• Bulletin of the Korean Chemical Society
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• 제20권12호
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• pp.1428-1432
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• 1999

[Fe$^{II}$(BLPA)DBCH]BPh₄ (1), a new functional model for the extradiol-cleaving catechol dioxygenases, has been synthesized, where BLPA is bis(6-methyl-2-pyridylmethyl)(2-pyridylmethyl)amine and DBCH is 3,5-di-tert-butylcatecholate monoanion. ¹H NMR and EPR studies confirm that 1 has a high-spin Fe(II) (S = 2) center. The electronic spectrum of 1 exhibits one absorption band at 386 nm, showing the yellow color of the typical [Fe$^{II}$(BLPA)] complex. Upon exposure to O₂, 1 is converted to an intense blue species within a minute. This blue species exhibits two intense bands at 586 and 960 nm and EPR signals at g = 5.5 and 8.0 corresponding to the high-spin Fe(III) complex (S = 5/2, E/D = 0.11). This blue complex further reacts with O₂ to be converted to (μ-oxo)Fe$^{III}_2$ complex within a few hours. Interestingly, 1 affords intradiol cleavage (65%) and extradiol cleavage (20%) products after the oxygenation. It can be suggested that 1 undergoes two different oxygenation pathways. The one takes the substrate activation mechanism proposed for the intradiol cleavage products after the oxidation of the $Fe^II\;to\;Fe^{III}$. The other involves the direct attack of O₂ to $Fe^{II}$ center, forming the $Fe^{III}$-superoxo intermediate which can give rise to the extradiol cleavage products. 1 is the first functional Fe(II) complex for extradiol-cleaving dioxygenases giving extradiol cleavage products.

• Coupled systems mechanics
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• 제8권4호
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• pp.351-375
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• 2019

The present work investigates the use of a rigid rocking block as a tool to reduce vibrations in a frame structure. The study is based on a simplified model composed by a 2-DOF linear system, meant to represent a general M-DOF frame structure, coupled with a rocking rigid block through a linear visco-elastic device, which connects only the lower part of the 2-DOF system. The possibility to restrain the block directly to the ground, by means of a second visco-elastic device, is investigated as well. The dynamic response of the model under an harmonic base excitation is then analysed in order to evaluate the effectiveness of the coupling in reducing the displacements and the drift of the 2-DOF system. The nonlinear equations of motion of the coupled assemblage 2-DOF-block are obtained by a Lagrangian approach and then numerically integrated considering some reference mechanical and geometrical quantities as variable parameters. It follows an extensive parametric analysis, whose results are summarized through behaviour maps, which portray the ratio between the maximum displacements and drifts of the system, with and without the coupling with the rigid block, for several combinations of system's parameters. When the ratio of the displacements is less than unity, the coupling is considered effective. Results show that the presence of the rocking rigid block improves the dynamics of the system in large ranges of the characterizing parameters.

• Coupled systems mechanics
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• 제9권6호
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• pp.539-562
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• 2020

In this paper the linear elastic coupling between a 2 degree of freedom shear-type frame system and a rigid block is analytically and experimentally investigated. As demonstrated by some of the authors in previous papers, it is possible to choose a coupling system able to guarantee advantages, whatever the mechanical characteristics of the frame. The main purpose of the investigation is to validate the analytical model. The nonlinear equations of motion of the coupled system are obtained by a Lagrangian approach and successively numerically integrated under harmonic and seismic excitation. The results, in terms of gain graphs, maps and spectra, represent the ratio between the maximum displacements or drifts of the coupled and uncoupled systems as a function of the system's parameters. Numerical investigations show the effectiveness of the nonlinear coupling for a large set of parameters. Thus experimental tests are carried out to verify the analytical results. An electro-dynamic long-stroke shaker sinusoidally and seismically forces a shear-type 2 d.o.f frame coupled with a rigid aluminium block. The experimental investigations confirm the effectiveness of the coupling as predicted by the analytical model.

• 한국기계가공학회지
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• 제21권7호
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• pp.64-70
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• 2022

The aim of this study is to improve the purification efficiency of odor gas by increasing the contact area between an odor gas and adsorbent. To analyze the flow in the adsorption tower, the flow characteristics in the hollow activated carbon-adsorption tower are identified by applying the loss model, which is a porous flow analysis model. The flow characteristics are investigated for pressure loss, velocity distribution, turbulent kinetic energy, and residence time distribution. The results show that the hollow adsorption tower performs better than the solid adsorption tower in terms of pressure loss and performance. The inner diameter of the hollow region inside the adsorption tower is 0.64 m (Di/Do = 0.37). Furthermore, the adsorbent performance is unaffected even when adsorbent stages are installed to replace the adsorbent.

• Geomechanics and Engineering
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• 제33권4호
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• pp.341-352
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• 2023

Long-short pile composite foundations bear both vertical and horizontal loads in many engineering applications. This study used indoor model tests to determine the horizontal bearing mechanism of a composite foundation with long and short piles under horizontal loads. A custom experimental device was developed to prevent excessive eccentricity of the vertical loading device caused by the horizontal displacement. ABAQUS software was used to analyze the influence of the load size and cushion thickness on the horizontal bearing mechanism. The results reveal that a large vertical load leads to soil densification and increases the horizontal bearing capacity of the composite foundation. The magnitude of the horizontal displacement of the pile and the horizontal load borne by the pile are related to the piles' positions. Due to different pile lengths, the long piles exhibit long pile effects and experience bending deformation, whereas the short piles rotate around a point (0.2 L from the pile bottom) as the horizontal load increases. Selecting a larger cushion thickness significantly improves the horizontal load sharing capacity of the soil and reduces the horizontal displacement of the pile top.

• 한국해양공학회지
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• 제22권5호
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• pp.75-82
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• 2008

As a basic study for establishing a countermeasure for an oxygen deficient water mass (ODW), we investigated the variation of ODW volume according to the enforced total pollution load management in Jinhae Bay. This study estimated the inflowing pollutant loads into Jinhae Bay and predicted the reduction in ODW by using a sediment-water ecological model (SWEM). The result obtained in this study are summarized as follows: 1) The daily average pollutant loads of COD, SS, TN, TP, DIN, and DIP inflowing into Jinhae bay in 2005 were estimated to be about 12,218 kg-COD/day, 91,884 kg-SS/day, 5,292 kg-TN/day, 182 kg-TP/day, 4,236 kg-DIN/day, and 130 kg-DIP/day. 2) The calculated results of the tidal current by the hydrodynamic model showed good agreement with the observed currents. Also, an ecological model well reproduced the spatial distribution of the water quality in the bay. 3) This study defined the ODWDI (ODW decreasing index) in order to estimate the ODW decreasing volume caused by a reduction in the inflowing pollutant loads. As a result, the ODWDI was predicted to be about 0.91 (COD 30% reduction), 0.87 (COD 50% reduction), 0.79 (COD 70% reduction), 0.85 (ALL 30% reduction), 0.66 (ALL 50% reduction), and 0.45 (ALL 70% reduction). The ODW volume was decreased 1.5 $\sim$ 2.6 times with a reduction in the COD, TN, and TP inflowing pollutant loads compared to a reduction in just the COD inflowing pollutant load. Therefore, it is necessary to enforce total pollution load management, not only for COD, but also fm TN and TP.

• 한국습지학회지
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• 제8권1호
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• pp.83-96
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• 2006

본 연구에서는 1차원 부정류 해석 모형인 FLDWAV 모형을 이용하여 낙동강 하류지역의 수리학적 특성을 분석하였다. 입력자료 구축을 위해서 KOWACO 홍수분석 모형을 이용한 합리적인 경계조건을 수립하였다. 과거의 홍수 사상에 대해서 적용한 결과 진동, 삼랑진 지점에서의 관측수위와 비교하여 정량적, 정성적인 면에서 일치하고 있는 것으로 나타났다. 또한 낙동강 유역의 하류경계조건으로 입력이 되는 하구둑 수위산정법을 개선하였다. 이를 위해 낙동강 하구에서 발생하는 천문조위와 과거의 하구둑 관측수위를 이용하여 합리적인 예측수위값을 산정하는 회귀방정식을 산정하였다. 본 연구에서 수행된 절차 등을 이용하면 타수계에서의 적용 및 홍수예경보 구축을 위한 지침으로 적용될 수 있을것으로 판단된다.

• Computers and Concrete
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• 제3권4호
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• pp.213-233
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• 2006

Over the past years techniques for non-linear analysis have been enhanced significantly via improved solution procedures, extended finite element techniques and increased robustness of constitutive models. Nevertheless, problems remain, especially for real world structures of softening materials like concrete. The softening gives negative stiffness and risk of bifurcations due to multiple cracks that compete to survive. Incremental-iterative techniques have difficulties in selecting and handling the local peaks and snap-backs. In this contribution, an alternative method is proposed. The softening diagram of negative slope is replaced by a saw-tooth diagram of positive slopes. The incremental-iterative Newton method is replaced by a series of linear analyses using a special scaling technique with subsequent stiffness/strength reduction per critical element. It is shown that this event-by-event strategy is robust and reliable. First, the model is shown to be objective with respect to mesh refinement. Next, the example of a large-scale dog-bone specimen in direct tension is analyzed using an isotropic version of the saw-tooth model. The model is capable of automatically providing the snap-back response. Subsequently, the saw-tooth model is extended to include anisotropy for fixed crack directions to accommodate both tensile cracking and compression strut action for reinforced concrete. Three different reinforced concrete structures are analyzed, a tension-pull specimen, a slender beam and a slab. In all cases, the model naturally provides the local peaks and snap-backs associated with the subsequent development of primary cracks starting from the rebar. The secant saw-tooth stiffness is always positive and the analysis always 'converges'. Bifurcations are prevented due to the scaling technique.

• Wind and Structures
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• 제37권6호
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• pp.399-412
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• 2023

Previous studies have shown that the integrated transfer function (ITF) is independent of turbulence characteristics and can be effectively applied to predict the buffeting response of elongated structures, assuming that the strip hypothesis is valid. However, existing research has not effectively identified the ITF through segment model vibration tests, and the influence of the 3D effect on the accuracy of the strip hypothesis and the characteristics of the ITF in wind tunnel tests has not been quantitatively studied. A segment model vibration measurement device that can change a test model's span-width ratio was designed in this study. An airfoil section and a streamlined box girder section structure were taken as the background, and their ITFs were effectively identified under different L/B (L denotes the turbulent integral scale and B denotes the structural width) and model span-width ratios. The influence laws of the 3D effect on the accuracy of the strip hypothesis and ITF identification in wind tunnel tests were systematically investigated. The results showed that L/B and the structural span-width ratio are two significant controlling factors that affect the accuracy of the strip hypothesis and ITF identification. The research provides an effective experimental method for accurately predicting the buffeting response of elongated structures based on ITFs identified through segment model vibration tests.

• 한국자동차공학회논문집
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• 제10권5호
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• pp.45-57
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• 2002

In this paper, the results gained by applying many impingement models to the cylinder and flat plate were analyzed in comparison with the experimental data to study a spray/wall interaction phenomena. To begin with, the behavior of spray injected normal to the wall was analysed using three different impingement models ; Naber and Reitz model(NR model), Watkins and Wang model(WW model) and Park and Watkins model(PW model) in the present calculation. The results obtained from these models were compared with experimental data of Katsura et. al. The results indicated that PW model was in better agreement with experimental data than the NR and WW model. Also f3r spray injected at 30DEG , the result of three models were compared with experimental data of Fujimoto et. al. The results showed that m model overpredicted the penetration in the radial direction because this model was based on the inviscid jet analogy. WW model did not predicted the radius and height of the wall spray effectively. It might be thought that this discrepancy was due to the lack of consideration of spray film velocity occurred at impingement site. The result of PW model agrees with the experimental data as time goes on. In particular, a height of the spray droplets was predicted more closely to the experimental data than the other two models. The results of PW model in which the spray droplets were distributed densely around the edge of droplet distribution shaped in a circle had an agreement with the experimental data of Fujimoto et. al. Therefore, it was concluded that PW model performed better than M and WW model for prediction of spray behavior. The numerical calculation using PW model performed to the cylinder similar to the real shape of DI engine. The results showed that vortex strength near the wall in the cylinder was stronger than that in the case of flat plate. Contrary to the flat plat, an existence of the side wall in the cylinder caused the tangential velocity component to be reduced and the normal velocity component to be increased. The flow tends to rotate to the inside of cylinder going upward to the right side wall of cylinder gradually as time passes. Also, the results showed that as the spray angle increases, the gas velocity distribution and the tumble flow seemed to be formed widely.