• Title/Summary/Keyword: DCM derivative

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White organic light-emitting devices with a new DCM derivative as an efficient red-emitting material

  • Lee, Mun-Jae;Lee, Nam-Heon;Song, Jun-Ho;Park, Kyung-Min;Yoo, In-Sun;Lee, Chang-Hee;Hwang, Do-Hoon
    • 한국정보디스플레이학회:학술대회논문집
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    • 2003.07a
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    • pp.940-943
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    • 2003
  • We report the fabrication and the characterization of white organic light-emitting devices consisting of a red-emitting layer of a new DCM derivative doped into 4,4'bis[N-(1-napthyl)-N-phenyl-amino]-biphenyl (${\alpha}-NPD$) and a blue-emitting layer of 1,4-bis(2,2-diphenyl vinyl)benzene (DPVBi). The device structure is ITO/PEDOT:PSS/${\alpha}-NPD$ (50 nm)/${\alpha}-NPD$:DCM (5 nm, 0.2 %)/DPVBi (x)/Alq3 (40 nm)/LiF (0.5 nm)/Al. The electroluminescence (EL) spectra consist of two broad peaks around 470 nm and 580 nm with the spectral emission depending on the thickness of DPVBi. The device with the DPVBi thickness of about 20 nm show a white light-emission with the Commission Internationale d'Eclairage(CIE) chromaticity coordinates of (0.33, 0.36). The external quantum efficiency is 2.6% and luminous efficiency is 2.0 lm/W at a luminance of 100 $cd/m^{2}$. The maximum luminance is about 30,270 $cd/m^{2}$ at 13.9 V.

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Efficient orange-red OLED using a new DCM derivative as a doping molecule

  • Hwang, Do-Hoon;Lee, Jong-Don;Lee, Moon-Jae;Lee, Chang-Hee
    • 한국정보디스플레이학회:학술대회논문집
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    • 2004.08a
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    • pp.579-581
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    • 2004
  • A new DCM derivative containing the phenoxazine moiety (DCPXZ) has been synthesized for use as a red fluorescent dye molecule in organic light-emitting diodes (OLEDs). The photoluminescence and electroluminescence properties of DCPXZ were examined. The maximum photoluminescence of DCPXZ in chloroform solution ($10^{-5}$ mol) was observed at 616 nm. EL devices were fabricated with the structure ITO/PEDOT-PSS/Cu-PC(15nm)/${\alpha}$-NPD(45nm)/$Alq_3$:DCPXZ(30nm)/$Alq_3$(30nm)/LiF(0.5nm)/Al. The maximum EL emission for the 2.0% DCPXZ-doped device was at 608 nm with CIE coordinates (0.57, 0.42). The EL device exhibited a maximum brightness of 15,000 cd/$m^2$ at 19.4 V and a power efficiency of 1.04 lm/W at a luminance of 100 cd/$m^2$.

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Surface Structure and Electrical Properties of Polyurethane LB Monolayers (폴리우레탄 LB단분자막의 표면구조 이미지와 전기적 특성)

  • 서정열;김도균;정상범;유승엽;신훈규;박재철;권영수
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.11a
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    • pp.320-323
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    • 2000
  • We attempted to fabricate polyurethane derivatives (PU-CN, PU-DCM) LB films by using LB method. Also, we investigated the monolayer behavior at the air-water interface by surface pressure-area ($\pi$-A) isotherms. And, the surface morphologies and the physicochemical properties of LB films were investigated by atomic force microscopy (AFM) and UV-vis spectroscopy, respectively. Also, the electrical properties of polyurethane derivatives LB films were investigated by using the conductivity and the dielectric constant. In the AFM images, we conclude that surface morphology of PU-DCM LB films is smooth and homogeneous and has optimal hydrophobicity and good stability, whereas PU-CN LB films give rougher surfaces with more excess material. In the I-V characteristics, the conductivity is different as to the polyurethane derivatives, it is considered that this phenomena could be described by the difference of lumophore pendant which was adhered at PU main chain.

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Fluorescent White OLEDs with a High Color-rendering Index Using a Silicon-Cored Anthracene Derivative as a Blue Host

  • Kwak, Jeong-Hun;Lyu, Yi-Yeol;Lee, Hyun-Koo;Char, Kook-Heon;Lee, Chang-Hee
    • Journal of Information Display
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    • v.11 no.3
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    • pp.123-127
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    • 2010
  • Fluorescent white organic light-emitting diodes showing high color-rendering indices (CRIs) of up to 81 was demonstrated, with a silicon-cored anthracene derivative (PATSPA) doped with DPAVBi utilized as the deep-blue host and dye materials, and the commercial dyes rubrene and DCM2 utilized as the orange- and red-light-emitting dyes. The devices, consisting of three emissive layers, showed bright-white-light emission, but the ratio of the blue peak to the orange and red peaks changed with the current density and the thickness of the blue emissive layer. A high CRI was achieved with the use of a deep-blue emitter doped in a novel host and by optimizing the blue-layer thickness. The device with a blue-layer thickness of 10 nm showed the Commission Internationale de l'Eclairage (CIE) color coordinate of (0.33, 0.35), a high CRI of 81, and a moderate external quantum efficiency of 2% at a current density of $2.5\;mA/cm^2$.

White Organic Light-Emitting Diodes Using a New DCM Derivative as an Efficient Orange-Red Doping Molecule

  • Lee, Jong-Don;Hwang, Do-Hoon;Cho, Nam-Sung;Lee, Sang-Kyu;Shim, Hong-Ku;Lee, Chang-Hee
    • 한국정보디스플레이학회:학술대회논문집
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    • 2005.07b
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    • pp.1416-1418
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    • 2005
  • A new DCM derivative containing a phenothiazine moiety, 4-(dicyanomethylene)-2-t-butyl-6-(9-ethylphenothiazine-2- enyl)-4H-pyran (DCPTZ), has been synthesized as an orange-red fluorescent dye molecule for organic lightemitting diodes (OLEDs). EL devices with the structure of $ITO/PEDOT-PSS/{\alpha}-NPD/Alq_3:DCPTZ/Alq_3/LiF/Al$ have been fabricated with changing the doping concentration of the DCPTZ. Maximum EL spectra of the devices ranged from $580{\sim}620$ nm depending on the doping concentration of the dye molecule. An EL device with 0.5 % doping concentration showed CIE coordinate (0.51, 0.47) at luminance of 100 $cd/m^2$. White light-emitting devices with the structure of $ITO/PEDOT-PSS/{\alpha}-NPD/{\alpha}-NPD:DCPTZ/DPVBi/Alq_3/$ LiF/Al have been also fabricated. The thickness of blue light-emitting 1,4-bis(2,2- diphenylvinyl)benzene (DPVBi) layer was changed to obtain a white light-emission. A white light-emission from the device was observed when the thickness of the DPVBi layer became thicker than 10 nm.

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Damping and vibration response of viscoelastic smart sandwich plate reinforced with non-uniform Graphene platelet with magnetorheological fluid core

  • Eyvazian, Arameh;Hamouda, Abdel Magid;Tarlochan, Faris;Mohsenizadeh, Saeid;Dastjerdi, Ali Ahmadi
    • Steel and Composite Structures
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    • v.33 no.6
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    • pp.891-906
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    • 2019
  • This study considers the instability behavior of sandwich plates considering magnetorheological (MR) fluid core and piezoelectric reinforced facesheets. As facesheets at the top and bottom of structure have piezoelectric properties they are subjected to 3D electric field therefore they can be used as actuator and sensor, respectively and in order to control the vibration responses and loss factor of the structure a proportional-derivative (PD) controller is applied. Furthermore, Halpin-Tsai model is used to determine the material properties of facesheets which are reinforced by graphene platelets (GPLs). Moreover, because the core has magnetic property, it is exposed to magnetic field. In addition, Kelvin-Voigt theory is applied to calculate the structural damping of the piezoelectric layers. In order to consider environmental forces applied to structure, the visco-Pasternak model is assumed. In order to consider the mechanical behavior of structure, sinusoidal shear deformation theory (SSDT) is assumed and Hamilton's principle according to piezoelasticity theory is employed to calculate motion equations and these equations are solved based on differential cubature method (DCM) to obtain the vibration and modal loss factor of the structure subsequently. The effect of different factors such as GPLs distribution, dimensions of structure, electro-magnetic field, damping of structure, viscoelastic environment and boundary conditions of the structure on the vibration and loss factor of the system are considered. In order to indicate the accuracy of the obtained results, the results are validated with other published work. It is concluded from results that exposing magnetic field to the MR fluid core has positive effect on the behavior of the system.