl mercaptan (MM) by UV reactor installed with $TiO_2$-coated perforated plate were studied. The photocatalytic decomposition rate of single toluene, toluene mixed with benzene, toluene mixed with acetone, and toluene mixed with MM fitted well on Langmuir-Hinshelwood (L-H) kinetics equation. The maximum elimination capacity was obtained to be $628g/m^3{\cdot}d$ for single toluene, $499g/m^3{\cdot}d$ for toluene mixed with benzene, $318g/m^3{\cdot}d$ for toluene mixed with acetone, and $513g/m^3{\cdot}d$ for toluene mixed with MM, respectively. The negative effect in photocatalytic decomposition of toluene are found to be in the order of acetone>benzene>MM.

• Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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• v.28 no.6
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• pp.52-59
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• 2014

This paper deals with the effect of decomposition products which occur in breakdown of mineral oil, on the insulation characteristics of its oil. Breakdown tests in the oil were conducted by the proposed experimental methods under a quasi-uniform field and AC HV (60Hz). The breakdown voltage in the oil shows characteristics of dispersion from successive breakdowns and, it is found that there are three patterns of the decomposition products behavior at the process of breakdown progress in the oil. Finally, the breakdown voltage dispersion in the oil can be described in detail based on the behavior patterns of the decomposition products and its diffusion time.

• The Korean Journal of Ecology
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• v.4 no.1_2
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• pp.38-51
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• 1981

The present investigation was estimated the effect of temperature, precipitatiion, and time on the decomposition of litters with litter bags of Pinus densiffora and Quercus mongolica at Gure where elevation in 50m, and at Nogodan where elevation in 1300m on Mt. Jiri. As the above results, decomposition model was proposed to relation of the environmental conditions. And was investigated the production and decomposition of litters from the stands of various forest communities in Kwangneung, Mt. Jiri and Mt. Halla. The results are as follows; The models for the decay of organic carbon (C) was as follows: $C=Coe^{-Kt}$ (limiting factor;time) $C=Coe^{-K'te}$ (limiting factor;tempedrature) $C=Coe^{-KnP}$ (limiting factor:precipitation) As observed in litter bag method, the decomposition rate of litter in Pinus densiflora was slower than that of Quercus mongolica. The higher elevation, the slower decomposition rate. The decomposition of litters at Gure where elevation in 50m was equally influenced by temperature and precipitation. But at Nogodan where elevation in 1300m was much inflenced by precipitation. The decay constant of litters was larger in hardwood forest than in coniferous forest. In the same species, the more elevatiion, the less decomposition constant. The time required for the decay of 50%, 95^, 99% of the accumulated litters in the forest floor were faster in hardwood forest than in coniferous forest. In the same species, the higher elevatiion, the longer time required.

• Elastomers and Composites
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• v.58 no.3
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• pp.121-127
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• 2023

The effect of diisocyanate type on the decomposition temperature of polyurethane (PU) hydrolysis was investigated in a subcritical water medium up to 250℃. PU samples were prepared using different types of diisocyanate: two aromatic diisocyanates (4,4'-methylene diphenyl diisocyanate (MDI) and methyl phenylene diisocyanate (TDI)), one unbranched aliphatic diisocyanate (hexamethylene diisocyanate (HDI)), and two cyclic aliphatic diisocyanates (4,4'-methylene dicyclohexyl diisocyanate (H₁₂MDI) and isophorone diisocyanate (IPDI)). The pressure had no effect on hydrolysis in the range of 70-250 bar. The decomposition temperature of the PU samples increased in the following order: TDI-PU (199℃) < H₁₂MDI ≈ IPDI ≈ HDI (218-220℃) < MDI-PU (237℃). This order of increase in temperature is related to the electron-donating ability of the group to connected to the nitrogen of the urethane unit. When the temperature of the (PU + water) mixture reached the specific decomposition temperature, the PU samples hydrolyzed completely within 5 min into primary amine and 1,4-butanediol. The hydrolysis products from MDI-PU and H₁₂MDI-PU were separated into a liquid phase rich in (BD + water) and a solid low phase rich in amine, whereas the products from TDI-, IPDI-, and HDI-PU existed in a single aqueous phase.

• Journal of the Korean Institute of Telematics and Electronics A
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• v.31A no.2
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• pp.67-74
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• 1994

Effects of the GaAs semiconductor particles on electrophysical phenomena at the Pt electrode/10S0-3TM KCl aqueous electrolyte interfaces have been studied using voltammetric time based and electrochemical impedance techniques. The anodic decomposition effect f the GaAs semiconductor particles on electrophysical phenomena was significantly observed during the positive potential scan (0 to 1.0 V vs. SCE). On the other hand, the cathodic decomposition effect of the GaAs semiconductor particles was negligible during thenegative potential scan (0 to -1.0 V vs. SCE). The GaAs semiconductor particles act as current activators or mediators during the anodic process and act as charge screens during the cathodic process. The electrolyte resistance and related impedance was increased due to the presence of the GaAs semiconductor particles. The anodic decomposition effect of the GaAs semiconductor particles can directly be applied to activate the hydrogen evolution.

• Environmental and Resource Economics Review
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• v.31 no.4
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• pp.825-848
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• 2022

This paper analyzed the factors for increasing energy consumption in the domestic manufacturing sector using the LMDI (Log mean division index) decomposition method for the period from 1999 to 2019. Among the LMDI decomposition analysis methods, both additive and multiplicative factor decomposition methods were used. in this analysis. According to the result of the analysis, the factor that increased energy consumption in the domestic manufacturing industry was the production effect, and the structure effect and intensity effect were found to be the factors that decreased energy consumption. In particular, the reduction of energy consumption due to the structure effect was greater than that of energy consumption effect due to the intensity effect. By period, it can be seen that energy consumption increased rapidly due to the production effect until 2011, but after that, the increase in energy consumption due to the production effect slowed down. On the other hand, after that, the energy reduction effect due to the structure effect and the intensity effect became prominent. In order to save energy in the manufacturing sector in the future, energy diagnosis and management through EMS (Energy management system) and FEMS (Factory energy management system) are more necessary. In addition, restructuring into a low-energy consumption industry seems more necessary.

• Journal of Ecology and Environment
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• v.34 no.4
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• pp.401-410
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• 2011

We assayed the effects of simulated acid rain on the mass loss, $CO_2$ evolution, dehydrogenase activity, and microbial biomass-C of decomposing Sorbus alnifolia leaf litter at the microcosm. The dilute sulfuric acid solution composed the simulated acid rain, and the microcosm decomposition experiment was performed at 23$^{\circ}C$ and 40% humidity. During the early decomposition stage, decomposition rate of S. alnifolia leaf litter, and microbial biomass, $CO_2$ evolution and dehydrogenase activity were inhibited at a lower pH; however, during the late decomposition stage, these characteristics were not affected by pH level. The fungal component of the microbial community was conspicuous at lower pH levels and at the late decomposition stage. Conversely, the bacterial community was most evident during the initial decomposition phase and was especially dominant at higher pH levels. These changes in microbial community structure resulting from changes in microcosm acidity suggest that pH is an important aspect in the maintenance of the decomposition process. Litter decomposition exhibited a positive, linear relationship with both microbial respiration and microbial biomass. Fungal biomass exhibited a significant, positive relationship with $CO_2$ evolution from the decaying litter. Acid rain had a significant effect on microbial biomass and microbial community structure according to acid tolerance of each microbial species. Fungal biomass and decomposition activities were not only more important at a low pH than at a high pH but also fungal activity, such as $CO_2$ evolution, was closely related with litter decomposition rate.

• Applied Microscopy
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• v.39 no.4
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• pp.325-332
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• 2009

It has been well known that grapefruit seed extract (GSE) have effects on the deodorization and a wide range disinfectant. But anybody do not research about the decomposition-inhibition effect of GSE. The present study was performed to investigate the decomposition-inhibition effect of GSE by measuring the microscope and electroscope observation with passage of time. A total of 30 healthy Sprague-Dawley (SD) rats weighting from 230 gm to 250 gm were used as experimental animals. One group that do not treated by GSE named control group and the other group that treated by 55% GSE named Experimental group. Under ether anesthesia, right kidney was obtained. Put each sample in $37^{\circ}C$ and humidity $80{\pm}5%$ incubator, we obtained each sample after 0 day, 1 day, 2 days, 3 days, 4 days and 5 days. 4 ${\mu}m$ of paraffin sections were obtained, stained H-E stain and observed by use of a microscope. Morphological change in tissue was similar to control 1 day group and experimental 3 days group. Therefore, decomposition-inhibition effect of GSE continued about 2 days and it protected necrosis. According to above results, the author suggest that 55% GSE is an effective decomposition inhibitor until 2 days on $37^{\circ}C$ and humidity $80{\pm}5%$ conditions.

• Journal of Environmental Science International
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• v.22 no.1
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• pp.83-89
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• 2013

Silicon carbide with aluminium oxide was used to remove the sulphur hexafluoride ($SF_6$) gas using microwave irradiation. The destruction and removal efficiencies (DREs) of $SF_6$ were studies as a function of various decomposition temperatures and microwave powers. The decomposition of $SF_6$ gas was analyzed using GC-TCD. XRD (X-ray powder diffraction) and XRF (X-ray Fluorescence Spectrometer) were used to characterize the properties of aluminum oxide. DREs of $SF_6$ were increased as the microwave powers were increased. Additive aluminium oxide on SiC increased the removal efficiencies and decreased the decomposition temperature. The XRD results show that the ${\gamma}-Al_2O_3$ was transformed to ${\alpha}-Al_2O_3$ during $SF_6$ decomposition by microwave irradiation. It was found that the best material to control $SF_6$ was SiC with $Al_2O_3$ 30 wt% in consideration of microwave energy consumption and $SF_6$ decomposition rate.

• Journal of the Korean Society of Industry Convergence
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• v.6 no.4
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• pp.269-275
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• 2003

A non-thermal plasma process combined with $Cr_2O_3/TiO_2$ catalyst was applied to the decomposition of trichloroethylene (TCE). A dielectric barrier discharge reactor operated with AC high voltage was used as the non-thermal plasma reactor. The effects of reaction temperature and input power on the decomposition of TCE and the formation of byproducts including HCl, $Cl_2$, CO, NO, $NO_2$ and $O_3$ were examined. At an identical input power, the increase in the reaction temperature from 373 K to 473 K decreased the decomposition of TCE in the plasma reactor. The presence of the catalyst downstream the plasma reactor not only enhanced the decomposition of TCE but also affected the distribution of byproducts, significantly. However, synergistic effect as a result of the combination of non-thermal plasma with catalyst was not observed, i.e., the TCE decomposition efficiency in this plasma-catalyst combination system was almost similar to the sum of those obtained with each process.