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Synthesis, Characterization, Luminescence and Biological Activity of Two Lanthanide Complexes Involving Mixed Ligands

  • Ma, De-Yun;Guo, Hai-Fu;Qin, Liang;Xu, Jun
    • Bulletin of the Korean Chemical Society
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    • v.34 no.9
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    • pp.2774-2780
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    • 2013
  • Two new isostructural dinuclear complexes, $Ln_2(4-cpa)_6(bpy)_2$ (Ln = Eu (1); Tb (2), 4-cpa = 4-chlorophenylacetate, bpy = 2,2'-bipyridine), have been hydrothermally synthesized and characterized by IR spectroscopy, elemental analysis, thermogravimetric analysis (TGA), powder X-ray diffraction and single-crystal X-ray diffraction. The lanthanide ions are bridged by two bidentate and two terdentate carboxylate groups to give centrosymmetric dimers with $Ln{\cdots}Ln$ separations of 3.967(2) and 3.956(3) ${\AA}$, respectively. Each metal atom is nine-coordinate and exhibits a distorted tricapped trigonal prismatic geometry. Three-dimensional fluorescence spectra show that both 1 and 2 emit bright red and green luminescence at room temperature, with long lifetimes of up to 0.369 ms (at 614 nm) and 0.432 ms (at 543 nm), respectively. Moreover, poor luminescence efficiency has been noted for complex 2. The 4-Hcpa ligand and complexes 1-2 have been screened for their phytogrowth-inhibitory activities against Brassica napus L. and Echinochloa crusgalli L., and the results are compared with the activity of quizalofop-P-ethyl.

Optimal Power Control Strategy for Wind Farm with Energy Storage System

  • Nguyen, Cong-Long;Lee, Hong-Hee
    • Journal of Electrical Engineering and Technology
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    • v.12 no.2
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    • pp.726-737
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    • 2017
  • The use of energy storage systems (ESSs) has become a feasible solution to solve the wind power intermittency issue. However, the use of ESSs increases the system cost significantly. In this paper, an optimal power flow control scheme to minimize the ESS capacity is proposed by using the zero-phase delay low-pass filter which can eliminate the phase delay between the dispatch power and the wind power. In addition, the filter time constant is optimized at the beginning of each dispatching interval to ensure the fluctuation mitigation requirement imposed by the grid code with a minimal ESS capacity. And also, a short-term power dispatch control algorithm is developed suitable for the proposed power dispatch based on the zero-phase delay low-pass filter with the predetermined ESS capacity. In order to verify the effectiveness of the proposed power management approach, case studies are carried out by using a 3-MW wind turbine with real wind speed data measured on Jeju Island.

Development with multi-layer passivation films for OLED with longer life time

  • Jung, Jae-Hoon;Lim, Jong-Sun;Rhee, Jung-Soo;Kim, Hoon;Lee, Sang-Pil;Kim, Nam-Deog;Ju, Byeong-Kwon;Lee, Joo-Won;Chung, Kyu-Ha
    • 한국정보디스플레이학회:학술대회논문집
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    • 2004.08a
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    • pp.684-687
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    • 2004
  • We have developed multi-layer passivation films of UV-polymerized film/inorganic composite film to improve the long lifetime of passivated OLEDs for very thin flat panel applications. Preliminary lifetime to half initial luminance ($L_{o}{\sim}\;3,000\;cd/m^2$) of order 300 Hr is achieved on the conventional encapsulated test pixel using a passive matrix drive at room temperature; 570 Hr lifetime is achieved on a de tested multi-layer passivated 9$mm^2$ test pixel.

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Measuring AGN Core-shift Effect by Extended KVN with Global Baselines

  • Jung, Taehyun;Dodson, Richard;Han, Seog-Tae;Byun, Do-Young;Sohn, Bong Won;Rioja, Maria J.;Honma, Mareki;Stevens, Jamie;de Vincente, Pablo
    • The Bulletin of The Korean Astronomical Society
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    • v.40 no.2
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    • pp.43.3-44
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    • 2015
  • Very Long Baseline Interferometry (VLBI) at millimeter wavelengths results in the highest angular resolutions achieved in astronomy and has a unique access to emission regions that are inaccessible with any other approach or at longer wavelengths. The simultaneous multi-frequency VLBI system in the Korean VLBI Network (KVN) is considered one of the most effective systems for compensating the atmospheric phase fluctuations, which is particularly bothersome at mm-VLBI. We have been demonstrating its performance and uniqueness at mm-VLBI observations. As a results, international VLBI partners from Japan, China, Australia and EU have expressed their interest on the KVN style simultaneous multi-frequency system. In this talk, we will report the activities for extending the simultaneous multi-frequency system to global VLBI network and introduce its science driver, measuring AGN core-shift effects.

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K and Cs Doped Ag/Al2O3 Catalyst for Selective Catalytic Reduction of NOx by Methane

  • Rao, Komateedi N.;Yu, Chang-Yong;Lack, Choi-Hee;Ha, Heon-Phil
    • Journal of Powder Materials
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    • v.18 no.6
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    • pp.510-516
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    • 2011
  • In the present study, potassium and caesium doped Ag/$Al_2O_3$ catalysts were synthesized by simple wet impregnation method and evaluated for selective catalytic reduction (SCR) of NOx using methane. TEM analysis and diffraction patterns demonstrated the finely dispersed Ag particles. BET surface measurements reveal that the prepared materials have moderate to high surface area and the metal amount found from ICP analysis was well matching with the theoretical loadings. The synthesized K-Ag/$Al_2O_3$ and Cs-Ag/$Al_2O_3$ catalysts exhibited a promotional effect on deNOx activity in the presence of $SO_2$ and $H_2O$. The long-term isothermal studies at $550^{\circ}C$ under oxygen rich condition showed the superior catalytic properties of the both alkali promoted samples. The crucial catalytic properties of materials are attributed to NO adsorption properties detected by the NO TPD.

An efficient ship detection method for KOMPSAT-5 synthetic aperture radar imagery based on adaptive filtering approach

  • Hwang, JeongIn;Kim, Daeseong;Jung, Hyung-Sup
    • Korean Journal of Remote Sensing
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    • v.33 no.1
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    • pp.89-95
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    • 2017
  • Ship detection in synthetic aperture radar(SAR)imagery has long been an active research topic and has many applications. In this paper,we propose an efficient method for detecting ships from SAR imagery using filtering. This method exploits ship masking using a median filter that considers maximum ship sizes and detects ships from the reference image, to which a Non-Local means (NL-means) filter is applied for speckle de-noising and a differential image created from the difference between the reference image and the median filtered image. As the pixels of the ship in the SAR imagery have sufficiently higher values than the surrounding sea, the ship detection process is composed primarily of filtering based on this characteristic. The performance test for this method is validated using KOMPSAT-5 (Korea Multi-Purpose Satellite-5) SAR imagery. According to the accuracy assessment, the overall accuracy of the region that does not include land is 76.79%, and user accuracy is 71.31%. It is demonstrated that the proposed detection method is suitable to detect ships in SAR imagery and enables us to detect ships more easily and efficiently.

DEEP-South: A New Taxonomic Classification of Asteroids

  • Roh, Dong-Goo;Moon, Hong-Kyu;Shin, Min-Su;Lee, Hee-Jae;Kim, Myung-Jin
    • The Bulletin of The Korean Astronomical Society
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    • v.41 no.2
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    • pp.49.1-49.1
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    • 2016
  • Asteroid taxonomy dates back to the mid-1970's and is based mostly on broadband photometric and spectroscopic observations in the visible wavelength. Different taxonomic classes have long been characterized by spectral slope shortward of 0.75 microns and the absorption band in 1 micron, the principal components. In this way, taxonomic classes are grouped and divided into four broad complexes; silicates (S), carbonaceous (C), featureless (X), Vestoids (V), and the end-members that do not fit well within the S, C, X and V complexes. The past decade witnessed an explosion of data due to the advent of large-scale asteroid surveys such as SDSS. The classification scheme has recently been expanded with the analysis of the SDSS 4th Moving Object Catalog (MOC 4) data. However, the boundaries of each complex and subclass are rather ambiguously defined by hand. Furthermore, there are only few studies on asteroid taxonomy using Johnson-Cousins filters, and those were conducted on a small number of objects, with significant uncertainties. In this paper, we present our preliminary results for a new taxonomic classification of asteroids using SMASS, Bus and DeMeo (2014) and the SDSS MOC 4 datasets. This classification scheme is simply represented by a triplet of photometric colors, either in SDSS or in Johnson-Cousins photometric systems.

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Improving Durability Performance of Reinforced Concrete Structures with Probabilistic Analysis

  • Ferreira, Rui Miguel
    • International Journal of Concrete Structures and Materials
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    • v.2 no.2
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    • pp.137-143
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    • 2008
  • In recent years, much research work has been performed on durability design and long-term performance of concrete structures in marine environments. In particular, the development of new procedures for probability-based durability design has been shown to provide a more realistic basis for the analysis. This approach has been successfully applied to several new concrete structures, where requirements for a more controlled durability and service life have been specified. For reinforced concrete structures in a marine environment, it is commonly assumed that the dominant degradation mechanism is the corrosion of the reinforcement due to the presence of chlorides. The design approach is based on the verification of durability limit states, examples of which are: depassivation of reinforcement, cracking and spalling due to corrosion, and collapse due to cross section loss of reinforcement. With this design approach the probability of failure can be determined as a function of time. In the present paper, a probability-based durability performance analysis is used in order to demonstrate the importance of the durability design approach of concrete structures in marine environments. In addition, the sensitivity of the various durability parameters affecting and controlling the durability of concrete structures in a marine environment is studied. Results show that the potential of this approach to assist durability design decisions making process is great. Based the crucial information generated, it is possible to prolong the service life of structures while simultaneously optimizing the final design solution.

Applications Development: a Value-Laden Process

  • Cayaba, Christobal;Pablo, Zelinna
    • Asia pacific journal of information systems
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    • v.24 no.3
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    • pp.371-391
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    • 2014
  • A long-drawn out debate in the field of technology is whether it is value-neutral or value-laden. While some have argued that this debate has been resolved given the increasingly accepted view that technology is socially constructed, this is still not reflected in mainstream research which still assumes that technology is neutral. What is clear is that both views tend to be linked to studies that primarily focus on explicit forms of technology such as technological designs and their usage. These studies, though significant, may be limited in terms of an underemphasis on the process by which these technologies emerge, a process that requires decision-making activities made by different stakeholders and thus involves value judgments. In order to understand the extent of value-neutrality or value-ladenness of technologies, therefore, it is important to examine not only the final outcomes but also the process involved in technological development (including the artifacts created and used). In this study, we explored how values may be embedded in a specific IT application, and in cases of conflict of values, how they are prioritized. We did this in the context of applications development through an examination of the stages ranging from requirements analysis to coding to testing and deployment.

The effect of lead on matrix metalloproteinase-9 expression in rat primary glial cells

  • Park, Min-Sik;Lee, Woo-Jong;Kim, Young-Eun;Ko, Kwang-Ho
    • Proceedings of the Korean Society of Applied Pharmacology
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    • 2003.11a
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    • pp.84-84
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    • 2003
  • Lead has long been considered as a toxic environmental pollutant, which severely damages central nervous system. Lead can cause hypo- and de-myelination, and glial cells are closely related with myelination or demyelination. Matrix metalloproteinases (MMPs) are proteolytic enzymes that are involved in the remodelling of the extracellular matrix in a variety of physiological and pathological processes. MMPs also seem to be important in the pathogenesis of inflammatory demyelinating diseases of the central and peripheral nervous system. In this study, we investigated whether lead affects MMP-9 expression in rat primary glial cells. Treatment of 0.1-5 ${\mu}$M lead dose- and time-dependently increased MMP-9 expression in rat primary glial cells. The activity of MMPs was determined using zymography. Lead activated Erk(1/2) but neither of the other endogenous MAP kinases, p38 or JNK. Inhibition of Erk(1/2) activation by PD98059, a MEK inihibitor, prevented lead-induced expression of MMP-9. The results of the present study suggest that lead intoxication may adversely affect brain function at least in part by inducing MMP-9 expression through Erk(1/2) activation in primary glial cells.

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