• Title/Summary/Keyword: DMP

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Crystal Structure and Molecular Stereochemistry of Novel Polymeric Cu2(DMP)44(DMSO) as a Platform for Phosphate Diester Binding

  • Rafizadeh, Massoud;Tayebee, Reza;Amani, Vahid;Nasseh, Mohammad
    • Bulletin of the Korean Chemical Society
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    • v.26 no.4
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    • pp.594-598
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    • 2005
  • Treatment of a solution of $CuCl_2$ in dimethyl phosphate (DMP) with DMSO under nitrogen atmosphere afforded to a light blue fluorescence powder. Slow evaporation of $H_2O$-DMSO solution of this powder resulted in blue-sky crystals of a new polymeric Cu(II) complex, with a unit cell composed of $Cu_2(DMP)_4$(DMSO), (1). The crystal and molecular structure of the complex acquired crystallographically. Compound (1) crystallizes in the monoclinic space group $P2_1$/n with a = 12.8920(11) $\AA$, b = 13.1966(11) $\AA$, c = 14.7926(13) $\AA$, $\alpha$ = 90$^{\circ}$, $\beta$ = 98.943(2)$^{\circ}$, $\gamma$ = 90$^{\circ}$, V= 2486.1(4) ${\AA}^3$, and Z = 4. A square pyramidal environment for the metal center was established by coordination of oxygen atoms of four bridging DMP ligands in the basal positions and binding a tri-centered oxygen atom of DMSO in the apical disposition of Cu(II). The sixth position was also affected by a weak interaction with the sulfur atom of another DMSO. The phosphorous atom in the bridging DMP was arranged in a deformed tetrahedron with (gg) conformation for methyl esters with $C_{2v}$ symmetry.

Complete Genome Sequence of Priestia flexa DMP08 Isolated from Kimchi, Traditional Korean Fermented Vegetables

  • Junghyun Park;Jong Hun Kim;Do-Won Jeong
    • Microbiology and Biotechnology Letters
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    • v.51 no.2
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    • pp.208-211
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    • 2023
  • Strain Priestia flexa DMP08, isolated from traditional Korean fermented vegetables kimchi, exhibits protease activity and lipase activity. The complete genome of strain DMP08 includes a single circular 3,999,911-bp chromosome without plasmids. The G+C content of the genome is 38.1 mol%. The genome includes 38 protease-and 3 lipase-encoding genes.

A new Dynamic Multilayer Perceptron Structure (새로운 동적 멀티레이어 퍼셉트론 구조)

  • Kim, Dong-Won;Oh, Sung-Kwun
    • Proceedings of the KIEE Conference
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    • 2000.11d
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    • pp.806-808
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    • 2000
  • We propose a new Dynamic Multilayer Perceptorn(DMP) architecture for optimal model identification of complex and nonlinear system in this paper. The proposed DMP scheme is presented as the generic and advanced type based on the GMDH(Group Method of Data Handling) method for the limitation of GMDH under only two system input variables. It is worth stressing that the number of the layers and the nodes in each layer of the DMP are not predetermined, unlike in the case of the popular multilayer perceptron structure, but these are generated in a dynamic manner. The experimental part of the study comes with representative nonlinear static system. Comparative analysis is included and shows that a new DMP can produce the model with higher accuracy than previous other works.

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Comparison of Gene Expression from Supernumerary Dental Pulp and Periodontal Ligament Stem Cells (과잉치 치수 세포와 치주인대 세포의 유전자 발현 비교)

  • Lee, Sangeun;Kim, Jongbin;Kim, Jongsoo
    • Journal of the korean academy of Pediatric Dentistry
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    • v.45 no.2
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    • pp.242-249
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    • 2018
  • The purpose of this study is to compare the properties of dental pulp and periodontal ligament stem cells from extracted supernumerary teeth by quantitative real-time PCR. Impacted supernumerary teeth in the maxillary anterior region were extracted. Dental pulp and periodontal ligament cells were collected from extracted supernumerary teeth on the same day. After isolation and culture of cells, compare characterization of them by using qRT-PCR. Primer sequences for odontoblasts are ONT, ALP, OCN, DMP-1 and DSPP. On dental pulp group, ONT has the largest quantity of gene expression, followed by OCN, ALP, DMP-1 and DSPP. On periodontal ligament group, ONT has the largest quantity of gene expression, followed by OCN, ALP, DSPP and DMP-1. Analysis of quantitative gene expression data using relative quantification showed that the expression of all genes decreased in periodontal ligament cells. Dental pulp and periodontal ligament stem cells from supernumerary teeth have the properties of odontoblasts. Considering that properties, supernumerary teeth were considered a useful donor site of dental pulp and periodontal ligament stem cells.

DRM System using Gstreamer based on DMP (DMP 기반의 Gstreamer를 이용한 DRM시스템)

  • Park, Ki-Chul;Lee, Joo-Young;Ahn, Sang-Woo;Nam, Je-Ho;Jung, Hoe-Kyung
    • Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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    • 2007.10a
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    • pp.611-614
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    • 2007
  • Due to illegal copying and distribution via the internet, the digital media that have been introduced create certain intellectual property issues. Because of this, several intellectual property groups have been created to create and maintain Digital Rights Management systems (DRM), in order to crack down on illegal and unauthorized copying. However, these systems are often created by many different companies, which leads to problems of interoperability. Despite attempts to regulate DRM systems, including the MPEG group's Intellectual Property Management and Protection" system, the system is still struggling to maintain some sort of interoperability between differing protocols. In this paper, we designed and implemented a DRM system with Gstreamer, following the DMP.

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Determination of Urinary Metabolites of Methidathion after Oral Administration and Dermal Application to Rats (흰쥐를 이용한 Methidathion의 경구투여 및 피부도포 후 뇨 중 대사물질 측정)

  • Min, Kyung-Jin;Kim, Hwa-Sun;Cha, Chun-Geun
    • Journal of Food Hygiene and Safety
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    • v.18 no.3
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    • pp.153-160
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    • 2003
  • This study was performed to determine the urinary metabolites of methidathion in rats. Urine samples were collected for 24 hours in metabolic cages following after oral administration and dermal application of methidation to rats. The urinary metabolites were identified by GC/MS and the excretion time courses of urinary dialkyl phosphate metabolites were analyzed by CG/FPD. The results obtained are summarized as follows: Three dialkyl phosphate metabolites, DMP, DMTP. and DMDTP, were detected in the rat urine. Urinary dialkyl phosphate metabolites were identified on the basis of their mass spectra by GC/MS. The molecular ions of DMP, DMTP,and DMDTP, were identified at m/z 198, and m/z 158, respectively. A comparison of excretion time courses of urinary dialkyl phosphate metabolites between the orally administrated and dermally applicated rats were also established, After oral administration, 79.2% of DMP, 93.9% of DMTP, and 83.0% of DMDTP were excreted into the urine by 12, 24, and 12 hours, respectively. After dermal application, 71.1% of DMP, 82.8% of DMTP 87.7% of DMDTP were excreted into the urine by 24, 48, 48 hours, respectively. Consequently, almost all of the dialkyl phosphates in oral administration were excreted within 48 hours. However, the metabolites in dermal application were excreted up to 168 hours. In the study, three urinary metabolites of methidation, DMP, DMTP and DMDTP, were detected in the rat both after oral administraion and dermal application with methidathion. And the urinary excretion in dermal application was more delayed than that in oral administration. Based on the results, it tis suggested that three urinary dealkyl phosphates, DMP, DMTP, and DMDTP, could be used as the biomarkers of exposure for methidathion.

Effect of Several Solvents on Low Temperature Wool Dyeing (몇 가지 용매가 양모의 저온염색에 미치는 영향)

  • Dho, Seong-Kook
    • Fashion & Textile Research Journal
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    • v.11 no.4
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    • pp.672-677
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    • 2009
  • To reduce the dependence of wool dyeing on the temperature several solvents with different properties and structures were added to the dye bath of C. I. Acid Yellow 42. Nearly the same total solubility parameters(${\delta}_t$) of solvents as those of wool fiber and hydrophobic part of the dyestuff were needed to increase disaggregation of dye molecules, loosening the wool fiber and wickabilty of dyeing solution; besides, the large surface tension(${\gamma}$) value of the solvents and the well balanced values of the three-component Hansen solubility parameters such as dispersion(${\delta}_d$), polar(${\delta}_p$), and hydrogen(${\delta}_h$) bonding parameters were required. Among the added solvents dimethyl phthalate(DMP) and acetophenone(AP) were satisfied with these conditions and worked the most successfully in the low temperature wool dyeing. Their effectiveness proven by the dyeing rate and the activation energy ($E_a$) of the dyeing was in the order of DMP > AP > DBE > CH > M >NONE. In conclusion the total solubility parameters(${\delta}_t$), the three-component Hansen parameters and the surface tension(${\gamma}$) of DMP and AP could be the guidelines to select suitable solvents for low temperature wool dyeing.

Implementation of protocols for a wireless communication network with a client/server architecture (클라이언트/서버 구종의 무선 통신망을 위한 프로토콜의 구현)

  • 조원홍;전중남;김석일
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.22 no.10
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    • pp.2205-2218
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    • 1997
  • We implement the CARMA-M (Collision Avoidance Radio Multiple Access-Mobile) protocol and DMP (Data-radio Multiplex Protocol) with a client/server architecture for a wireless communication netowrk. These protocols support a data transfer function between a remote computer and a mobile portable computer with a wireless modem which are proposed by dataradio in U.S.A. With the review and analysis of the proposed protocol, the impelementation methods of DMP, CARMA-M and LLC to interface the protocols are presented. Moreover the FEC technique is added to find and correct the errors generated in communication. The simulation method of a wireless network using wires is also shown to verify the implemented protocols.

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Effect of Some Amides on the Hindered Rotation of N-C(S) Bond of Thioacetamide in $CCl_4$ ($CCl_4$속에서 Thioacetamide의 N-C(S) 부자유회전에 미치는 몇가지 Amide의 영향)

  • Seong-Gu Ro;Young-Sang Choi;Chang-Ju Yoon
    • Journal of the Korean Chemical Society
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    • v.31 no.6
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    • pp.486-490
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    • 1987
  • The effect of the hydrogen-bonding between thioacetamide (TA) and amides (N,N-dimethylformamide (DMF), N,N-dimethylacetamide (DMA) and N,N-dimethylpropionamide (DMP)) on the hindered rotation of N-C(S) bond of TA was investigated by the nmr spectroscopy. The $^1H$-nmr spectrum of $NH_2$ group in TA was distinctly separated into two peaks with increasing the amount of $CCl_4$ and the effect of amides on the peak separation was in the order of DMF < DMA < DMP. Those phenomena were interpreted in terms of hydrogen-bonding between TA and amide.

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An Exploratory Case Study on the Localization Activities of Automotive Components SMEs: Transplants of Hyundai/Kia suppliers in the US (자동차 부품 중소기업의 해외 현지화 활동에 대한 탐색적 사례연구: - 미국진출 현대차/기아차 협력업체를 중심으로 -)

  • Ha, Seongwook;Lee, Sang Kon
    • Knowledge Management Research
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    • v.13 no.2
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    • pp.19-35
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    • 2012
  • This study empirically investigates the differences of dominant management problems (hereafter, DMPs) among transplants in different degree of localization, based on the exploratory case study on the nine transplants of Hyundai/Kia suppliers in US using AHP(Analytic Hierarchy Process) technique. On the results of the literature review, this study divides the DMPs of transplants into three main categories such as building human infrastructure, stabilizing manufacturing processes, and building learning network. Each categories is also divided into four subcategories. The degree of localization includes two variables such as the localization stage and the employee size of transplant. Main findings are as follows. First, 'Communication among Korean and local employees' is important DMP in all transplants examined. Second, 'Local adaptation of Korean manufacturing technology' and 'Education on the Korean culture and management practices' are more important DMPs for less-localized transplants than more-localized ones. On the contrary, 'Motivating local employees' is more important DMP for more-localized transplants than less-localized ones. Third, 'Education on the technology and quality' is more important DMP for transplants in post-production stage than in stabilization stage. On the contrary, 'Staffing local employees' is more important DMP for transplants in stabilization stage than in post-production stage. Fourth, 'Acquiring test and measurement equipments' is more important DMP for small-sized transplants than large-sized ones. On the contrary, 'adopting new technology' and 'Building local suppliers network' are more important DMPs for large-sized transplants than small-sized ones.

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