• 제목/요약/키워드: DOC

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Variations of DOC and Phenolics in Pore-water of Peatlands (이탄습지 공극수내 용존유기탄소와 페놀계열 물질의 변화도)

  • Freeman, Chris;Kim, Seon-Young;Kang, Ho-Jeong
    • Korean Journal of Ecology and Environment
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    • 제35권4호통권100호
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    • pp.306-311
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    • 2002
  • The amount and composition of dissolved organic carbon in wetlands are of great importance for their influence in secondary productivity, various biogeochemical processes, and aquatic ecosystem functions. In the present study, we measured variations of DOC and phenolics concentrations in pore-water of three northern peatlands (bog, fen, and swamp) over a 1-year period. General microbial activity (soil respirometry) and phenol oxidase enzyme activity were determined in the same peatlands to elucidate mechanisms underlying the differences in DOC and phenolics contents. The concentrations of DOC varied 25.5-45.4 (bog),29.2-71.4 (fen), and 13.5-87.6 (swamp) mg/L, while phenolic concentrations ranged 13.3-48.1 (bog), 7.6-29.5(fen) , and 4.9-30.8 (swamp) mg/L. The seasonal variations of DOC and phenolics in the swamp suggest that litterfall may be one of the most important factors for the DOC dynamics in such systems. The lowest microbial activity and phenol oxidase activity were found in the bog, which appears to Induce high percentage of phenolic contents in pore-water from bogs. It is also suggested that not only the DOC concentrations but also composition of DOC is of great importance in wetland biogeochernistry.

Effects of Organic Matter Concentration in Soil on Phytoavailability of Cadmium in Medicinal Plants

  • Noh, Yong-dong;Kim, Kwon-Rae;Kim, Won-Il;Jung, Ki-Yuol;Hong, Chang Oh
    • Korean Journal of Soil Science and Fertilizer
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    • 제48권5호
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    • pp.319-325
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    • 2015
  • The safety of plant species used as a source for herbal medicines and dietary supplements has recently been questioned due to poisonings associated with the presence of cadmium (Cd) in these plants. These plants can derive Cd from their presence in the soil. Organic matter (OM) concentrations in soils could affect the availability of Cd for plants. To determine the effect of OM concentration in soil on the concentration of plant available Cd and uptake of this toxic element by medicinal plants, soil and plant samples were collected from 102 fields supporting for 5 species of medicinal plants in 6 province of South Korea. Concentrations of OM and dissolved organic carbon (DOC) in soils affected the phytoavailability of Cd. One M $NH_4OAc$ extractable Cd concentration in soil increased with increasing OM concentrations. There were significantly positive relationships between 1 M $NH_4OAc$ extractable Cd concentration and OM concentration in soil and between 1 M $NH_4OAc$ extractable Cd concentration and DOC concentration. Likewise, OM and DOC concentrations significantly affected Cd concentration in medicinal plant soils. Cadmium concentration in medicinal plants increased with increasing OM concentration in soil [Cd concentration $(mg\;kg^{-1})= 0.179+1.424{\times}10^{-3}$ OM concentrations, $R^2=0.042*$] and with DOC concentration [Cd concentration $(mg\;kg^{-1})= 0.150+5.870{\times}10^{-4}$ DOC concentrations, $R^2=0.124***$]. These results might result from Cd-DOC complex which is easily absorbed Cd form by plant root. Dissolved organic carbon concentration had more positive relationship with Cd concentration in medicinal plants and 1 M $NH_4OAc$ extractable Cd concentration in soils than OM. Cadmium concentration in all 5 species of medicinal plant (Atractylodes macrocephala Koidzumi, Astragalus membranaceus, Codonopsis lanceolata, Platycodon grandiflorum, and Rehmannia glutinosa) significantly increased with increasing DOC concentration in soil. From the above results, formation of Cd-DOC complex caused by OM application might be mainly attributed to increase in Cd concentration in medicinal plants.

A Study on the Flow Uniformity and Characteristics of Exhaust gas in Diesel Particulate Filter/Diesel Oxidation Catalyst of Ship Diesel Reduction System by Computational Fluid Dynamics (CFD에 의한 선박용 DPF/DOC내 배기가스의 유동 균일도 및 특성 연구)

  • Kim, YunJi;Han, Danbee;Baek, Youngsoon
    • Clean Technology
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    • 제25권2호
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    • pp.153-160
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    • 2019
  • As air pollution becomes more serious due to the increased number of diesel vessel operations, ship regulations on harmful emissions strengthen. Therefore, the development of a diesel exhaust after-treatment system for ships is required, and the higher the flow uniformity of the exhaust treatment system, the higher the treatment efficiency. With the computer software ANSYS Fluent, pressure drop and flow uniformity were used in this study to simulate flow rate with and without a baffle in both a Diesel Oxidation Catalyst (DOC) and Diesel Particulate Filter (DPF) system. The system pressure drop was found to be 38 to 40 mbar in the existing system condition, and the flow uniformity was approximately 84 to 92% at the inlet and outlet of the DOC. When the baffle was installed inside the system, the pressure increased and the flow uniformity was lowered due to an increase in flow rate. When the exhaust gas flow was reduced by 50% from $7,548kg\;h^{-1}$ to $3,772kg\;h^{-1}$, the flow uniformity at the inlet and outlet of the DOC increased by approximately 1 to 3% due to the low flow rate. In the case of DPF, the flow uniformity of exhaust gas was 98 to 99% because the uneven flow proceeded after uniformly flowing from the DOC.

Characteristics of Chlorination Byproducts Formation of Amino Acid Compounds (아미노산 성분에서의 염소 소독부산물 생성 특성)

  • Son, Hee-Jong;Choi, Young-Ik;Bae, Sang-Dae;Jung, Chul-Woo
    • Journal of Korean Society of Environmental Engineers
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    • 제31권5호
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    • pp.332-340
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    • 2009
  • This study was conducted to analyze and determine formation potentials for chlorination disinfection by-products (DBPs) from twenty amino acid compounds with or without $Br^-$. Two of twenty amino acid compound were tryptophan and tyrosine that were relatively shown high for formation of trihalomethanes (THMs)/dissolved organic carbon (DOC) whether or not $Br^-$ presented. Other 18 compounds were shown low for formation of THMs/DOC whether or not $Br^-$ presented. Five amino acid compounds that were tryptophan, tyrosine, asparagine, aspartic acid and histidine were shown high for formation of haloacetic acids (HAAs)/DOC whether or not $Br^-$ presented. Although formation of dichloroacetic acid (DCAA) was dominated in asparagine, aspartic acid and histidine, trichloroacetic acid (TCAA) was dominated in tryptophan and tryptophan. The formation of haloacetnitriles (HANs)/DOC whether or not $Br^-$ presented was high in Aspartic acid, histidine, asparagine, tyrosine and tryptophan. Specially, aspartic acid was detected 660.2 ${\mu}$g/mg (HAN/DOC). Although the formation of chloralhydrate (CH)/DOC was shown high in asparagine, aspartic acid, histidine, methionine, tryptophan and tyrosine, the formation of Chloropicrin (CP)/DOC was low (1 ${\mu}$g/mg) in twenty amino acid compounds. The formations of THM, HAA and HAN were also investigated in functional groups of amino acids. The highest formation of THM was shown in amino acids compounds (tryptophan and tyrosine) with an aromatic functional group. Highest, second-highest, third-highest and fourth-highest functional groups for formation of HAA were aromatic, neutral, acidic and basic respectively. In order of increasing functional groups for formation of HAN were acidic, basic, neutral and aromatic.

Quartz Dissolution by Irradiated Bacillus Subtilis (방사선을 조사(照射)한 Bacillus Subtilis에 의한 석영 용해)

  • Lee, Jong-Un
    • Economic and Environmental Geology
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    • 제42권4호
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    • pp.335-342
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    • 2009
  • The effects of bacterial lysis on the rate of quartz dissolution were investigated under pH 7 condition using Bacillus subtilis cells which were either irradiated or non-irradiated with gamma ray. The amount of dissolved organic carbon (DOC) which resulted from bacterial lysis increased in slurries of quartz and bacteria mixture over experimental period. Lysis of non-irradiated bacteria led to the elevated concentration of dissolved silicon when compared with abiotic control. Concomitant increase in the amounts of DOC and dissolved silicon over time indicated that lixiviation of silicon from quartz was due to bacterial lysis. Higher amounts of DOC and dissolved silicon were present in the irradiated bacterial slurries than those of non-irradiated bacteria. The enhancement of quartz dissolution in the irradiated bacterial slurries was likely attributed to disruption of organic molecules in the bacterial cells by gamma ray and formation of effective ligands for quartz dissolution. The results suggest that the effects of bacterial lysis on mineral weathering rate should be considered for prediction of time for released radionuclides to migrate to surface biosphere in high level radioactive waste disposal site.

Operation of Advanced Water Treatment Processes for Downstream River Source Water (상수원수의 고도정수처리 공정 파일롯 운전 연구)

  • Wang, Chang-Keun;Oh, Sang-Eun
    • Journal of Korean Society of Environmental Engineers
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    • 제34권1호
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    • pp.1-6
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    • 2012
  • Down Stream K River has high COD (4-10 mg/L) and high $NH_3$-N concentration (3.5 mg/L during winter period). Although $NH_3$-N itself is not reported harmful at this level, it must be removed to meet drinking water standard (0.5 mg/L). We constructed a pilot plant modifying the processes of conventional drinking water facilities. Prechlorination and powdered activated carbon (PAC) dechlorination was adopted prior to a flocculation tank to remove ammonia and prevent disinfection byproducts (DBPs) formation. Also, GAC processes was included after sand filter to remove residual DOC. This pilot having a capacity of 36 ton/day was operated for one year. The GAC processes were successful to remove ammonia and many organic pollutants (DOC, MBAS, UV-254 nm absorbance, etc). Influent DOC concentrations were very high as 3~6 mg/L throughout the plant operation. It was impossible to achieve 1.0 mg/L effluent DOC, indicating that bed depth (2 m) should be increased to achieve more strict DOC quality standards. When $Cl_2$ dose was well controlled ($Cl_2/NH_3$-N ratio 10~11 on a weight basis), $NH_3$-N removal was 98% and THMs was very low possibly due to low free residual chlorine and PAC dechlorination.

A study on comparison and decomposition of organic matter in Nakdong river basin (낙동강 수계 유기물 비교 및 분해에 관한 연구)

  • Han, Gyuseong;Lee, Jaesoon;Kwon, Bomin;Choi, Kwangsoon
    • Proceedings of the Korea Water Resources Association Conference
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    • 한국수자원학회 2018년도 학술발표회
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    • pp.487-487
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    • 2018
  • 본 연구에서는 2017년 5월부터 12월까지 주단위로 낙동강 수계 5개 보 구간(칠곡보~창녕함안보)에서 본류와 유입지천의 유기물(BOD, $COD_{Mn}$, TOC) 분석 및 상관관계 조사하였으며, 강정고령보~창녕함안보의 대표지점에 대해서는 용존유기물(DOC)의 분해특성을 조사하였다. 본류의 유기물 농도는 BOD $2.7mgO_2/L$($2.3{\sim}3.1mgO_2/L$), $COD_{Mn}$ $5.6mgO_2/L$($5.0{\sim}6.2mgO_2/L$), TOC 4.7 mgC/L($4.2{\sim}5.2mgO_2/L$), 유입지천은 BOD $3.4mgO_2/L$($1.1{\sim}5.6mgO_2/L$), $COD_{Mn}$ $7.1mgO_2/L$($2.5{\sim}10.9mgO_2/L$), TOC $5.7mgO_2/L$(2.3~8.7 mgC/L)로 각각 나타났다. 유기물간 상관성 분석결과 본류의 BOD와 COD, TOC 상관계수(r)은 각각 0.97, 0.98, COD와 TOC는 0.91, 유입지천의 BOD와 COD, TOC는 각각 0.81, 076, COD와 TOC는 0.99로 나타났다. 본류 구간에서 탄소로 환산된 BOD-C/TOC 산화율은 21.5%(20.4~22.5%), COD-C/TOC 45.7%(44.3~48.0%), 유입지천의 BOD-C/TOC 산화율은 23.6%(13.1~31.0%), COD-C/TOC 48.0%(41.3~53.3%)로 각각 나타났다. 강정고령보~창녕함안보 대표지점의 DOC 분해특성은 DOC 중 R-DOC가 86.9%(74.5~94.3%), L-DOC 13.0%(5.7~25.5%)로 나타났다. L-DOC의 분해속도(k)는 0.21 /day(0.11~0.38 /day)로 계산되었으며, 보별 평균 분해속도는 합천창녕보(0.25 /day) > 강정고령보(0.22 /day) > 창녕함안보(0.21 /day) > 달성보(0.18 /day)순으로 나타났다. 유기물 농도는 본류에서는 하류로 갈수록 증가하는 경향을 보였으며, 유입지천은 지점별로 다양하게 나타났다. 유기물간 상관성은 유입지천보다 본류구간이 상관계수가 높게 나타났다. TOC에 대한 BOD와 $COD_{Mn}$산화율은 본류구간 보다 유입지천에서 큰 변동을 보였으며, 실제 유기물 총량 대비 BOD와 $COD_{Mn}$은 각각 77.0%, 52.7% 낮게 나타났다. DOC 중 난분해성 유기물이 대부분을 차지하였으며, 타 보 대비 달성보 내에 난분해성 유기물이 높은 것으로 나타났다.

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Rheological Properties of Cement Paste Mixed with Aqueously Dispersed Single-Walled Carbon Nanotubes (Single-Walled 탄소나노튜브 수용액 혼입 시멘트 페이스트의 유변학적 특성)

  • Kim, Ji-Hyun;Chung, Chul-Woo
    • Journal of the Korea Institute of Building Construction
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    • 제19권2호
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    • pp.113-121
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    • 2019
  • Single walled carbon nanotube (SWCNT) has been used as a material for reinforcing various advanced materials because it has superior mechanical properties. However, pure SWCNT that does not have any functional group has a hydrophobic character, and exists as bundles due to the strong Van der Waals attraction between each SWCNT. Due to these reasons, it is very difficult to disperse SWCNTs in the water. In this work, in order to use SWCNT for production of cementitious composites, SWCNT was first dispersed in water to make an aqueous solution. Sodium deoxycholate (DOC) and Sodium dodecyl sulfate (SDS) were chosen as surfactants, and the dosage of DOC and SDS were 2wt% and 1wt%, respectively. Sonication and ultracentrifugation were applied to separate each SWCNT and impurities. Using such processed SWCNT solutions, cement paste was prepared and its shear stress vs. strain rate relationship was studied. The yield stress and plastic viscosity of cement paste were obtained using Bingham model. According to the results in this work, cement pastes made with DOC and SDS showed similar rheological behavior to that of air entrained cement paste. While cement paste made with DOC 2 wt.% SWCNT solution showed similar rheological behavior to that of plain cement paste, cement paste made with SDS 1 wt.% SWCNT solution showed different rheological behavior showing much less yield stress than plain cement paste.

Method of Related Document Recommendation with Similarity and Weight of Keyword (키워드의 유사도와 가중치를 적용한 연관 문서 추천 방법)

  • Lim, Myung Jin;Kim, Jae Hyun;Shin, Ju Hyun
    • Journal of Korea Multimedia Society
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    • 제22권11호
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    • pp.1313-1323
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    • 2019
  • With the development of the Internet and the increase of smart phones, various services considering user convenience are increasing, so that users can check news in real time anytime and anywhere. However, online news is categorized by media and category, and it provides only a few related search terms, making it difficult to find related news related to keywords. In order to solve this problem, we propose a method to recommend related documents more accurately by applying Doc2Vec similarity to the specific keywords of news articles and weighting the title and contents of news articles. We collect news articles from Naver politics category by web crawling in Java environment, preprocess them, extract topics using LDA modeling, and find similarities using Doc2Vec. To supplement Doc2Vec, we apply TF-IDF to obtain TC(Title Contents) weights for the title and contents of news articles. Then we combine Doc2Vec similarity and TC weight to generate TC weight-similarity and evaluate the similarity between words using PMI technique to confirm the keyword association.