• 제목/요약/키워드: DER index

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Studies on The Elution Behavior of Ni(II)-${\alpha}$-isonitroso-${\beta}$-diketone Imine Chelates in Reversed-Phase Liquid Chromatography

  • Lee, Won;Kim, In-Whan;Kim, Mi-Kyoung;Kim, Yong-Jun;Jung, Hae-Rim;No, Kyoung-Tai;Kim, Su-Yeon
    • 분석과학
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    • 제8권4호
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    • pp.519-527
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    • 1995
  • The retention mechanism of Ni(II)-${\alpha}$-isonitroso-${\beta}$-diketone imine chelates in reversed-phase HPLC has been studied by examining the effect of temperature, mobile phase composition in acetonitrile-water mixture, and molecular structure on retention. The empirical retention equation was investigated to evaluate the properties of S (hydrophilic index). The value of the S index of the Ni(II) chelates decrease with the increasing column temperature and a linear relationship between S and log $k{_w}^{\prime}$ has been found. The results showed that the S index is influenced by the interaction between Ni(II) chelates and mobile phase. Molecular properties, van der Waals molar volume, polarizability and dipole moment, of the Ni(II) chelates were calculated by Cerius 2 program and the calculations were performed at Universal Force Field (UFF) model. The S value and log $k{_w}^{\prime}$ increase with decreasing the dipole moment of Ni(II) chelates.

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파고와 파형경사의 상관성을 고려한 피복석의 신뢰성 해석 및 부분안전계수 산정 (Reliability Analysis and Evaluation of Partial Safety Factors of Breakwater Armor stones Considering Correlation between Wave Height and Wave Steepness)

  • 김승우;서경덕
    • 한국해안·해양공학회논문집
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    • 제20권3호
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    • pp.300-309
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    • 2008
  • 지금까지 연구된 피복석의 부분안전계수는 각 확률변수가 독립이라고 가정하여 계산하였다. 하지만 피복석의 안정공식 중 van der Meer 공식에서 파형경사와 파고는 독립이 아니며 상관성을 가지고 있다. 본 연구에서는 이들의 상관성을 고려한 부분안전계수를 산정하였고 이를 상관성을 고려하지 않은 다른 연구자들의 결과와 비교하였다. 파고와 파형경사의 상관성은 주기의 변동성과 밀접한 관계가 있다. 주기의 변동성이 작아짐에 따라 파고와 파형경사의 상관성은 커지며, 상관성 고려 여부에 따른 계산 결과의 차이가 커진다. 따라서 주기의 변동성이 작은 지역에서는 상관성을 충분히 검토하여 부분안전계수를 산정해야 할 것이다.

기계학습과 네트워크를 이용한 수학교육 연구의 영향력 판별 프로그램 개발 (Development of an impact Identification Program in Mathematical Education Research Using Machine Learning and Network)

  • 오세준;권오남
    • 한국수학교육학회지시리즈E:수학교육논문집
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    • 제37권1호
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    • pp.21-45
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    • 2023
  • 본 연구는 수학교육에서 영향력 있는 논문을 판별하는 기계학습 프로그램 개발 연구이다. 이를 위하여 과학계량학의 관점에서 논문의 영향력을 조명하고, 수학교육 연구 네트워크를 구성하고, 네트워크 중심성 지수인 PageRank로 수학교육 연구의 영향력으로 정의하였다. 영향력 있는 수학교육 연구를 판별하기 위하여 기계학습 모델을 설계하였으며, 이를 이용하여 영향력 있는 논문이 게재된 비율이 높은 학술지를 조사한 결과 Journal for Research in Mathematics Education(25.66%), Educational Studies in Mathematics(22.12%), Zentralblatt für Didaktik der Mathematik(8.46%), Journal of Mathematics Teacher Education(5.8%), Journal of Mathematical Behavior(5.51%) 순으로 나타났다. 수학교육 전문가들이 직접 논문을 읽고 질적으로 평가한 선행연구 결과와 유사한 결과를 기계학습 프로그램으로 도출할 수 있었다. 많은 인원과 시간이 필요했던 수학교육 연구의 영향력 평가를 인공지능을 이용하여 효율적으로 실시할 수 있었다는 점에서 의의가 있다.

무역항 및 연안항 피복재의 파괴확률과 부분안전계수 해석 (Analysis of Probabilities of Failure and Partial Safety Factors of Armor Units on Tranding and Coastal Harbors)

  • 이철응;박동헌
    • 산업기술연구
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    • 제28권B호
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    • pp.157-165
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    • 2008
  • Level II AFDA and Level III MCS reliability models are applied to analyze the stability of armor units on trading and coastal harbors in Korea. Hudson's formula and Van der Meer's formula are used in this reliability analysis. Also, probability density functions of reliability index and probability of failure are derived by the additional analysis. In addition, the partial safety factors of all harbors related to armor units can be straightforwardly evaluated by the inverse-reliability method. The upper and lower limits and average level of partial safety factors can be statistically investigated with the results of all cases applied in this paper. Therefore, it may be possible to design armor units of new breakwaters including the uncertainty of random variable and target level by using the present results.

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Optimization for nonlinear systems via block pulse transformation

  • Ahn, Doo-Soo;Park, Jun-Hun;Kim, Jong-Boo;Lee, Seung;Go, Young-Ki
    • 제어로봇시스템학회:학술대회논문집
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    • 제어로봇시스템학회 1990년도 한국자동제어학술회의논문집(국제학술편); KOEX, Seoul; 26-27 Oct. 1990
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    • pp.969-973
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    • 1990
  • This paper presents a method of suboptimal control for nonlinear systems via block pulse transformation. The adaptive optimal control scheme proposed by J.P. Matuszewski is introduced to minimize the performance index. Nonlinear systems are controlled using the obtained optimal control via block pulse transformation. The proposed method is simple and computationally advantageous. Viablity of the this method is established with simulation results for the van der Pol equation for comparision with other methods.

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디젤기관의 연소실내 NO 생성농도 예측에 관한 연구 (A Study on the Calcuation of NO Formation in Cylinder for Diesel Engines)

  • 남정길
    • Journal of Advanced Marine Engineering and Technology
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    • 제23권4호
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    • pp.543-551
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    • 1999
  • Diesel engine is a major source of the air pollution. In general the concentrations of these pollu-tants in diesel engine exhaust differ from values calculated assuming chemical equibrium. Thus the detailed chemical mechanisms by which these pollutions form and the kinetic of these process-es are important in determining emission levels. In this study the computer program has been developed to calculate the required thermodynam-ic properties of combustion products(10 spacies) for both equilibrium and non-equilibrium in cylin-der for diesel engines. Nitric oxide emissions are calculated by using the extended Zeldovich Kinet-ic mechanism with a steady state assumption for the N concentration and equilibrium values used for H, O, $O_2$ and OH concentrations. By the results it is confirmed that developed simulations program with the NO prediction model is validated against residual mass fraction combustion index of Wiebe's functions pre-mixed com-bustion ration fuel injection timing.

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Structural Parameters of Galaxies in the Virgo Cluster

  • Kim, Suk;Yi, Wonhyeong;Rey, Soo-Chang;Sung, Eon-Chang;Jerjen, Helmut;Lisker, Thorsten;Lee, Youngdae;Lee, Woong;Chung, Jiwon;Pak, Mina
    • 천문학회보
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    • 제38권2호
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    • pp.47.1-47.1
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    • 2013
  • We present structural parameters of galaxies in the Extended Viro Cluster Catalog (EVCC), new catalog of galaxies in the Viro cluster using homogeneous Sloan Digital Sky Survey (SDSS) Date Release 7 (DR7) data. The EVCC covers more extended region of the Viro cluster than of the Virgo Cluster Catalog (VCC) and presents updated morphologies of galaxies using multi-band images and spectral features. We obtain the surface brightness profiles of galaxies using ellipse task in IRAF. Based on the analysis of surface brightness profile we construct a catalog of various structural parameters of galaxies, i.e. central surface brightness, effective radius, sersic index, effective surface brightness, and mean effective surface brightness. Taking advantage of these structural parameters in various parameter spaces, we refine criteria of dividing giant elliptical and dwarf elliptical galaxies. In addition, we found that bulge dominated galaxies have larger sersic index and brighter central surface brightness than disk dominated galaxies. At fixed magnitude, dwarf elliptical galaxies dwarf lenticular galaxies, and dwarf irregular low surface brightness (LSB) galaxies show larger effective radii than giant elliptical galaxies, giant lenticular galaxies, and irregular high surface brightness (HSB) galaxies, respectively. Dwarf elliptical galaxies and dwarf irregular LSB galaxies occupy the similar structural parameter spaces. We suggest that giant elliptical galaxies and dwarf elliptical galaxies may have different origin.

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High early pregnancy serum 25-hydroxy vitamin D level, within a sub-optimal range, is associated with gestational diabetes mellitus: a prospective cohort study

  • Yong, Heng Yaw;Shariff, Zalilah Mohd;Palaniveloo, Lalitha;Loh, Su Peng;Yusof, Barakatun Nisak Mohd;Rejali, Zulida;Bindels, Jacques;Tee, Yvonne Yee Siang;van der Beek, Eline M.
    • Nutrition Research and Practice
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    • 제16권1호
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    • pp.120-131
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    • 2022
  • BACKGROUND/OBJECTIVES: Low early pregnancy serum 25-hydroxy vitamin D (25[OH]D) levels can increase gestational diabetes mellitus (GDM) risk, although inconsistent findings related to that association have been reported. This study examined the association of serum vitamin D with GDM and the possible influencers on this association. SUBJECTS/METHODS: This study included 259 pregnant women within the Seremban Cohort Study (SECOST). Blood samples at < 14 weeks of gestation were drawn to determine serum 25(OH)D levels. GDM diagnosis was made at 24 to 32 weeks of gestation using a standard procedure. Association between serum vitamin D and GDM was tested using binary logistic regression. RESULTS: Nearly all women (90%) had mild (68.3%) or severe (32.2%) vitamin D deficiency (VDD). Non-GDM women with mild VDD had a significantly higher mean vitamin D intake than GDM women with mild VDD (t = 2.04, p < 0.05). Women with higher early pregnancy serum vitamin D levels had a greater risk of GDM. However, this significant association was only identified among those with a family history of type 2 diabetes mellitus (T2DM) and in women with a body mass index indicating overweight or obese status. CONCLUSIONS: The high prevalence of VDD in this sample of pregnant women underscores the need for effective preventive public health strategies. Further investigation of this unexpected association between serum vitamin D level and GDM risk in predominantly VDD pregnant women and the potential effects of adiposity and family history of T2DM on that association is warranted.

Optimal Relocating of Compensators for Real-Reactive Power Management in Distributed Systems

  • Chintam, Jagadeeswar Reddy;Geetha, V.;Mary, D.
    • Journal of Electrical Engineering and Technology
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    • 제13권6호
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    • pp.2145-2157
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    • 2018
  • Congestion Management (CM) is an attractive research area in the electrical power transmission with the power compensation abilities. Reconfiguration and the Flexible Alternating Current Transmission Systems (FACTS) devices utilization relieve the congestion in transmission lines. The lack of optimal power (real and reactive) usage with the better transfer capability and minimum cost is still challenging issue in the CM. The prediction of suitable place for the energy resources to control the power flow is the major requirement for power handling scenario. This paper proposes the novel optimization principle to select the best location for the energy resources to achieve the real-reactive power compensation. The parameters estimation and the selection of values with the best fitness through the Symmetrical Distance Travelling Optimization (SDTO) algorithm establishes the proper controlling of optimal power flow in the transmission lines. The modified fitness function formulation based on the bus parameters, index estimation correspond to the optimal reactive power usage enhances the power transfer capability with the minimum cost. The comparative analysis between the proposed method with the existing power management techniques regarding the parameters of power loss, cost value, load power and energy loss confirms the effectiveness of proposed work in the distributed renewable energy systems.

LEAD LEACHABILITY FROM QUICKLIME TREATED SOILS IN A DIFFUSION CONTROLLED ENVIRONMENT

  • Moon, Deok-Hyun
    • Environmental Engineering Research
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    • 제10권3호
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    • pp.112-121
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    • 2005
  • The effectiveness of quicklime-based stabilization/solidification (S/S) in immobilizing lead (Pb) was assessed by performing semi-dynamic leaching tests (ANS16.1). In order to simulate landfill leaching conditions, the ANS 16.1 test was modified by using 0.014 N acetic acid (pH = 3.25) instead of distilled water. Artificial soil samples as well as field soil samples contaminated with Pb were tested. The effectiveness of quicklime treatment was evaluated by determining diffusion coefficients ($D_e$) and leachability indices (LX). A model developed by de Groot and van der Sloat was used to elucidate the controlling Pb leaching mechanisms. Overall, upon quicklime treatment Pb leachability was significantly reduced in a]l of the samples tested. The mean LX values were higher than 9 for an artificial soil sample containing 30% kaolinite treated with 10% quicklime and for a field soil sample treated with 10% quicklime, which suggests that S/S treated soils can be considered acceptable for "controlled utilization". Moreover, quicklime treatment was more effective in artificially contaminated soil with high kaolinite content (30%), indicating the amount of clay plays an important role in the success of the treatment. The controlling Pb leaching mechanism was found to be diffusion, in all quicklime treated samples.