• Title/Summary/Keyword: DISPERSE

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The Dyeing Properties of Poly(trimethylene terephthalate) by Disperse Dyes with Different Energy Level (Energy Level이 다른 분산염료를 이용한 Poly(trimethylene terephthalate)섬유의 염색성)

  • 백지연;김정렬;이난형;윤태희;김삼수
    • Textile Coloration and Finishing
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    • v.15 no.5
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    • pp.316-320
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    • 2003
  • In order to investigate the dyeing property of poly trimethylene terephthalate(PTT) fabric, the dyeing of PTT fabric was carried at under condition of different dyeing temperature by using several disperse dyes with different energy level. Particularly, this study discussed the PTT dyeing thermodynamically. Used disperse dyes were selected based on the their chemical structure and energy level. The obtained results were as followings; The dye adsorption of S type disperse dye such as C. I. Disperse Blue 79 increased with increasing dyeing temperature. In a exhaustion rate of PTT fabric with disperse dyes, C. I. Disperse Blue 56 showed higher values than that of C. I. Disperse Orange 29 and Blue 79. For the interpretation of thermodynamic dyeing behavior, the partition coefficient ( K ) and some several thermodynamic parameters such as standard affinity$(-\mu^\circ)$ and heat of dyeing$(\Delta{H}^\circ)$ calculated from the adsorption isotherm. From above results, as the energy level of disperse dye is small, the partition coefficient and standard affinity increased. But the heat of dyeing of PTT fabric with disperse dye showed high negative value in order of E type(C. I. Disperse Blue 56), SE type(C. I. Disperse Orange 29) and S type(C. I. Disperse 79).

Compatibility Analysis of Disperse Dyes in Dyeing of PET/Spandex Blends (폴리에스테르/스판덱스 혼방직물 염색에서 분산염료의 상용성 및 특성분석)

  • 정용식;이근완;박병기
    • Textile Coloration and Finishing
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    • v.14 no.4
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    • pp.208-213
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    • 2002
  • In dyeing PET/Spandex blends with disperse dyes, many disperse dyes are absorbed more readily into Spandex than PET. Inorganic/organic(I/O) values can characterize the affinity of disperse dyes for Spandex and PET fibers. As I/O values of disperse dyes approach that of Spandex, the dye uptake in Spandex increases. On the contrary, the disperse dyes of higher I/O values are absorbed more into PET than Spandex. The dye uptake in PET increases with increasing I/O values of disperse dyes. As I/O values of disperse dyes increase, the rate of dyeing become slower in the dyeing of PET/Spandex blends. Hence, the affinity and the compatibility of disperse dyes in PET/Spandex blends dyeing can be evaluated with I/O value.

Dyeing of N/P Union Fabric with Reactive Disperse Dyes (반응성 분산염료를 이용한 N/P 교직물의 염색)

  • 김성동;이종렬;안창희;김규식;이권선
    • Textile Coloration and Finishing
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    • v.16 no.1
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    • pp.26-33
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    • 2004
  • Two reactive disperse dyes having $\alpha$-bromoacrylamide or acrylamide group were synthesized and their dyeing properties were compared with a disperse dye. Dyeing properties of reactive disperse dyes were strongly influenced by the chemical structure of reactive group. The amount of absorbed reactive disperse dye containing $\alpha$-bromoacrylamide group on polyester fiber was less than the disperse dye, and that on nylon fiber was much higher. When polyester and nylon fiber were simultaneously dyed in a dye pot, nylon fiber absorbed the reactive disperse dye more than polyester fiber. The reactive disperse dye having acrylamide group could reduces difference in color depth to a large extent, but the application of carrier or variation of dyebath pH were not sufficient for giving the same color depth to both fibers. The N/P union fabric could be dyed with the reactive disperse dye and its wash fastness were good to excellent.

Dyeing of meta-Aramid Fabric with Temporarily Solubilized Reactive Disperse Dyes (일시적 수용성 반응성 분산염료를 이용한 메타 아라미드 섬유의 염색성 연구)

  • Lee, Yeon Ju;Lee, Jung Jin
    • Textile Coloration and Finishing
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    • v.25 no.4
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    • pp.262-270
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    • 2013
  • Temporarily solubilized reactive disperse dyes containing ${\beta}$-sulfatoethylsulfonyl group were applied to 100% meta-aramid knitted fabric and their dyeing properties were investigated. Reactive disperse dyes showed relatively high K/S values on meta-aramid fabric when compared with conventional disperse dye or reactive dye, which showed very low K/S values. Color yields of reactive disperse dyes were highly dependent on dyeing pH and optimum results were obtained at pH 6. Percent exhaustion of reactive disperse dye on meta-aramid fabric was over 80% at 2% o.w.f of dye concentration. Wash fastness of pyridone-based reactive disperse dyes was very good to excellent while that of aminoazobenzene reactive disperse dyes was medium to good. Light fastness of all the reactive disperse dyes was very poor which seems to be due to the low photostability of meta-aramid fiber itself.

High Fastness Dyeing Technology of Polyester Microfiber with Several Disperse Dyes and Vat dye (수종의 분산 염료 및 환원염료에 의한 Polyester microfiber의 고견뢰 염색기술)

  • 백진주;권오대;손아름;이난형;김삼수
    • Textile Coloration and Finishing
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    • v.15 no.6
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    • pp.1-7
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    • 2003
  • Polyester microfiber has usually greater dye uptake than normal denier polyester fiber in same dyeing condition. In spite of this high dye uptake dyed microfiber fabric has not only low visual colour depth but also poor washing fastness property. In order to study high colouring dyeing technology and high washing fastness of polyester microfiber, dyeing property of polyester microfiber was investigated according to the dye solubility and particle size of used disperse dyes in aqueous dye solution. After disperse dyeing, dyed fabric with disperse dye was redyed with a vat dye without reduction clearing in order to obtain a high washing fastness property. The result were as followings ; A small particle sized disperse dyes such as C. I. Disperse Blue 56 and Red 60 showed high rate of initial exhaution compared with a large particle sized disperse dyes like C. I. Disperse Blue 165 and Red 343. In study of dyeing property of polyester microfiber with C. I. Vat Blue 1, polyester microfiber could achieve high dye uptake at a given optimum vatting process conditions. On the other hand, in consecutive dyeing with disperse and vat dye, K/S value of polyester microfiber with a small particle sized disperse dye increased without reduction clearings, but K/S value of polyester microfiber with a large particle sized disperse dye decreased with reduction clearings.

Dyeing of Cotton and Polyester/Cotton Blend with Disperse Dyes Using Sodium 2-(2,3-dibromopropionylamino)-5-(4,6-dichloro-1,3,5-triazinylamino)-benzenesulfonate

  • Kim, Mi-Kyung;Yoon, Seok-Han;Kim, Tae-Kyeong;Bae, Jin-Seok;Yoon, Nam-Sik
    • Fibers and Polymers
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    • v.7 no.4
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    • pp.352-357
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    • 2006
  • The cotton fabrics were pretreated by sodium 2-(2,3-dibromopropionylamino)-5-(4,6-dichloro-1,3,5-triazinylamino) benzenesulfonate (DBDCBS) at alkaline condition ofroom temperature and then dyed with four disperse dyes having amino groups (C.I. Disperse Yellow 9, C.I. Disperse Red 11, C.I. Disperse Blue 56 and C.I. Disperse Violet 1) at acidic condition of high temperature. A novel hetero-bifunctional bridge compound, DBDCBS, has two reactive groups such as dichloro-striazinyl group and ${\alpha},\;{\beta}$-dibromopropionylamido group. The first has reactivity towards hydroxy group of cellulosic fiber and the second shows reactivity towards amino groups of disperse dye containing amino groups. The results indicate that it is possible to dye polyester/cotton blend at one-bath dyeing using one kind of disperse dye containing amino groups. Therefore, two kinds of dyeing methods such as two-bath process one-bath dyeing and one-bath process one-bath dyeing were investigated and their dyeabilities were compared. The differences between these two methods were negligibly small so that perfect one-bath one-step dyeing of polyester/cotton blend by one kind of disperse dye was achieved.

Dyeing Properties and Improvement of Washfastness of Ultrafine Polyester (해도형 극세사 폴리에스테르의 염색성 및 세탁견뢰도 향상에 관한 연구)

  • 김성동;이권선;이병선;안창희;김규식
    • Textile Coloration and Finishing
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    • v.15 no.1
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    • pp.48-55
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    • 2003
  • As the polyester fiber becomes thinner, thermomigration that is the most important factor deteriorating the washfastness, is more dominant. For improving the washfastness of ultrafine polyester dyed with disperse dye, it is necessary either to decrease the amount of thermomigrated dyes on the fiber surface, or to use a disperse dye containing diester group in the coupling component. This paper is concerned to investigate the relation between the chemical structure of three disperse dyes and their dyeing properties and washfastness. The disperse dye whose molecular size is big, can dye ultrafine polyester with good build-up, and its washfastness is reasonably good. Other disperse dye which has diester group, shows the same dyeing properties as the standard disperse dye, and its washfastness is better than that of the standard disperse dye.

Effects of Thermomigration on the Washfastness of Disperse Dyes Having Different Molecular Size

  • Kim, Sung-Dong;Kim, Min-Jung;Lee, Byung-Sun;Lee, Kwon-Sun
    • Fibers and Polymers
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    • v.5 no.1
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    • pp.39-43
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    • 2004
  • Effects of chemical structure of disperse dyes applied to conventional and microdenier polyesters on the dyeing property and washfastness were studied. It was found that washfastness of dyed polyester fabric is closely related to the degree of thermomigration of disperse dye during heatsetting. The bulky disperse dye, which was synthesized by substituting two acetoxy groups of C.I. Disperse Red 82 with two benzoxy groups, showed almost the same amount of absorbed dye by the microdenier polyester as C.I. Disperse Red 82, but the degree of thermomigration was low and subsequent washfastness was excellent. The high grade of washfastness of the bulky disperse dye might be caused by the increased dye-fiber interaction and the reduced mobility.

PET Dyeing in Black Shade with Disperse Dyes of Three Primary Color

  • Kim, Hae-Rim;Lee, Jung-Jin
    • Textile Coloration and Finishing
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    • v.21 no.5
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    • pp.27-34
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    • 2009
  • PET fabric was dyed in black shade with disperse dyes of three primary color. The effect of combination ratio of dye concentration and energy type of disperse dye on dyeing and color property of black dyed PET fabric was investigated. Dyeing compatibility of disperse dyes of three primary color on PET was evaluated by comparison of dyeing rates of them. From the results, color property was dependent upon the combination ratio of dye concentration. In order to obtain low lightness ($L^*$) and black color, blue dye should be added enough. S-type disperse dye and $130^{\circ}C$ dyeing was suitable rather than SE-type dyes or $120^{\circ}C$ dyeing. Disperse dyes of three primary color used showed good dyeing compatibility at high dye concentration. Washfastness was fair to moderate and lightfastness was moderate.

Dyeing Properties on Polylactic Acid (PLA) Fabrics by Disperse Dyes (분산염료에 의한 PLA 직물의 염색성)

  • Lee, So Hee;Song, Wha Soon
    • Journal of the Korean Society of Clothing and Textiles
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    • v.37 no.7
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    • pp.952-961
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    • 2013
  • This study optimizes a suitable dyeing method for polylactic acid (PLA) fabrics using disperse dyes. For this, disperse red 60 (DR 60), disperse blue 56 (DB 56), and disperse yellow 54 (DY 54) were used and dyed on PLA fabrics dependent of dyeing temperature and time. The fastness of PLA fabrics dyed with three disperse dyes were evaluated; in addition, dye exhaustion, color strength (K/S value), and colorimetric properties of PLA fabrics were compared with PET fabrics. The experiments indicated optimum dyeability of PLA fabrics with disperse dyes. The dyeing temperature was $90^{\circ}C$ for every dye and the dyeing time were 20 min, 60 min, and 40 min for DR 60, DB 56, DY 54, respectively. PLA fabrics had good color fastness to washing, dry cleaning fastness, hot pressing fastness, rub fastness, and perspiration fastness by DR 60, DB 56, and DY 54. The dye exhaustion of PLA fabrics were lower than PET fabrics; however, K/S values were higher than PET fabrics.