• Polymer(Korea)
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• v.36 no.2
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• pp.245-250
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• 2012

Branched polypropylenes (PP) with long chain branch were prepared by solid state reaction with three different branching agent of 0.3 wt% content. The chemical structures, non-isothermal crystallization behavior and complex viscosity of the branched PP were investigated by FTIR, DSC, optical microscope, and dynamic rheological measurement. The chemical structure of the branched PP was confirmed by the existence of =C-H stretching peak of the branching agent at 3100 $cm^{-1}$. There was no distinct change in melting temperature in case of PP-D-0-3 and PP-F-0-3, but PP-H-0-3 indicated a decrease in melting temperature. The decrease in melting temperature was interpreted by the fact that the degradation reaction of PP was more dominant than branched reaction, and confirmed by a decrease in complex viscosity. The non-isothermal crystallization behavior of the branched PP was analyzed using by Avrami equation. The Avrami exponent of PP was 3, and the values of the branched PP with DVB and FS were below 3. The activation energy of PP calculated by Kissinger method was 25 kJ/mol, and there were no big difference in activation energies of the branched PPs compared to PP.

• Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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• 2010.05a
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• pp.609-611
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• 2010

IPTV(Internet Protocol Television)is the point in commercial and broadcast content from the numerous channels that are growing exponentially, Many people with mobile devices anywhere, anytime you want to use IPTV, demand will increase. Numerous channels for collecting information about EPG (Electronic Program Guide) service, IP (Internet Protoco) communications using a fast search of content for broadcast EPG is time to take advantage of the service. Using the current wired network, the Android-based IPTV services to take advantage of the EPG in the mobile environment to provide an environment being studied, and Country of the European digital broadcast standard DVB-MHP standard is followed by subsequent research and development of the EPG service is required. In this study, using the existing wired network, IPTV EPG service information of the channel in a mobile environment user-friendly as possible by providing channels for EPG service information to users quickly and easily search for content to provide an environment and Android-based mobile IPTV environment to take advantage of the EPG service channels of broadcast channels with in the EPG service for users to gather information retrieval system is proposed.

• Korean Journal of Materials Research
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• v.6 no.8
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• pp.761-767
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• 1996

The composite fiber adsorbents containing amidoxime group were prepared and separation properties of uranium ion from seawater were investigated. The amount of uranium adsorption was increased with an increase in adsorption time. When the mole ratio of monomer and comonomer, such as acrylonitrile (AN), tetraethyleneglycol dimethacrylate(TEGMA), and divinylbenzene (DVB), were 1 :0. 1 :0.003, this resin showed the maximum adsorption ability for uranium at a level of pH 8. The amount of uranium adsorption was also increased linearly to one hour with an increase in the content of adsorbent which was added in the composite fiber adsorbents(CFA). The maximum adsorption for uranium of CF A showed at $25^{\circ}C$. Hence, the adsorption ability of CF A for calcium and magnecium ions were increased gradually by the recycling of adsorption and disorption, the adsorption content of their on were 0.3, 0.9mmole/g-adsorbents, respectly. It also showed that the adsorption contents of Ca and \1g ions were much lower than them of uranium. The desorption of uranium on the CF A was carried out , bout 100% within 30min, and the desorption rate of various CF A were equalled.

• Applied Chemistry for Engineering
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• v.22 no.6
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• pp.679-684
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• 2011

Branched polypropylenes (LCB-PP) with a long chain branch were prepared by the solid-state and molt-state reaction. Divinylbenzene (DVB), 1,4-benzenediol (RES), and furfuryl sulphide (FS) were used as branching agents of fabricate LCB-PP/silicate composites. Chemical structures, thermal properties, and rheological properties of the LCB-PP were determined by FT-IR, DSC, TGA, and dynamic rheometer (ARES). The chemical structure of the LCB-PP was confirmed by the existence of =C-H stretching peak of the branching agent at $3100cm^{-1}$. From DSC and TGA results, the melting reaction was more effective than the solid state reaction in the manufacture of LCB-PP, which was additionally certified by rheological properties. Based on rheological properties, FS was the best for branching efficiency of PP. Compared to PP, LCB-PPs indicated an increase of complex viscosity in the low frequency and shear thinning tendency, and G'-G" plot represented an increase in elasticity and the heterogeneousness in a melt state. Rheological properties of LCB-PP/silicate composites were observed with the silicate content. When 5 wt% silicate was added in LCB-PP, distinct changes in the shear thinning and the slope of G'-G" plots were observed.

• Journal of the Korean Chemical Society
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• v.29 no.2
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• pp.144-150
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• 1985

For the separation of boron isotopes, aminated polystyrenedivinylbenzene ion-exchange resins were prepared by chloromethylation of styrene-divinylbenzene copolymer (DVB 10%), followed by the reaction of methylamine. During the preparation of styrene-divinylbenzene copolymer, heptane for the porous resin and toluene for the non-porous resin were used as diluent, and the pore volume of the resins was determined by mercury porosimeter. In both water and aqueous alcohol solutions, the distribution coefficient of boric acid was decreased in accordance with increasing the alcohol concentration and the number of carbon atoms in the alcohol molecules. As a result of separatioin of boron isotope with nonporous and porous resin in water solvent, the separation efficiency of porous resin is better than that of the nonporous, and the result in both water and 50% methyl alcohol solvent relevant to nonporous resin indicated that the latter was better than the former.

• Bulletin of the Korean Chemical Society
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• v.25 no.2
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• pp.271-279
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• 2004

The aroma component of Hallabong peel has been characterized by GC-MS with two different extraction techniques: solid-phase trapping solvent extraction (SPTE) and headspace solid-phase microextraction (HSSPME). Aroma components emitted from Hallabong peel were compared with those of other citrus varieties: lemon, orange and grapefruit by SPTE and GC-MS. d-Limonene (96.98%) in Hallabong was the main component, and relatively higher peaks of cis- ${\beta}$-ocimene, valencene and -farnesene were observed. Other volatile aromas, such as sabinene, isothujol and ${\delta}$-elemene were observed as small peaks. Also, principal components analysis was employed to distinguish citrus aromas based on their chromatographic data. For HSSPME, the fiber efficiency was evaluated by comparing the partition coefficient ($K_{gs}$Kgs) between the HS gaseous phase and HS-SPME fiber coating, and the relative concentration factors (CF) of the five characteristic compounds of the four citrus varieties. 50/30 ${\mu}$m DVB/CAR/PDMS fiber was verified as the best choice among the four fibers evaluated for all the samples.

• Proceedings of the Korean Society of Broadcast Engineers Conference
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• 2014.06a
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• pp.243-245
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• 2014

본 논문에서는 OFDM(Orthogonal Frequency Division Multiplexing)시스템에서 OFDM 심벌 타이밍 옵셋에 따른 4096QAM 의 uncoded-BER(Bit Error Rate) 및 성상도를 측정하였다. uncoded-BER 은 수신기의 FEC(Forward Error Correction) 복호기 이전에서 측정된 BER 을 의미한다. 측정을 위해, OFDM 을 사용하는 DVB-C2(Digital Video Broadcasting for Cable Systems 2) 송수신기를 FPGA(Field Programmable Gate Array)를 이용하여 구현하였으며, OFDM 심벌의 CP(Cyclic Prefix)를 이용하여 OFDM 심벌 동기를 수행하였다. 일반적으로, OFDM 심벌 동기는 OFDM 심벌에서 CP 가 반복된다는 특성을 이용한 상관기를 사용한다. 또한, ISI(Inter Symbol Interference) 및 ICI(Inter Channel Interference)를 최소화하기 위해, 채널의 최대 지연시간을 고려하여 CP 내에서 OFDM 심벌 동기가 획득된다. 이럴 경우 수신기에서는 각 부반송파에 할당된 QAM 심벌들의 위상 회전이 발생하지만, 등화기에서 이러한 위상 회전이 보상된다. 부반송파에 할당된 파일롯 심벌들을 이용하여 채널 추정 및 보상을 하는 등화기에서, 파일롯 심볼들도 OFDM 심벌 타이밍 옵셋에 의해 위상회전이 발생하기 때문에 채널 추정 값에 영향을 미친다. 따라서, 본 논문에서는 4096QAM 과 ZF-LE(Zero Forcing Linear Equalizer)를 사용한 경우, OFDM 심벌 타이밍 옵셋에 따른 uncoded-BER 및 성상도의 측정 결과를 제시하였다.

• Journal of the Korean Society of Tobacco Science
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• v.35 no.1
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• pp.7-12
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• 2013

A Solid-phase micro extraction(SPME) was evaluated as a tool for headspace sampling of tobacco samples. Several experimental parameters (sampling temperature, pH, and type of SPME fibers) were optimized to improve sampling efficiency in two aspects ; maximum adsorption and selective adsorption of volatile organic acids onto SPME fibers. Among four types of SPME fibers such as PDMS(Polydimethylsiloxane), PA(Polyacrylate), Car/PDMS (Carboxen/Polydimethylsiioxane) and PDMS/DVB(Polydimethylsiioxane/Divinylbenzene) which were investigated to determine the selectivity and adsorption efficiency. A variety of tobacco samples such as flue cured, burley and oriental were used in this study. The effect of these parameters was often dominated by the physical and chemical nature (volatility, polarity) of target compounds. This method allowed us to make important improvements in selectivity and sensitivity. The Car/PDMS fiber was shown to be the most efficient at extracting the 10 selected volatile organic acids. The parameters were optimized: $80^{\circ}C$ adsorption temperature, 30 min of adsorption time, $240^{\circ}C$ desorption temperature, 1 min of adsorption time.

• The Journal of the Korea Contents Association
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• v.10 no.8
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• pp.59-65
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• 2010

This paper proposes an implementation of a hardware module for transmitting MPEG-2 TS data over the internet protocol (IP)-based network. This implementation consists of two modules; one is an encapsulation module which bridges between n TS packets, where $1\;{\leq}\;n\;{\leq}\;7$, and an IP packets, the other is a packet conversion module which extracts an DSM-CC PS packet from consecutive TS packets and then reconstructing an IP packet. So, these IP packets are carried over 150 megabits per second. Although overall work flow of the proposed DeMUX is based on the reference design of ALTERA, the DeMUX is enhanced by modifying it and performs more functions by adding a packet conversion module. The DeMUX is described by Verilog-HDL (hardware description language) and shows the faithful functionality and throughput through the simulation.

• Proceedings of the Korean Society of Broadcast Engineers Conference
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• 2011.07a
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• pp.466-469
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• 2011

최근 무선전송에서 SISO(single input singe output) 시스템의 전송률이 샤논 한계(Shannon limit)에 근접함에 따라, 이것을 극복하여 더 높은 데이터 전송률을 얻기 위해 MIMO(multiple input multiple output) 시스템에 대한 연구가 활발하게 이루어지고 있다. 현재 진행 중인 DVB-NGH 시스템 표준화에도 전송률 개선을 위해 MIMO SM(Spatial Multiplexing) 기술에 대해 고려하고 있으며, 방송 시스템 내 송수신 안테나들 간 상관(correlation)이 발생하는 경우에 성능 개선을 위해 Precoding과 MIMO SM을 결합한 $2{\times}2$ 구조의 MIMO SM 방법이 제안되었다. 이 방법은 두 개의 송신안테나에 모두 16QAM 신호가 전송되는 경우와 두 송신안테나에 각각 16QAM, QPSK 신호가 전송되는 경우를 포함하고 있다. 이때 고출력 증폭기(high power amplifier) 전단에서 두 송신 안테나에 서로 다른 변조가 적용되는 경우에 PAPR(peak-to-average power ratio)이 달라서 고출력 증폭기 출력단의 송신전력 차이로 인해 각 신호의 방송권역(coverage)이 같지 않은 문제가 발생한다. 본 논문은 이러한 문제를 극복하기 위해 $2{\times}2$ MIMO SM 방식에서 송신 안테나별로 신호의 변조방식이 서로 다른 경우에 송신신호의 PAPR을 같게 하여 증폭기 출력단에서 각 송신신호의 전력이 동일하게 할 수 있는 방법을 제안한다. 제안한 방법은 수신기의 복잡도를 증가시키지 않으면서 두 송신 신호의 방송권역을 동일하게 한다.