• Title/Summary/Keyword: Decomposition analysis

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Thermal Decomposition of Phase Stabilized Ammonium Nitrate (PSAN) (상안정화 질산암모늄(PSAN)의 열분해)

  • 김준형;임유진
    • Journal of the Korean Society of Propulsion Engineers
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    • v.3 no.4
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    • pp.23-30
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    • 1999
  • The thermal decomposition of phase stabilized ammonium nitrate(PSAN) was studied by means of thermogravimetric analysis(TGA). In this study, potassium nitrate and zinc oxide were used as the phase stabilizers in the range of contents from 0 wt.% to 8 wt.%. The kinetics and mechanism for the decomposition were evaluated using integral methods. It was found that the thermal kinetic parameters such as activation energy(I) and frequency factor(A) increase with the increase of the stabilizer contents, and the mechanism of decomposition also changes.

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THE USE OF ITERATIVE METHODS FOR SOLVING NAVEIR-STOKES EQUATION

  • Behzadi, Shadan Sadigh;Fariborzi Araghi, Mohammad Ali
    • Journal of applied mathematics & informatics
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    • v.29 no.1_2
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    • pp.381-394
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    • 2011
  • In this paper, a Naveir-Stokes equation is solved by using the Adomian's decomposition method (ADM), modified Adomian's decomposition method (MADM), variational iteration method (VIM), modified variational iteration method (MVIM), modified homotopy perturbation method (MHPM) and homotopy analysis method (HAM). The approximate solution of this equation is calculated in the form of series which its components are computed by applying a recursive relation. The existence and uniqueness of the solution and the convergence of the proposed methods are proved. A numerical example is studied to demonstrate the accuracy of the presented methods.

Structural Analysis of Space Truss by using New Force Method based on Singular Value Decomposition (특이값 분해로 정식화 된 새로운 하중법을 이용한 입체 트러스 구조 해석)

  • Lee, Su-Hyun;Chung, Woo-Sung;Lee, Jae-Hong
    • Journal of the Computational Structural Engineering Institute of Korea
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    • v.24 no.5
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    • pp.481-489
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    • 2011
  • In this paper presents new force method by using singular value decomposition. The existing force method has some advantages about analysis of truss structures such as it is easier basic concept than finite element method, which apply to analyze truss structures. However, this method has complex formulation for analysis. Therefore, in this study proposes new force method using singular value decomposition, which is both having easy basic concept and simple computation than existing force method. The proposed method is illustrated through numerical examples.

Parallel Process System and its Application to Steam Generator Structural Analysis

  • Chang Yoon-Suk;Ko Han-Ok;Choi Jae-Boong;Kim Young-Jin
    • Journal of Mechanical Science and Technology
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    • v.19 no.11
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    • pp.2007-2015
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    • 2005
  • A large-scale analysis to evaluate complex material and structural behaviors is one of interesting topic in diverse engineering and scientific fields. Also, the utilization of massively parallel processors has been a recent trend of high performance computing. The objective of this paper is to introduce a parallel process system which consists of general purpose finite element analysis solver as well as parallelized PC cluster. The later was constructed using eight processing elements and the former was developed adopting both hierarchical domain decomposition method and balancing domain decomposition method. Then, to verify the efficiency of the established system, it was applied for structural analysis of steam generator in nuclear power plant. Since the prototypal evaluation results agreed well to the corresponding reference solutions it is believed that, after reinforcement of PC cluster by increasing number of processing elements, the promising parallel process system can be utilized as a useful tool for advanced structural integrity evaluation.

Thermal Decomposition of Ammonium Salts of Transition Metal Oxyacids. V. Study on the Thermal Decomposition of Ammonium Metavanadate (전위금속의 산소산염의 열분해에 관한 연구 (제5보) Ammonium Metavanadate의 열분해에 따르는 $V_2O_5$의 생성)

  • Il-Hyun Park
    • Journal of the Korean Chemical Society
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    • v.16 no.3
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    • pp.157-165
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    • 1972
  • Thermal decomposition of ammonium metavanadate has been investigated by using the quartz spring balance and differential thermal analysis. It showed that the decomposition of ammonium metavanadate is proceeded at two stages which correspond to $180^{\circ}C-220^{\circ}C$ and $310^{\circ}C-330^{\circ}C$ decomposition temperatures, respectively. Evolved ammonia gas in thermal decomposition has been analyzed quantitatively by titration. And the constituents of gases evolved have been evaluated by gas chromatography and omegatron spectrometer. From these results, it was concluded that the gases evolved in the first step decomposition were $NH_3$ and $H_2O$ with 2:1 ratio and the second step decomposition corresponded to the formation of $NH_3$, $H_2O$ and $N_2O$ which was produced in oxidation of $NH_3$ by $V_2O_5$. The decomposition products were identified by means of X-ray diffraction method. The decomposition product in air was V_2O_5 and the product in vacuum $V_3O_7.$ The kinetics of the thermal decomposition was studied, giving the values of the activation energy of 41.4 kcal/mole and 64.4 (kcal/mole) respectively.

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Studies on Thermal Decomposition of Barium Titanyl Oxalate by Factor Analysis of X-Ray Diffraction Patterns

  • Seungwon Kim;Sang Won Choi;Woo Young Huh;Myung-Zoon Czae;Chul Lee
    • Bulletin of the Korean Chemical Society
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    • v.14 no.1
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    • pp.38-42
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    • 1993
  • Factor analysis was applied to study the thermal decomposition of barium titanyl oxalate (BTO) which is used as the precursor of barium titanate. BTO was synthesized in $H_2O$ solvent and calcined at various temperatures. The X-ray diffraction patterns were obtained to make the data matrix of peak intensity vs. 2${\theta}$. Abstract factor analysis and target transformation factor analysis were applied to this data matrix. It has been found that the synthesized BTO consists of the crystals of $BaC_2O_4{\cdot}0.5H_2O\;and\;BaC_2O_4{\cdot}2H_2O$ as well as the amorphous solid of TiO-oxalate. The results also indicate that the BTO was transformed via $BaCO_3\;to\;BaTiO_3\;and\;Ba_2TiO_4$ during the thermal decomposition.

Hierarchical Smoothing Technique by Empirical Mode Decomposition (경험적 모드분해법에 기초한 계층적 평활방법)

  • Kim Dong-Hoh;Oh Hee-Seok
    • The Korean Journal of Applied Statistics
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    • v.19 no.2
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    • pp.319-330
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    • 2006
  • A signal in real world usually composes of multiple signals having different scales of frequencies. For example sun-spot data is fluctuated over 11 year and 85 year. Economic data is supposed to be compound of seasonal component, cyclic component and long-term trend. Decomposition of the signal is one of the main topics in time series analysis. However when the signal is subject to nonstationarity, traditional time series analysis such as spectral analysis is not suitable. Huang et. at(1998) proposed data-adaptive method called empirical mode decomposition (EMD) . Due to its robustness to nonstationarity, EMD has been applied to various fields. Huang et. at, however, have not considered denoising when data is contaminated by error. In this paper we propose efficient denoising method utilizing cross-validation.

Experimental Study on Air Decomposition By-Product Under Creepage Discharge Fault and Their Impact on Insulating Materials

  • Javed, Hassan;LI, Kang;Zhang, Guoqiang;Plesca, Adrian Traian
    • Journal of Electrical Engineering and Technology
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    • v.13 no.6
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    • pp.2392-2401
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    • 2018
  • Creepage discharge faults in air on solid insulating material play a vital role in degradation and ageing of material which ultimately leads to breakdown of power equipment. And electric discharge decompose air in to its by-products such as Ozone and $NO_x$ gases. By analyzing air decomposition gases is a potential method for fault diagnostic in air. In this paper, experimental research has been conducted to study the effect of creepage discharge on rate of generation of air decomposition by-products using different insulating materials such as RTV, epoxy and fiberglass laminated sheet. Moreover XRF analysis has been done to analyze creepage discharge effect on these insulating materials. All experiments have been done in an open air test cell under constant temperature and pressure conditions. While analysis has been made for low and high humidity conditions. The results show that the overall concentration of air decomposition by-products under creepage discharge in low humidity is 4% higher than concentration measured in high humidity. Based on this study a mathematical relationship is also proposed for the rate of generation of air decomposition by-products under creepage discharge fault. This study leads to indirect way for diagnostic of creepage discharge propagation in air.

Robust Primary-ambient Signal Decomposition Method using Principal Component Analysis with Phase Alignment (위상 정렬을 이용한 주성분 분석법의 강인한 스테레오 음원 분리 성능유지 기법)

  • Baek, Yong-Hyun;Hyun, Dong-Il;Park, Young-Cheol
    • Journal of Broadcast Engineering
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    • v.19 no.1
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    • pp.64-74
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    • 2014
  • The primary and ambient signal decomposition of a stereo sound is a key step to the stereo upmix. The principal component analysis (PCA) is one of the most widely used methods of primary-ambient signal decomposition. However, previous PCA-based decomposition algorithms assume that stereo sound sources are only amplitude-panned without any consideration of phase difference. So it occurs some performance degradation in case of live recorded stereo sound. In this paper, we propose a new PCA-based stereo decomposition algorithm that can consider the phase difference between the channel signals. The proposed algorithm overcomes limitation of conventional signal model using PCA with phase alignment. The phase alignment is realized by using inter-channel phase difference (IPD) which is widely used in parametric stereo coding. Moreover, Enhanced Modified PCA(EMPCA) is combined to solve the problem of conventional PCA caused by Primary to Ambient energy Ratio(PAR) and panning angle dependency. The simulation results are presented to show the improvements of the proposed algorithm.

Quantitative Analysis of Heavy Metals in Packaging Papers

  • Jo, Byoung-Muk;Jeong, Myung-Joon
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.39 no.5
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    • pp.45-51
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    • 2007
  • This study was carried out to investigate various heavy metal contents in packaging papers by pre-treatments for ICP-ES (Inductively Coupled Plasma Emission Spectrometry) analysis. Pre-treatment methods of heavy metals in this study include extraction, migration and decomposition methods (dry ashing, $HNO_3-HClO_4-HF,\;HNO_3,\;and\;H_2SO_4-HNO_3$). Test results were compared with conventional extraction (water) and migration (3% acetic acid) methods. The five representative heavy metals (Cd, As, Pb, Cr and Hg) were analyzed. For Cd, Hg, and As, the results were below detection limit of the instrumental technique. It was considered that the migration test was a better method compared to extraction test, but all the decomposition methods showed much higher detection values than the extraction or migration test. In case of recycled corrugated containers, 3% acetic acid solution extracted about 25% of chromium and 30% of lead compared to the content by decomposition methods. Among all decomposition methods, the nitric acid - perchloric acid - hydrofluoric acid treatment brought a slightly higher detection value than others, but there was no significant difference among them except sulfuric acid - nitric acid method.