• 대한화학회지
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• 제26권6호
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• pp.363-368
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• 1982

피리딘과 요오드, 일브롬화요오드 및 일염화요오드 사이에 생성되는 전하이동 착물을 사염화탄소 용액내에서 자외선 분광 광도법을 사용하여 연구한 결과$ C_5H_5N{\cdot}I_2}$, $ C_5H_5N{\cdot}IBr$ 및 $ C_5H_5N{\cdot}ICl$형의 1:1 분자 착물이 생성됨을 알았다. 이들 착물 생성에 대한 흡수최대는 온도가 상승함에 따라 blue shift 되므로 이를 고려하여 각 온도에서의 평형 상수와 흡광계수를 구하였다. 이 값으로부터 이들 착물 생성에 대한 ${\Delta}H$, ${\Delta}D$및${\Delta}S$의 열역학적 파라미터를 산출하였다. 이 결과 착물의 상대적 안정도가 다음과 같은 순서로 됨을 알 수 있었다. $ C_5H_5N{\cdot}I_2$ < $ C_5H_5N{\cdot}IBr$ < $ C_5H_5N{\cdot}ICl$ 이 순서는 피리딘에 대한 그들의 상대적 산성도를 의미하며 전자수용체의 편극율 및 할로겐 원자의 전기 음성도의 차이에 의하여 설명될 수 있다.

• 정보관리학회지
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• 제23권2호
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• pp.265-285
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• 2006

문헌범주화에서는 학습문헌집합에 부여된 주제범주의 정확성이 일정 수준을 가진다고 가정한다. 그러나, 이는 실제 문헌집단에 대한 지식이 없이 이루어진 가정이다. 본 연구는 실제 문헌집단에서 기 부여된 주제범주의 정확성의 수준을 알아보고, 학습문헌집합에 기 부여된 주제범주의 정확도와 문헌범주화 성능과의 관계를 확인하려고 시도하였다. 특히, 학습문헌집합에 부여된 주제범주의 질을 수작업 재색인을 통하여 향상시킴으로써 어느 정도까지 범주화 성능을 향상시킬 수 있는가를 파악하고자 하였다. 이를 위하여 과학기술분야의 1,150 초록 레코드 1,150건을 전문가 집단을 활용하여 재색인한 후, 15개의 중복문헌을 제거하고 907개의 학습문헌집합과 227개의 실험문헌집합으로 나누었다. 이들을 초기문헌집단, Recat-1, Recat-2의 재 색인 이전과 이후 문헌집단의 범주화 성능을 kNN 분류기를 이용하여 비교하였다. 초기문헌집단의 범주부여 평균 정확성은 16%였으며, 이 문헌집단의 범주화 성능은 $F_1$값으로 17%였다. 반면, 주제범주의 정확성을 향상시킨 Recat-1 집단은 $F_1$값 61%로 초기문헌집단의 성능을 3.6배나 향상시켰다.

• Asian-Australasian Journal of Animal Sciences
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• 제31권4호
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• pp.595-606
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• 2018

Objective: The Fusarium mycotoxins of deoxynivalenol (DON) and zerolenone (ZEN) cause health hazards for both humans and farm animals. Therefore, the main intention of this study was to reveal DON and ZEN effects on the mRNA expression of pro-inflammatory cytokines and other immune related genes in the liver of piglets. Methods: In the present study, 15 six-week-old piglets were randomly assigned to the following three different dietary treatments for 4 weeks: control diet, diet containing 8 mg DON/kg feed, and diet containing 0.8 mg ZEN/kg feed. After 4 weeks, liver samples were collected and sequenced using RNA-Seq to investigate the effects of the mycotoxins on genes and gene networks associated with the immune systems of the piglets. Results: Our analysis identified a total of 249 differentially expressed genes (DEGs), which included 99 upregulated and 150 downregulated genes in both the DON and ZEN dietary treatment groups. After biological pathway analysis, the DEGs were determined to be significantly enriched in gene ontology terms associated with many biological pathways, including immune response and cellular and metabolic processes. Consistent with inflammatory stimulation due to the mycotoxin-contaminated diet, the following Kyoto encyclopedia of genes and genomes pathways, which were related to disease and immune responses, were found to be enriched in the DEGs: allograft rejection pathway, cell adhesion molecules, graft-versus-host disease, autoimmune thyroid disease (AITD), type I diabetes mellitus, human T-cell leukemia lymphoma virus infection, and viral carcinogenesis. Genome-wide expression analysis revealed that DON and ZEN treatments downregulated the expression of the majority of the DEGs that were associated with inflammatory cytokines (interleukin 10 receptor, beta, chemokine [C-X-C motif] ligand 9), proliferation (insulin-like growth factor 1, major facilitator superfamily domain containing 2A, insulin-like growth factor binding protein 2, lipase G, and salt inducible kinase 1), and other immune response networks (paired immunoglobulin-like type 2 receptor beta, Src-like-adaptor-1 [SLA1], SLA3, SLA5, SLA7, claudin 4, nicotinamide N-methyltransferase, thyrotropin-releasing hormone degrading enzyme, ubiquitin D, histone $H_2B$ type 1, and serum amyloid A). Conclusion: In summary, our results demonstrated that high concentrations DON and ZEN disrupt immune-related processes in the liver.

• 대한치과보철학회지
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• 제42권5호
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• pp.535-543
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• 2004

Purpose: The purpose of this study is to compare the effect of two fiber post systems and one metal cast post system on the fracture strength and fracture pattern of crowned, endodontically treated teeth with 2 mm-height of the reamining tooth structure. Materials and methods: A total of 36 recently extracted sound human mandibular premolars were selected Each tooth structure of the crown portion except 2mm-height of the one above the cementoenamel junction was removed. After being endodontically treated, they were randomly distributed into 3 groups: group 1, restored with quarts fiber post(D.T. Light-Post), group 2, with glass fiber post(FRC Postec), and group 3, metal cast post and core. All teeth were fully covered with nonprecious metal crowns. Each specimen was embedded in an acrylic resin block and then secured in a universal load-testing machine. A compressive load was applied at a 130 degree angle to the long axis of the tooth until fractured, at a crosshead speed 20mm/min. The highest fracture loads were measured and recorded as the fracture strength of each specimen. Fracture areas were measured on the mid-buccal and mid-lingual point from the crown margins. One-way analysis of variance and Turkey test were used to determine the statistic significance of the different fracture loads and areas among the groups (p<0.05). Results: The mean fracture loads were $1391{\pm}$425N(group 1), $1458{\pm}476N$(group 2) and $1301{\pm}319N$(group 3). The fracture loads among the three groups had no statistically signifiant difference (p>.05). The mean fracture area of the fiber post was closer to the crown margin than that of the metal cast post and core(p<.05). The metal cast post showed unrestorable and catastrophic fracture patterns. Conclusion: Within the limitations of this study, fracture loads with any statistically significant difference were not recorded for endodontically treated teeth restored with two fiber posts and the metal cast post. But teeth restored with the fiber posts typically showed the fracture pattern close to the crown margin, which was almost restorable.

• 문화기술의 융합
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• 제6권2호
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• pp.437-447
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• 2020

본 연구의 목적은 드론 기반 스마트 방역 연구로서 드론을 방재 분야에 활용을 통한 대응방안과 기대효과를 연구하는 것이다. 현행 방재업무의 문제점에 대한 검토와 이에 따른 대응안을 환경적, 시장적, 기술적 접근으로 살펴보면 다음과 같다. 첫째로 환경적 측면에서 드론 기반 관제를 활용한 방재업무의 활용 효과는 산림, 조류인플루엔자, 가축, 시설지역, 모기 유충, 해충 등 광범위한 활용과 AI 및 콜레라 등 각종 방역업무 단순화 및 효과적 방역체계 제공 할 수 있다. 둘째, 시장적 측면에서 방역방법의 신기술 도입을 통한 국내 표준화 드론을 활용한 소독방역 임무 활용에 따른 축산·가축 방역 관련 법령, 행정규칙의 기준마련, 관련 산업의 동반성장과 신시장 발굴, 가축 질병 방역에 투입되는 연간 예산 절감의 효과를 가져온다. 셋째, 기술적 측면은 (1) 새로운 가축 질병 방역형태인 다중드론 활용 소독 방역의 현장적용, (2) 드론 산업 소프트웨어 분야의 혁신, (3) 다양한 시장에 적용 가능한 드론 관제/제어 통합시스템으로 산업 다변화, (4) 빅데이터 드론 이동로 3차원 공간정보 분석 정밀 드론 교통정보제공으로 안전성 높은 비행 보장, (5) 다수의 드론 동시 자동 임무 비행이 가능하여 저비용 고효율 시스템 보급 실현, (6) 고도의 정밀 비행기술 불필요에 따른 분야별 드론 이용자 증가로 고찰되었다. 본 연구는 문헌 조사와 전문가의 의견을 기반으로 작성되어 향후 연구 분야는 드론 기반 서비스에 대한 실증적 자료를 기반으로 그 효과에 대해 입증하는 작업이 필요하다. 본 연구의 기대효과는 드론을 방재업무에 적극적 활용 지원 또는 이와 관련된 정책을 수립하는데 이바지 한다.

• 한국통신학회논문지
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• 제27권1A호
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• pp.26-34
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• 2002

IS-95 또는 IMT-2000 등의 이동통신 시스템에서는 10~20msec 길이의 프레임 단위로 정보를 교환하게 되므로 수신측에서는 이와 같은 크기의 프레임을 저장할 버퍼가 필요하다. 연성판정 비터비 복호기를 사용할 때, 이를 위한 버퍼의 크기, 즉 한 프레임에 들어 있는 비트 수는 길쌈부호의 부호율(1 대 n), 전송속도(bps), 그리고 연성판정 비트 수에 비례하여 증가한다. 본 논문에서는 연성판정 비트 수를 4 비트에서 3 비트로 낮추면서 비터비 복호기의 성능 저하를 줄이기 위한 양자화 방법을 제안한다. 연성판정 비트 수(4,3,2,1)별로 양자화 판정 기준 점의 오프셋 크기와 양자화 간격에 대해 비터비 복호기의 성능을 AWGN 환경에서 시뮬레이션 하였고, 이를 토대로 최적의 BER 성능을 갖는 오프셋 크기와 양자화 간격을 결정하였다. 그 결과로서 4 비트 연성판정의 성능에 근접하는 3비트 연성판정 양자화 방법을 도출하였고, IS-95(4 비트)의 최대 40배의 전송속도를 지원하는 IMT-2000 시스템에 적용하였을 대 미미한 성능 손실(-0.05 dB)을 유지하면서 입력 버퍼의 크기를 3/4 배로 줄일 수 있음을 보였다. 또한, 다양한 전송속도에 따라 반복된 누산 입력신호를 제안된 비트 수로 변환하기 위한 최적 SMT(symbol metric table)를 고안하였다.

• 대한기계학회논문집A
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• 제36권1호
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• pp.9-16
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• 2012

최근 태양광발전 시스템에서 태양광을 집광하는 광학기술이 접목된 집광기가 대두되고 있다. 본 연구에서는 광도파로 원리를 기반으로 한, 간단하면서 생산이 용이한 새로운 개념의 평면형 집광기를 제안하였다. 해당 집광기에서는 태양광 집광을 위하여 빛의 전반사와 굴절의 법칙에 의해 빛을 유도하는 마이크로 단위의 광학 패턴이 적용되었다. 본 집광기의 주요 설계변수로는 광도파 집광기의 기하집 광비 $R_c$와 마이크로 패턴의 두 각도 ${\Theta}_1$, ${\Theta}_2$를 선정하였다. 광학해석을 위한 시뮬레이션은 SPEOS로 수행되었으며 주요 설계변수의 변화에 따른 집광기의 광학효율을 예측하였다. 기하집광비 4, 5, 6에 대해서 광학효율 최대치가 각각 65.60%, 54.78%, 46.78%로 예측되었다. 집광기의 마이크로 패턴의 두 각도 ${\Theta}_1$, ${\Theta}_2$ 및 태양광 입사각에 따른 광학효율도 예측하였다.

• Elastomers and Composites
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• 제34권2호
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• pp.156-176
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• 1999

Rubber chemicals such as accelerators, antidegradants, vulcanizing agents, processing agents and retarders are very important to the production and protection of tires and rubber goods. The use of accelerators and antidegradants are evaluated in various tire components. This paper will focus on how to vulcanize tires economically and maintain the physical properties of each tire component without severe degradation due to oxygen, heat and ozone. Also, new non-nitrosoamine accelerators and non-staining antiozonants will be discussed. Lastly, the future requirements of antidegradants and accelerators in the tire industry will be reviewed. Tires have been vulcanized with Sulfenamides as primary accelerators and either Guamdine's or Thiurams as secondary accelerators to achieve proper properties at service conditions. However, interior components such as the carcass can be vulcanized with Thiazoles as a primary accelerator to cure faster than the external components. Using the combination of Sulfenamide with secondary accelerators in a tire tread compound and the combination of a Thiazole and Guanidine in a carcass compound will be presented with performance data. Uniroyal Chemical and another Rubber Chemical Manufacturer have developed, "Tetrabenzyl Thiuram Disulfide," (TBzTD) as a non-Nitrosoamine accelerator, which could replace Nitrosoamine generating Thiurams. This new accelerator has been evaluated in a tread compound as a secondary accelerator. Also, Flexsys has developed N-t-butyl-2-benzothiazole Sulfenamide (TBSI) as a non-Nitrosoamine accelerator which could replace 2-(Morpholinothio) -benzothiazole (MBS), a scorch delayed Sulfendamide accelerator. TBSI has been evaluated in a Natural Rubber (NR) belt skim compound vs. MBS. An optimum low rolling resistant cure system has been developed in a NR tread with Dithiomorpholine (DTDM). Also, future requirements for developing accelerators will be discussed such as the replacement of DTDM and other stable crosslink systems. Antidegradants are divided into two different types for use in tire compounds. Internal tire compounds such as apex, carcass, liner, wire breaker, cushion, base tread and bead compounds are protected by antioxidants against degradation from oxygen and heat due to mechanical shear. The external components such as sidewall, chafer and cap tread com-pounds are protected from ozone by antiozonants and waxes. Various kinds of staining and non-staining antioxidants have been evaluated in a tire carcass compound. Also, various para-phenylene diamine antiozonants have been evaluated in a tire sidewall compound to achieve the improved lifetime of the tire. New non-staining antiozonants such as 2, 4, 6-tris-(N-1, 4-dimethylpentyl-p-phenylene diamine) 1, 3, 5 Trizine (D-37) and un-saturated Acetal (AFS) will be discussed in the tire sidewall to achieve better appearance. The future requirements of antidegradants will be presented to improve tire performance such as durability, better appearance and longer lasting tires.

• Journal of Astronomy and Space Sciences
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• 제30권4호
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• pp.269-277
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• 2013

In this study, we present results of precise orbital geodetic parameter estimation using satellite laser ranging (SLR) observations for the International Laser Ranging Service (ILRS) associate analysis center (AAC). Using normal point observations of LAGEOS-1, LAGEOS-2, ETALON-1, and ETALON-2 in SLR consolidated laser ranging data format, the NASA/GSFC GEODYN II and SOLVE software programs were utilized for precise orbit determination (POD) and finding solutions of a terrestrial reference frame (TRF) and Earth orientation parameters (EOPs). For POD, a weekly-based orbit determination strategy was employed to process SLR observations taken from 20 weeks in 2013. For solutions of TRF and EOPs, loosely constrained scheme was used to integrate POD results of four geodetic SLR satellites. The coordinates of 11 ILRS core sites were determined and daily polar motion and polar motion rates were estimated. The root mean square (RMS) value of post-fit residuals was used for orbit quality assessment, and both the stability of TRF and the precision of EOPs by external comparison were analyzed for verification of our solutions. Results of post-fit residuals show that the RMS of the orbits of LAGEOS-1 and LAGEOS-2 are 1.20 and 1.12 cm, and those of ETALON-1 and ETALON-2 are 1.02 and 1.11 cm, respectively. The stability analysis of TRF shows that the mean value of 3D stability of the coordinates of 11 ILRS core sites is 7.0 mm. An external comparison, with respect to International Earth rotation and Reference systems Service (IERS) 08 C04 results, shows that standard deviations of polar motion $X_P$ and $Y_P$ are 0.754 milliarcseconds (mas) and 0.576 mas, respectively. Our results of precise orbital and geodetic parameter estimation are reasonable and help advance research at ILRS AAC.

• Animal Bioscience
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• 제34권11호
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• pp.1811-1821
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• 2021

Objective: A trial was conducted to investigate the effects of supplemental levels of Mn provided by organic and inorganic trace mineral supplements on growth, tissue mineralization, mineral balance, and antioxidant status of growing broiler chicks. Methods: A total of 500 male chicks (8-d-old) were used in 10-day feeding trial, with 10 treatments and 10 replicates of 5 chicks per treatment. A 2×5 factorial design was used where supplemental Mn levels (0, 25, 50, 75, and 100 mg Mn/kg diet) were provided as MnSO₄·H₂O or MnPro. When Mn was supplied as MnPro, supplements of zinc, copper, iron, and selenium were supplied as organic minerals, whereas in MnSO₄·H₂O supplemented diets, inorganic salts were used as sources of other trace minerals. Performance data were fitted to a linearbroken line regression model to estimate the optimal supplemental Mn levels. Results: Manganese supplementation improved body weight, average daily gain (ADG) and feed conversion ratio (FCR) compared with chicks fed diets not supplemented with Mn. Manganese in liver, breast muscle, and tibia were greatest at 50, 75, and 100 mg supplemental Mn/kg diet, respectively. Higher activities of glutathione peroxidase and superoxide dismutase (total-SOD) were found in both liver and breast muscle of chicks fed diets supplemented with inorganic minerals. In chicks fed MnSO₄·H₂O, ADG, FCR, Mn balance, and concentration in liver were optimized at 59.8, 74.3, 20.6, and 43.1 mg supplemental Mn/kg diet, respectively. In MnPro fed chicks, ADG, FCR, Mn balance, and concentration in liver and breast were optimized at 20.6, 38.0, 16.6, 33.5, and 62.3 mg supplemental Mn/kg, respectively. Conclusion: Lower levels of organic Mn were required by growing chicks for performance optimization compared to inorganic Mn. Based on the FCR, the ideal supplemental levels of organic and inorganic Mn in chick feeds were 38.0 and 74.3 mg Mn/kg diet, respectively.