• Title/Summary/Keyword: Decolorization

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A Study on the Preparation of the Dimensionally Stable Anode(DSA) with High Generation Rate of Oxidants(I) (산화제 생성율이 높은 촉매성 산화물 전극(DSA)의 개발에 관한 연구(I))

  • Kim, Dong-Seog;Park, Young-Seek
    • Journal of Environmental Science International
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    • v.18 no.1
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    • pp.49-60
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    • 2009
  • Fabrication and oxidants formation of 1 and 2 component metal oxide electrode, which is known to be so effective to destruct non-biodegradable organics in wastewater, were studied. Five electrode materials (Ru, Pt, Sn, Sb and Gd) were used for the 1 and 2 component electrode. The metal oxide electrode was prepared by coating the electrode material on the surface of the titanium mesh and then thermal oxidation at $500^{\circ}C$ for 1 h. The removed RhB per 2 min and unit W for one component electrode decreased in the following sequences: Ru/Ti>Sb/Ti>Pt/Ti>Gd/Ti>Sn/Ti. The concentration of oxidants generated in 1 and 2 component electrodes was in the order of: $ClO_2$> free Cl>$H_2O_2>O_3$. OH radical was not generated from in entire one and two component electrodes. RhB degradation rate and generated oxidants of the Ru-Sn=9:1 electrode was higher than that of the two component electrode. The exact relationship between the removal of RhB and the generated oxidants concentration was not obvious. However, it was assumed that electrode with high RhB decolorization had high oxidant concentration.

The Separation, Purification and Utilization of Wood Main Components by Steam Explosion in Low Pressure (II) - Characterization and Utilization of Separated Wood Polysaccharides - (저압(低壓) 폭쇄처리(爆碎處理)에 의한 목재주성분(木材主成分)의 분리(分離)·정제(精製) 및 이용(利用) (II) - 탄수화물(炭水化物)의 화학적(化學的) 성상(性狀)및 이용(利用) -)

  • Eom, Chan-Ho;Eom, Tae-Jin;Lee, Jong-Yoon
    • Journal of the Korean Wood Science and Technology
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    • v.24 no.2
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    • pp.20-25
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    • 1996
  • Wood chips of oak(Quercus mongolica) and larch(Larix leptolepis) were exploded with the optimum condition. Main components of exploded wood were separated with hot hot water and methanol. The hemicelluloses were purified from hot water extracts and alditol complexs were prepared from purified hemicellulose. And also, cellulose nitrate was prepared from extractive residue and characterized. The results can be summarized as follows. 1. Amounts of carbohydrate(72~79%) in the crude hemicellulose of larch wood was more than those of oak wood(55~66%). 2. The crude hemicelluloses were mainly composed of oligosaccharides in oak wood but those in larch wood contained about 50% monosaccharides. 3. Decolorization of hemicellulose was successful with activated charcoal and ion-exchange resin treatment. The alditol yields were 56.3~82.9%. 4. The degree of substitution(D.S.) of cellulose nitrate was 1.95~2.87 and it showed a good acetone solubility.

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Synthesis and Characterization of ZnS and ZnS/TiO2 Nanocomposites and Their Enhanced Photo-decolorization of MB and 1,5-Diphenyl Carbazide

  • Meng, Ze-Da;Ullah, Kefayat;Zhu, Lei;Ye, Shu;Oh, Won-Chun
    • Journal of the Korean Ceramic Society
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    • v.51 no.4
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    • pp.307-311
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    • 2014
  • ZnS and $ZnS/TiO_2$ were prepared by chemical deposition. The prepared photocatalysts were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), energy-dispersive X-ray (EDX), and transmission electron microscopy (TEM). The generation of reactive oxygen species was detected by monitoring the oxidation reaction from 1,5-diphenyl carbazide (DPCI) to 1,5-diphenyl carbazone (DPCO). Excellent catalytic degradation of methylene blue (MB) solution was observed using the $ZnS/TiO_2$ composites during irradiation with visible light. The results show that the photocatalytic performance of $TiO_2$ nanoparticles is improved by loading with ZnS.

Activated Carbon Fibers from Chemically Modified Coal Tar Pitches

  • Ryu, S.K.;Shim, J.W.;Yang, K.S.;Mochida, I.
    • Carbon letters
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    • v.1 no.1
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    • pp.6-11
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    • 2000
  • Coal tar pitch was chemically modified with 10 wt% benzoquinone (BQ) to raise the softening point of isotropic pitch precursor and the precursor was melt-spun into pitch fibers, stabilized, carbonized and activated with steam at $900^{\circ}C$. The weight loss of carbon fiber-benzoquinone (CF-BQ) increased with the increase of activation time like other fibers, but was lower than those of Kureha fiber at the same activation time in spite of larger geometric surface area. Those adsorption isotherms fitted into 'Type I' according to Brunauer, Deming, Deming and Teller classification. However, there was very thin low-pressure hysteresis that lower closure points of the hysteresis are about 0.42-0.45. From the pore size distribution curves, there might be some micropores having narrow-necked bottle; a series of interconnected pore is more likely than discrete bottles. FT-IR studies showed that the functional groups such as carboxyl, quinone, and phenol were introduced to ACFs-BQ surface after steam activation. Methylene blue decolorization and iodine adsorption capacity of ACF-BQ increased linearly with the increase of specific surface area and was larger than that of ACF-Kureha at the same specific surface area.

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Low-temperature Synthesis of Graphene-CdLa2S4 Nanocomposite as Efficient Visible-light-active Photocatalysts

  • Zhu, Lei;Oh, Won-Chun
    • Journal of the Korean Ceramic Society
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    • v.52 no.3
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    • pp.173-179
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    • 2015
  • We report the facile synthesis of graphene-$CdLa_2S_4$ composite through a facile solvothermal method at low temperature. The as-prepared products were characterized by X-ray diffraction (XRD) and by Scanning electron microscopy (SEM) with energy dispersive X-ray (EDX) analysis and BET analysis, revealing the uniform covering of the graphene nanosheet with $CdLa_2S_4$ nanocrystals. The as-prepared samples show a higher efficiency for the photocatalytic degradation of typical MB dye compared with P25 and $CdLa_2S_4$ bulk nanoparticles. The enhancement of visible-light-responsive photocatalytic properties by decolorization of Rh.B dye may be attributed to the following causes. Firstly, graphene nanosheet is capable of accepting, transporting and storing electrons, and thus retarding or hindering the recombination of the electrons with the holes remaining on the excited $CdLa_2S_4$ nanoparticles. Secondly, graphene nanosheet can increase the adsorption of pollutants. The final cause is that their extended light absorption range. This work not only offers a simple way to synthesize graphene-based composites via a one-step process at low temperature but also a path to obtain efficient functional materials for environmental purification and other applications.

Analysis of Papers on Curcuma longa Rhizoma for Possibility Evaluation of Therapeutic against dementia (강황의 항치매효과에 대한 체계적인 문헌고찰)

  • Jo, Na Young
    • The Journal of the Society of Korean Medicine Diagnostics
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    • v.22 no.1
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    • pp.11-18
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    • 2018
  • Objectives The incidence of degenerative diseases is increasing as society ages, and this increased the economic burden on society. Oxidative stress was also under suspicion as one of the causes. Recent studies have found that Curcuma longa Rhizoma had antioxidant, anti-inflammatory, antimutagenic, and anticancer effects. Through this study, we figure out trends in Curcuma longa Rhizoma research and evaluate the therapeutic potential of Curcuma longa Rhizoma for dementia. Methods The search was made using domestic and international internet search sites. "Naver academic," "Google scholar," "Korea institute of oriental medicine (KIOM OASIS)," "Korean traditional knowledge portal (KTKP)," "Library of Congress," "Research information sharing service (RISS)," "National Digital Science Links (NDSL)," and "Pub med" are used to search. The searched for words were "turmeric," "Curcuma longa Rhizoma," "antioxidant," and "nerve regeneration." Results It could be seen that a lot of research done on Curcuma longa recently. In previous studies, the most common research disease was cancer. In previous studies, the most common effects of Curcuma longa was antioxidant and anticancer. Curcumin, Vitamin B1, and various essential oils were the functional components of Curcuma longa Rhizoma. Curcuma longa Rhizoma performs DPPH radical scavenging activity and ABTS radical cation decolorization activity; it inhibits NO and iNOS. Conclusion The destruction of nerve cells due to oxidative stress is a cause of dementia. Curcuma longa Rhizoma have antioxidant effects. Therefore, we believed that it is an effective treatment for dementia. Various studies will be made on Curcuma longa Rhizoma.

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Characteristics of high concentration. yield multi discharge type ozonizer for dyeing water treatment (염색폐수 처리용 고농도.고수율 다중방전형 오존발생기의 특성)

  • Lee, Dong-Heon;Song, Hyun-Jig;Lee, Sang-Geun;Lee, Dong-Wook;Park, Won-Zoo;Lee, Kwang-Sik;Jean, Young-Ju;Kim, Sang-Ku
    • Proceedings of the KIEE Conference
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    • 2000.07c
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    • pp.2141-2143
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    • 2000
  • In this paper, high concentration yield multi-discharge type ozonizer (MDO) of new discharge type using superposed silent discharge was designed and manufactured, MDO can be consisted with 3 kind of multi discharge type ozonizer (MDO) in accordance with power supply method that supplying power, which has 180[$^{\circ}$] phase difference, to 3 electrodes and double gap. At the moment, discharge characteristics and ozone generation characteristics of each MDO were investigated in accordance with quantity of supplied gas, the number of MDO, and the shapes of each MDO. In result, ozone generation characteristics of 17185[ppm] and 783[g/kWh] were obtained, and when ozone of 17185 [ppm] was in contact with dyeing water waste, decolorization characteristics was excellent, so it confirmed that MDO could be used as water environment improvement facility.

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The Study of Restoration Technique of Wax-treated Volume for the Annals of the Joseon Dynasty(I) - Evaluation of degradation behavior of reproduced waxy paper - (조선왕조실록 밀랍본 복원기술연구(제1보) - 재현밀랍지의 열화거동평가 -)

  • Jeong, Seon-Hwa;Jeong, So-Young;Seo, Jin-Ho;Lee, Hye-Yun
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.39 no.1 s.119
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    • pp.56-63
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    • 2007
  • The purpose of this research was to identify causes of damage of wax-treated volume of "The Annals of the Joseon Dynasty". As one of the efficient restoration methods, analyses of damaged state of reproduced wax-treated paper through tests of degradation of wax-treated paper under an artificial setting were performed, and in particular, differences between lightness and acidity were observed. On the whole, it was confirmed that yellow wax-treated papers were more stable than white wax-treated papers against artificial aging treatment, which is thought to be because the white wax-treated paper was more affected by a variety of substances interacting with paper than yellow wax-treated paper under artificially aged conditions, which were added in the course of refinement and processing operation such as decolorization and deodorization.

Two Manganese Peroxidases and a Laccase of Trametes polyzona KU-RNW027 with Novel Properties for Dye and Pharmaceutical Product Degradation in Redox Mediator-Free System

  • Lueangjaroenkit, Piyangkun;Teerapatsakul, Churapa;Sakka, Kazuo;Sakka, Makiko;Kimura, Tetsuya;Kunitake, Emi;Chitradon, Lerluck
    • Mycobiology
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    • v.47 no.2
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    • pp.217-229
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    • 2019
  • Two manganese peroxidases (MnPs), MnP1 and MnP2, and a laccase, Lac1, were purified from Trametes polyzona KU-RNW027. Both MnPs showed high stability in organic solvents which triggered their activities. Metal ions activated both MnPs at certain concentrations. The two MnPs and Lac1, played important roles in dye degradation and pharmaceutical products deactivation in a redox mediator-free system. They completely degraded Remazol brilliant blue (25 mg/L) in 10-30 min and showed high degradation activities to Remazol navy blue and Remazol brilliant yellow, while Lac1 could remove 75% of Remazol red. These three purified enzymes effectively deactivated tetracycline, doxycycline, amoxicillin, and ciprofloxacin. Optimal reaction conditions were $50^{\circ}C$ and pH 4.5. The two MnPs were activated by organic solvents and metal ions, indicating the efficacy of using T. polyzona KU-RNW027 for bioremediation of aromatic compounds in environments polluted with organic solvents and metal ions with no need for redox mediator supplements.

Formation of Oxidants and Removal of Dye Rhodamine B using PbO2 Electrode (PbO2 전극을 이용한 산화제 생성과 염료 Rhodaime B 제거)

  • Park, Young-Seek
    • Journal of Korean Society on Water Environment
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    • v.27 no.2
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    • pp.194-199
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    • 2011
  • This study has been carried out to evaluate the performance of $PbO_2$ electrode for the purpose of degradation of N,N-Dimethyl-4-nitrosoaniline (RNO, indicator of OH radical), generation of ozone and decolorization of Rhodamine B (RhB) in water. The effect of the applied current (0.2~1.2 A), electrolyte type (NaCl, KCl and $Na_2SO_4$), electrolyte concentration (0.0~2.5 g/L) and solution pH (3~11) were evaluated. Experimental results showed that RhB and RNO removal were increased with the increase of current, NaCl dosage and decrease of pH. Ozone generation tendencies appeared with the almost similar to the RhB and RNO degradation, except of solution pH (Ozone generation was increased with increase of pH). Optimum current for RhB degradation and consumption of electric power was 1.0 A. The RhB degradation with Cl type electrolyte were higher than that with the sulfate type. Optimum NaCl dosage for RhB degradation was 1.0 g/L.