• 제목/요약/키워드: Decay Curves

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NaSr(PO3)3:Eu2+ 청색 형광체의 온도 의존적 형광 특성 (Temperature Dependent Optical Performance of the NaSr(PO3)3:Eu2+ Blue Phosphors)

  • 윤창용;이상호
    • 한국방사선학회논문지
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    • 제15권3호
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    • pp.391-399
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    • 2021
  • 고상법을 이용하여 Eu 이온이 첨가된 다중인산염 NaSr(PO3)3형광체를 합성하고 탄소열환원법을 통하여 NaSr(PO3)3:Eu2+ 형광체를 완성하였다. X선 회절 측정(XRD)을 통하여 형광체의 결정상을 확인하였다. NaSr(PO3)3:Eu2+ 형광체의 Eu2+ 농도 변화에 따른 발광 방출 및 여기 스펙트럼과 수명시간을 측정하였다. 320 nm 근자외선 여기에서 NaSr(PO3)3:Eu2+ 형광체는 Eu2+의 4f65d → f7(8S7/2) 전이에 따른 420 nm 중심의 밴드를 방출하였다. Eu2+ 첨가 된 형광체의 열적 특성을 증가시키기 위해 온도 의존적 방출 스펙트럼과 형광 감쇠 곡선을 측정하고 형광체의 온도 의존성을 설명하였다. 본 연구로 희토류 이온이 첨가된 NaSr(PO3)3:Eu2+는 디스플레이, 검출기 등에 온도 센서 역할을 할 수 있는 우수한 온도 의존성을 보여준다.

연소물의 질량증가와 연소시간의 상관관계를 고려한 화재곡선 예측 (Prediction of Fire Curves Considering the Relationship between Mass Increase and Combustion Time of Combustibles)

  • 남은준;이태일;지광습
    • 한국구조물진단유지관리공학회 논문집
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    • 제28권2호
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    • pp.9-16
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    • 2024
  • 본 논문에서는 부피단위의 화재곡선을 단위면적당 화재곡선으로 구하여 화재곡선 식을 FDS 표면열방출율법에 대입할 수 있도록 하고자 하였다. 화재곡선을 총 연소특성시간을 고려하여 무차원으로 표현하였으며, 성장구간비 𝛽i, 유지구간비 𝛽s , 감쇄구간비 𝛽d를 고려하여 화재강도에 대한 적절한 비율을 나타내도록 개선하였다. 또한, 질량증가에 따라 변화하는 연소 특성시간 보정함수 𝛾(m/m0)를 도출하였으며, 질량비가 증가함에 따라 성장시간 값을 제어하기 위해 성장구간비 𝛽i를 보정하는 함수 αi(m/m0)를 도출하였다. 이에 따라 기존 데이터를 활용하여 연소물의 기준질량을 선정하고, 질량 증가에 따른 화재곡선을 예측할 수 있는 식을 확립하였다.

Synthesis and color-controllable luminescence in Dy3+-activated CaWO4 phosphors

  • Du, Peng;Yu, Jae Su
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2015년도 제49회 하계 정기학술대회 초록집
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    • pp.170.2-170.2
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    • 2015
  • Enormous interest in trivalent rare-earth (RE) ions activated luminescent materials has been gaining owing to their promising applications in bio-imaging, solar cells, white light-emitting diodes and field-emission displays. Among these trivalent RE ions, dysprosium (Dy3+) was widely investigated due to its unique photoluminescence (PL) emissions. A series of Dy3+-activated CaWO4 phosphors were prepared by a facile high-temperature solid-state reaction method. The X-ray diffraction, PL spectra, cathodoluminescence (CL) spectra as well as PL decay curves were used to characterize the prepared samples. Under ultraviolet light excitation, the characteristic emissions of Dy3+ ions were observed in all the obtained phosphors. Furthermore, the PL emission intensity increased gradually with the increment of Dy3+ ion concentration, reaching its maximum value at an optimized Dy3+ ion concentration. Additionally, color-tunable emissions were obtained in Dy3+-activated CaWO4 system by adjusting the Dy3+ ion concentration and excitation wavelength. Ultimately, strong CL properties were observed in Dy3+-activted CaWO4 phosphors. These results suggested that the Dy3+-activted CaWO4 phosphors may have potential applications in the field of miniature color displays.

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강유전성 고분자인 P(VDF-TrFE)공중합체의 전기광학계수의 완화현상 (Relaxation phenomena of electro-optic coefficient in P(VDF-TrFE) copolymers)

  • 임종선;박광서
    • 한국광학회지
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    • 제12권3호
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    • pp.225-229
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    • 2001
  • 강유전성 고분자인 P(VDF-TrFE) 공중합체의 전기광학계수의 완화현상을 고찰하였다. 이 고분자인 전기광학계수는 단순 반사법에 의해 측정하였고 완화현상은 KWW 확장된 지수 함수꼴로 분석하였다. Tc 근방에서 극화시킨 공중합체들은 시간적으로 더 안정적이였고 온도에 의존하는 완화시간$au$를 Arrhenius 형태로 분석하여 50mol%의 TrFe를 가진 공중합체가 28mol%를 가진 공중합체보다 활성화에너지가 더 컸다. 이를 통해 $60^{\circ}C$에서 극화시킨 50mol%의 TrFE를 가진 공중합체가 더안정적임을 알 수 있다.

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적외선 영역에서의 HgTe 나노입자 광전류 특성 (Photocurrent characteristics of close-packed HgTe nanoparticles in the infrared-wavelength range)

  • 김현석;박병준;김진형;이준우;김동원;조경아;김상식
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2004년도 추계학술대회 논문집 Vol.17
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    • pp.25-28
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    • 2004
  • Photocurrent spectrum, photoresponse, and I-V measurements were made for close-packed HgTe nanoparticles without organic capping materials to investigate their photocurrent characteristics in the infrared range. In absorption and photoluminescence (PL) spectra taken for the close-packed nanoparticles film, the wavelengths of exciton peaks was red-shifted, compared with organic capped HgTe nanoparticles dispersed in solution. This red-shift is caused by the lessening of the exciton binding energy. The I-V curves and photoresponse for the close-packed nanoparticles film reveal their dark current and fast photoresponse with no current decay, respectively. The observation suggests that the HgTe nanoparticles are a very prospect material applicable for photodetectors in the whole IR range.

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Modeling Dynamics of Nonconservative Pollutants in Streams with Pools and Riffles

  • Seo, Il-Won;Yu, Dae-Young
    • 한국수자원학회:학술대회논문집
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    • 한국수자원학회 1993년도 수공학연구발표회논문집
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    • pp.175-182
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    • 1993
  • The complex nature of low flow transport and tranformation of nonconservative pollutants in natural streams with pools and riffles has been investigated using a numerical solution of a proposed mathematical model that is based on a set of mass balance equations describing hydrodynamic processes (advection, dispersion, and mass exchange mechanicms in streams and in storage zones) and chemical processes (reaction or decay). In this study, a mathematical model (named "Storage-Transformation Model") has been developed to predict adequately the non-Fickian nature of mixing and transformation mechanisms for decaying substances in natural streams under low flow conditions. Comparisons between the concentration-time curves predicted usingthe proposed model and the measured stream data shows that the Storage-Transformation Model yields better agreements in the goneral shape, peak concentration and time to peak than the 1-D dispersion model. The result of this study also demonstrates the differences between transport in pool-and-riffle streams versus transport in more uniform channels. The proposed model shows significant improvement over the conventional 1-D disperision model in predicting natural mixing and stroage processes in streams through pools and riffles.

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Pulsed Photostimulated Luminescence of Irradiated Black and White Peppers and Effects of Long-Term Storage

  • Oh, Man-Jin;Yi, Sang-Duk;Jeoung, Hyun-Kyo;Chang, Kyu-Seob;Yang, Jae-Seung;Song, Chi-Kwang
    • Preventive Nutrition and Food Science
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    • 제7권2호
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    • pp.195-200
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    • 2002
  • Changes in accumulated pulsed photostimulated luminescene (PPSL) signals were observed after storage, which affected the ability to detect irradiation in black and white peppers. The PPSL curves were accumulated linearly during the 120 s measurement times, and PPSL signals increased according to irradiation doses. Threshold levels of black and white peppers were below 557$\pm$220 and 503$\pm$92 photon counts in 60 s, and below 679$\pm$351 and 812 $\pm$ 648 photon counts in 120 s, respectively. The PPSL signals of black and white peppers linearly increased with irradiation dose up to 5 kGy, but very little from 5~10 kCy. The accumulated PPSL signals of irradiated black and white peppers had higher decay rates when stored in normal room conditions than in a darkroom Detection of irradiation was possible for up to 12 months after irradiation, if the samples were stored in a darkroom.

Structural and Optical Properties of Yellow-Emitting CaGd2ZrSc(AlO4)3:Ce3+ Phosphor for Solid-State Lighting

  • Kim, Yoon Hwa;Kim, Bo Young;Viswanath, Noolu S.M.;Arunkumar, Paulraj;Im, Won Bin
    • 한국세라믹학회지
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    • 제54권5호
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    • pp.422-428
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    • 2017
  • Single-phase yellow phosphor, $CaGd_{2-x}ZrSc(AlO_4)_3:xCe^{3+}$ ($CGZSA:Ce^{3+}$), possessing cubic symmetry with varied $Ce^{3+}$ concentrations, was synthesized using the solid-state reaction method. The samples were characterized using X-ray diffraction (XRD), excitation spectra, emission spectra, thermal quenching, and decay curves. The cubic phase of $CGZSA:Ce^{3+}$ phosphor was confirmed via XRD analysis. The photoluminescence spectra of $CGZSA:Ce^{3+}$ phosphor demonstrated that the phosphor could be excited at the wavelength of 440 nm; a broad yellow emission band was centered at 541 nm. These results indicate that the phosphors are adequately excited by blue light and have the potential to function as yellow-emitting phosphors for applications in white light-emitting diodes.

시간상관 단일광자 계수법에의한 Rhodamine 6G에서 Malachite Green으로의 에너지 전달 연구 (Study for Energy Transfer from Rhodamine 6G to Malachite Green Using Time Correlated Single Photon Counting Method)

  • 김현수;엄효순;최규관;정홍식;김웅
    • 한국광학회지
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    • 제2권4호
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    • pp.203-208
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    • 1991
  • 모드동기된 아르곤 이온 레이저를 여기광원으로 사용한 시간상관 단일광자 계수장치를 이용하여 에틸렌글리콜 용매 내에서 Rhodamine 6G에서 Malachite Green으로의 비복사 에너지전달과정을 연구하였다. 측정된 donor의 형광소멸곡선을 full-fitting 방법으로 분석 처리하여 acceptor 농도의 변화에 따른 환산농도와 임계전이거리를 구했다. donor의 농도가 acceptor의 농도 보다 클때는 donor-donor의 원거리 쌍극자 모멘트에 의한 에너지 이주 효과를 고려해야하며 Forster 모델 보다 Huber 모델이 더 적절하였다.

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Optical follow-up observation of three long GRBs with SomangNet facilities

  • Paek, Gregory S.H.;Im, MyungShin;Kim, Joonho;Lim, Gu;Jeong, Mankeun;Kang, Wonseok;Kim, Taewoo;Burkhonov, Otabek;Mirazaqulov, Davron;Ehgamberdiev, Shyhrat A.;Seo, Jinguk;Lee, Chung-Uk;Kim, Seung-Lee;Sung, Hyung-Il
    • 천문학회보
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    • 제46권1호
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    • pp.49.5-50
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    • 2021
  • We report the optical follow-up observations of three long γ-ray burst events, GRB 201020A, GRB 201103B and GRB 210104A by the network of telescopes in the SomangNet project. We show light curves, color evolution and SED evolution, and fit them to a single power law function to derive decay index and compare their properties with other long GRBs samples. Also, we show a good observational example that 0.4-1m class telescopes in SomangNet have potential to catch dim light from high red shift object (R>22 mag) by deep imaging. In conclusion, we found that three GRBs have optical afterglow properties of long GRB and our results are consistent with the reports of high energy analysis.

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