• Title/Summary/Keyword: DSC analysis

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Comparison of Differential Scanning Calorimetry with Enzymatic Method for the Determination of Gelatinization Degree of Corn Starch (DSC에 의한 전분의 Endothermic peak와 효소분석법에 의한 호화도 비교)

  • Lee, Boo-Yong;Mok, Chul-Kyoon;Lee, Cherl-Ho
    • Korean Journal of Food Science and Technology
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    • v.25 no.4
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    • pp.400-403
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    • 1993
  • Gelatinization degrees of torn and waxy corn starches in the low-moisture environment were determined by DSC thermogram and enzymatic analysis, the results were compared each other As the moisture content increased from 20% to 70%, the enthalpy of endothermic peak of starch increased linearly in DSC thermograms. When the moisture content exceeded above 70%, the DSC enthalpy of starch remained constant in DSC thermogram. The enthalpies for gelatinization of corn and waxy corn starches were 3.23 cal/g and 4.2 cal/g, respectively. When gelatinization degrees of starches were measured by enzymatic analysis, the gelatinization degree increased linearly as the moisture content increased from 20% to 80%. A linear correlation between DSC and enzymatic analysis was obtained only when the moisture content was under 70%.

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Electrochemical Impedance Spectroscopy Analysis on the Dye-sensitized Solar Cell with Different $TiO_2$ thicknesses ($TiO_2$ 두께에 따른 염료감응형 태양전지의 전기화학적 임피던스 분석)

  • Kim, Hee-Je;Lee, Jeong-Gee;Seo, Hyun-Woong;Son, Min-Kyu;Kim, Jin-Kyoung;Prabalkar, K.;Shin, In-Young
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.58 no.12
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    • pp.2425-2430
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    • 2009
  • Dye-sensitized solar cell(DSC) is composed of a dye-adsorbed nanoporous $TiO_2$ layer on fluorine-doped tin oxide(FTO) glass substrate, electrolyte, and platinium doped counter electrode. Among these, a dye-absorbed nanoporous $TiO_2$ layer plays an important role in the performance of the DSC because the injected electrons from excited dye molecules move through this layer. And the condition of $TiO_2$ layer such as the morphology and thickness affects on the electron movement. Therefore, the performances and the efficiency of DSC change as the thickness of $TiO_2$ layer is different. Electrochemical Impedance Spectroscopy(EIS) is the powerful analysis method to study the kinetics of electrochemical and photoelectrochemical processes occurring in the DSC especially the injected electron movements. So we analyzed the DSCs with different $TiO_2$ thicknesses by using EIS to understand the influence of the $TiO_2$ thickness to the performance of the DSC clearly. Finally, we got the EIS analysis on the DSC with different $TiO_2$ thickness from the internal resistance of the DSC, the electron life time and the amount of dye molecules.

Development of Modified Disturbed State Concept Model for Liquefaction Analysis (액상화 해석을 위한 수정교란상태개념 모델 개발)

  • Park, Keun-Bo;Choi, Jae-Soon;Park, Inn-Joon;Kim, Ki-Poong;Kim, Soo-Il
    • Journal of the Korean Geotechnical Society
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    • v.24 no.3
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    • pp.35-51
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    • 2008
  • In this paper, the application of the DSC model to the analysis of liquefaction potential is examined through experimental and analytical investigations. For more realistic description of dynamic responses of saturated sands, the DSC model was modified based on the dynamic effective stress path and excess pore pressure development. Both static and cyclic undrained triaxial tests were performed for sands with different relative densities and confining stresses. Based on test results, a classification of liquefaction phases in terms of the dynamic effective stress path and the excess pore pressure development was proposed and adopted into the modified DSC model. The proposed methods using the original and modified DSC models were compared with examples with different relative densities and confining stresses. Based on the comparisons between the predicted results using the original and modified DSC models and experimental data, the parameters required to define the model were simplified. It was also found that modified model more accurately simulate initial liquefaction and dynamic responses of soil under cyclic undrained triaxial tests.

Implementation of DSC Model for Clay-pile Interface Under Dynamic Load (동하중을 받는 점토-파일 접촉면 거동모사를 위한 DSC 모델의 수치해석적 이용)

  • Park, Inn-Joon;Yoo, Ji-Hyeung
    • Journal of the Korean Geotechnical Society
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    • v.19 no.3
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    • pp.93-104
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    • 2003
  • The Disturbed State Concept (DSC) model, with simplified unloading/reloading formulation, is implemented in a nonlinear dynamic finite element program fur porous media named DSC_DYN2D. In this research, the DSC constitutive model is utilized using the HiSS model for relative intact (RI) part and the critical state model for the fully adjusted (FA) part in the material. The general formulation for implementation is developed. The cyclic loading tests from the field load test data on a pile segment were numerically simulated using the finite element program DSC_DYN2D and compared with field measurements and those from the previous analysis with the HiSS model. The DSC predictions show improved agreement with the field behavior of the pile compared to those from the HiSS model. Overall, the computer procedure with the DSC model allows improved and realistic simulation of the complex dynamic soil-structure interaction problems.

The Effect of DSC Analysis Condition on the Glass Transition Temperature of curred Epoxy This paper studies on the effect of DSC(Differential Scanning Calorimeter) analysis condition on the glass transition temperature of silica filled epoxy network polymer used for ultra-high voltage apparatus. The effects of temperature scanning rate specimen size and gas flow rate on measured glass transition temperature have been studied in order to select optimum thermal analysis condition. (에폭시 경화물 DSC에 의한 유리전이 온도 측정의 분석조건 의존성)

  • 오무원;권혁삼
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1994.05a
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    • pp.30-33
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    • 1994
  • This paper studies on the effect of DSC(Differential Scanning Calorimeter) analysis condition on the glass transition temperature of silica filled epoxy network polymer used for ultra-high voltage apparatus. The effects of temperature scanning rate specimen size and gas flow rate on measured glass transition temperature have been studied in order to select optimum thermal analysis condition.

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Study on the Thermal Property and Aging Prediction for Pressable Plastic Bonded Explosives through ARC(Heat-wait-search method) & Isothermal Conditions (ARC(Heat-wait-search method)와 Isothermal 조건을 이용한 압축형 복합화약의 열적 특성 및 노화 예측 연구)

  • Lee, Sojung;Kim, Seunghee;Kwon, Kuktae;Jeon, Yeongjin
    • Journal of the Korean Society of Propulsion Engineers
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    • v.22 no.4
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    • pp.55-60
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    • 2018
  • The thermal property is one of the most important characteristics in the field of energetic materials. Because energy materials release decomposition heat, differential scanning calorimetry (DSC) is frequently used for thermal analysis. However, thermodynamic events, such as melting can interfere with DSC kinetic analysis. In this study, we use isothermal mode for DSC measurement to avoid thermodynamic issues. We also merge accelerating rate calorimetry(ARC) data with DSC data to obtain a robust prediction results for small scale samples and for large scale samples as well. For the thermal property prediction, advanced kinetics and technology solutions(AKTS) programs are used.

Cure Kinetics of Epoxy/Diamine System Modified with Malononitrile by Barrett Method and Integral Method (Malononitrile에 의해 개질된 Epoxy/Diamine계의 경화반응 속도론: Barrett Method와 Integral Method)

  • Cheon, In-Suk;Don, Yun-Seung;Sim, Mi-Ja;Kim, Sang-Uk
    • Korean Journal of Materials Research
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    • v.4 no.5
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    • pp.574-580
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    • 1994
  • This study is about cure kinetics of DGEBA/MDA/MN(malononitrile) system by Barrett method and Integral method using DSC dynamic run. Curing behavior was shown through DSC and the heat change involved in a reaction could be measured directly with DSC. The kinetic parameters such as activation energy, pre-exponential factor and reaction order were given by Barrett method and Integral method obtained in an assumption that the area of DSC enthalpic analysis curve was propotional to the enthalpic change.

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A Study on Domestic Shared University Operation Case Analysis: Focusing on DSC(Daejeon·Sejong·Chungnam) Platform University (국내 공유대학 운영 사례 분석: DSC(대전·세종·충남) 공유대학을 중심으로)

  • Kim, Donghyeun;Hwang, Youngsik;Bae, Yura;Kim, Taehoon
    • Journal of Engineering Education Research
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    • v.26 no.4
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    • pp.47-57
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    • 2023
  • This paper examines the characteristics of shared universities in Korea and seeks future development directions from the analysis of its operation. This study overviews the current status of students and the characteristics of each major in the DSC Shared University. This provides the future improvement direction and analyzes the survey of attending students. The results shows the most DSC students are engineering students, and they are taking classes centering on the major courses opened by their school. Future direction of shared universities include the recruitment of students from various backgrounds, expansions of enrollment in other schools' curriculum.

Analyzing the Possibility of the Building Integrated Photovoltaic with DSC by the Case Studies (사례연구를 통한 DSC에 의한 BIPV 가능성 분석 연구)

  • Lee, Eung-Jik
    • The Journal of Sustainable Design and Educational Environment Research
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    • v.16 no.2
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    • pp.54-63
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    • 2017
  • The various colors and transparency of DSC and operability unrelated with directions greatly expand the use of BIPV, as a multi-functional composite of module. Therefore the possibility of DSC BIPV is examined by the case study and the analysis and then its applicability is examined. Most of the DSC BIPVs, which are found through a total of six case studies and analyzes in Korea and abroad, are mainly implemented with window glass and shading devices. This is related to the DSC transparency property. Improvements are due to the irritation of the eye due to the color of the red module. Therefore, it is important to take into account the color of the BIPV window depending on the use of the building and the room. Meanwhile, some colors of application model may stimulate eyes and such colors should be considered by use of buildings and rooms in the application of BIPV window. DSC BIPV has prospective diffusibility with the development of flexible module for the application of building surface.

Kinetics analysis of energetic material using isothermal DSC (등온 DSC를 이용한 고에너지 물질의 정밀 반응 모델 기법 개발)

  • Kim, Yoocheon;Park, Jungsu;Kwon, Kuktae;Yoh, Jai-ick
    • 한국연소학회:학술대회논문집
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    • 2015.12a
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    • pp.219-222
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    • 2015
  • The kinetic analysis of energetic materials using Differential Scanning Calorimetry (DSC) is proposed. Friedman Isoconversional method is applied to DSC experiment data and AKTS software is used for analysis. The frequency factor and activation energy are extracted as a function of product mass fraction. The extracted kinetic scheme does not assume multiple chemical steps to describe the response of energetic materials; instead, multiple set of Arrhenius factors are used in describing a single global step. The proposed kinetic scheme has considerable advantage over the standard method based on One-Dimenaionl Time to Explosion (ODTX). Reaction rate and product mass fraction simulation are conducted to validate extracted kinetic scheme. Also a slow cook-off simulation is implemented for validating the applicability of the extracted kinetics scheme to a practical thermal experiment.

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