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Mechanical and thermodynamic stability, structural, electronics and magnetic properties of new ternary thorium-phosphide silicides ThSixP1-x: First-principles investigation and prospects for clean nuclear energy applications

  • Siddique, Muhammad;Iqbal, Azmat;Rahman, Amin Ur;Azam, Sikander;Zada, Zeshan;Talat, Nazia
    • Nuclear Engineering and Technology
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    • v.53 no.2
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    • pp.592-602
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    • 2021
  • Thorium compounds have attracted immense scientific and technological attention with regard to both fundamental and practical implications, owing to unique chemical and physical properties like high melting point, high density and thermal conductivity. Hereby, we investigate the mechanical and thermodynamic stability and report on the structural, electronic and magnetic properties of new silicon-doped cubic ternary thorium phosphides ThSixP1-x (x = 0, 0.25, 0.5, 0.75 and 1). The first-principles density functional theory procedure was adopted within full-potential linearized augmented plane wave (FP-LAPW) method. The exchange and correlation potential terms were treated within Generalized-Gradient-Approximation functional modified by Perdew-Burke-Ernzerrhof parameterizations. The proposed compounds showed mechanical and thermodynamic stable structure and hence can be synthesized experimentally. The calculated lattice parameters, bulk modulus, total energy, density of states, electronic band structure and spin magnetic moments of the compounds revealed considerable correlation to the Si substitution for P and the relative Si/P doping concentration. The electronic and magnetic properties of the doped compounds rendered them non-magnetic but metallic in nature. The main orbital contribution to the Fermi level arises from the hybridization of Th(6d+5f) and (Si+P)3p states. Reported results may have potential implications with regard to both fundamental point of view and technological prospects such as fuel materials for clean nuclear energy.

A first-principles theoretical investigation of the structural, electronic and magnetic properties of cubic thorium carbonitrides ThCxN(1-x)

  • Siddique, Muhammad;Rahman, Amin Ur;Iqbal, Azmat;Azam, Sikander
    • Nuclear Engineering and Technology
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    • v.51 no.5
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    • pp.1373-1380
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    • 2019
  • Besides promising implications as fertile nuclear materials, thorium carbonitrides are of great interest owing to their peculiar physical and chemical properties, such as high density, high melting point, good thermal conductivity. This paper reports first-principles simulation results on the structural, electronic and magnetic properties of cubic thorium carbonitrides $ThC_xN_{(1-x)}$ (X = 0.03125, 0.0625, 0.09375, 0.125, 0.15625) employing formalism of density-functional-theory. For the simulation of physical properties, we incorporated full-potential linearized augmented plane-wave (FPLAPW) method while the exchange-correlation potential terms in Kohn-Sham Equation (KSE) are treated within Generalized-Gradient-Approximation (GGA) in conjunction with Perdew-Bruke-Ernzerhof (PBE) correction. The structural parameters were calculated by fitting total energy into the Murnaghan's equation of state. The lattice constants, bulk moduli, total energy, electronic band structure and spin magnetic moments of the compounds show dependence on the C/N concentration ratio. The electronic and magnetic properties have revealed non-magnetic but metallic character of the compounds. The main contribution to density of states at the Fermi level stems from the comparable spectral intensity of Th (6d+5f) and (C+N) 2p states. In comparison with spin magnetic moments of ThSb and ThBi calculated earlier with LDA+U approach, we observed an enhancement in the spin magnetic moments after carbon-doping into ThN monopnictide.

Distance Sensing of Moving Target with Frequency Control of 2.4 GHz Doppler Radar (2.4 GHz 도플러 레이다의 주파수 조정을 통한 이동체 거리 센싱)

  • Baik, Kyung-Jin;Jang, Byung-Jun
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
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    • v.30 no.2
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    • pp.152-159
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    • 2019
  • In general, a Doppler radar can measure only the velocity of a moving target. To measure the distance of a moving target, it is necessary to use a frequency-modulated continuous wave or pulse radar. However, the latter are very complex in terms of both hardware as well as signal processing. Moreover, the requirement of wide bandwidth necessitates the use of millimeter-wave frequency bands of 24 GHz and 77 GHz. Recently, a new kind of Doppler radar using multitone frequency has been studied to sense the distance of moving targets in addition to their speed. In this study, we show that distance sensing of moving targets is possible by adjusting only the frequency of a 2.4 GHz Doppler radar with low cost phase lock loop. In particular, we show that distance can be sensed using only alternating current information without direct current offset information. The proposed technology satisfies the Korean local standard for low power radio equipment for moving target identification in the 2.4 GHz frequency band, and enables multiple long-range sensing and radio-frequency identification applications.

Optical Properties of Y3Al5O12;Ce3+,Pr3+ Transparent Ceramic Phosphor for High Power White Lighting (고출력 백색 광원용 Y3Al5O12;Ce3+,Pr3+ 투명 세라믹 형광체의 광학특성)

  • Kang, Taewook;Lim, Seokgyu;Kim, Jongsu;Jeong, Yongseok
    • Korean Journal of Materials Research
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    • v.29 no.2
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    • pp.116-120
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    • 2019
  • We prepared $Y_3Al_5O_{12};Ce^{3+},Pr3^{+}$ transparent ceramic phosphor using a solid state reaction method. By XRD pattern analysis and SEM measurement, our phosphors reveal an Ia-3d(230) space group of cubic structure, and the transparent ceramic phosphor has a polycrystal state with some internal cracks and pores. In the Raman scattering measurement with an increasing temperature, lattice vibrations of the transparent ceramic phosphor decrease due to its more perfect crystal structure and symmetry. Thus, low phonon generation is possible at high temperature. Optical properties of the transparent ceramic phosphor have broader excitation spectra due to a large internal reflection. There is a wide emission band from the green to yellow region, and the red color emission between 610 nm and 640 nm is also observed. The red-yellow phosphor optical characteristics enable a high Color Rendering Index (CRI) in combination with blue emitting LED or LD. Due to its good thermal properties of low phonon generation at high temperature and a wide emission range for high CRI characteristics, the transparent ceramic phosphor is shown to be a good candidate for high power solid state white lighting.

Polarimetry of Three Asteroids in Comet-Like Orbits (ACOs)

  • Geem, Jooyeon;Ishiguro, Masateru;Bach, Yoonsoo P.;Kuroda, Daisuke;Naito, Hiroyuki;Hanayama, Hidekazu;Kim, Yoonyoung;Kwon, Yuna G.;Jin, Sunho;Sekiguchi, Tomohiko;Okazaki, Ryo;Vaubaillon, Jeremie J.;Imai, Masataka;Ono, Tatsuharu;Futamuts, Yuki;Takagi, Seiko;Sato, Mitsuteru;Kuramoto, Kiyoshi;Watanabe, Makoto
    • The Bulletin of The Korean Astronomical Society
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    • v.44 no.1
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    • pp.65-65
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    • 2019
  • Near-Earth objects consist of a mixture of bodies originated from outer solar system and main asteroidal belt, which are recognized as comets and near-Earth asteroids. In principal, they have orbits distinguishable by their orbital elements. It is, however, that some comets are recognized as asteroids because they could have lost the most of volatile materials in their subsurface layers. Due to their asteroidal appearances, it has been challenging to discriminate such dormant comets from a list of known asteroids. Here we propose to utilize polarimetric technique for finding such dormant comets. We thus conducted a polarimetric observations of three candidates of dormant comet nuclei, (331471) 1984 QY1, (3552) Don Quixote and (944) Hidalgo, by using the 1.6-m Pirka Telescope at the Nayoro observatory (operated by Hokkaido University, Japan). We selected these asteroids in comet-like orbits (ACOs) based on the orbital elements (i.e., the Tisserand parameter with respect to Jupiter TJ < 3). We found that 1984 QY1 has a polarimetric albedo (geometric albedo determined via polarimetry) pV = 0.16 +/- 0.06 while both Don Quixote and Hidalgo have Rc-band polarimetric albedos pR < 0.05. In accordance with the polarimetric result together with a dynamical analysis, we surmised that 1984 QY1 could be an S-type asteroid evolved into the current orbit via 3:1 mean motion resonance with Jupiter. On the contrary, the previous spectroscopic studies indicated that Don Quixote and Hidalgo are classified into D-type taxonomic group, which are typical of comet nuclei. In this presentation, we will introduce our polarimetric observations of ACOs and emphasize that polarimetry is powerful for discriminating the asteroidal and cometary origins.

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Searching for LSB Dwarf Satellite Galaxies Around Nearby Galaxies in IMSNG Data

  • Lim, Gu;Im, Myungshin;Kim, Jisu;Lee, Jeong Hwan;Choi, Changsu;Ehgamberdiev, S.;Burkhonov, O.;Mirzaqulov, D.
    • The Bulletin of The Korean Astronomical Society
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    • v.44 no.1
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    • pp.75.2-75.2
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    • 2019
  • Low surface brightness (LSB) dwarf galaxies hold a key to resolve the small-scale problems of Lambda Cold Dark Matter (LCDM) paradigm such as missing satellites problem. Many recent studies found LSB dwarf galaxies around massive galaxies beyond Local Group up to 10Mpc. Motivated by this, we can increase the number of them by searching for LSB dwarf galaxies around galaxies up to 40Mpc. We use stacked deep (${\mu}_R{\sim}26.2mag\;arcsec^{-2}$) optical B, R-band images taken from Maidanak 1.5m telescope, one of facilities of Intensive Monitoring Survey of Nearby Galaxies (IMSNG) which monitored nearby galaxies in a day cadence from 2014 to 2016. Extended LSB sources in ambient regions of 16 nearby galaxies are selected using central surface brightness and total R magnitude criteria. After that, 24 LSB dwarf candidates are selected with visual inspection. To identify if the candidates are satellites or not, we are trying to compare the number density of LSB dwarf candidates around massive galaxies with those in Canada-France-Hawaii-Telescope Legacy Survey (CFHTLS) wide fields which have no dominant massive galaxies for control sample.

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Quality Enhancement of Wave Data Observed by Radar at the Socheongcho Ocean Research Station (소청초 종합해양과학기지 Radar 파랑 관측 데이터의 신뢰도 향상)

  • Min, Yongchim;Jeong, JinYong;Shim, Jae-Seol;Do, Kideok
    • Journal of Coastal Disaster Prevention
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    • v.4 no.4
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    • pp.189-196
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    • 2017
  • Ocean Research Stations (ORSs) is the ocean platform type observation towers and measured oceanic, atmospheric and environmental data. These station located on the offshore area far from the coast, so they can produce the data without land effect. This study focused to improve the wave data quality of ORS station. The wave observations at ORSs are used by the C-band (5.8 GHz, 5.17 cm) MIROS Wave and Current Radar (MWR). MWR is convenient to maintenance and produce reliability wave data under bad weather conditions. MWR measured significant wave height, peak wave period, peak wave direction and 2D wave spectrum, so it's can provide wave information for researchers and engineers. In order to improve the reliability of MWR wave data, Datawell Waverider Buoy was installed near the one ORS (Socheoncho station) during 7 months and validate the wave data of MWR. This study found that the wave radar tend to be overestimate the low wave height under wind condition. Firstly, this study carried out the wave Quality Control (QC) using wind data, however the quality of wave data was limited. So, this study applied the four filters (Correlation Check, Direction Filter, Reduce White Noise and Phillips Check) of MWR operating software and find that the filters effectively improve the wave data quality. After applying 3 effective filters in combination, the RMSE of significant wave height decreased from 0.81m to 0.23m, by 0.58m and Correlation increased from 0.66 to 0.96, by 0.32, so the reliability of MWR significant wave height was significantly improved.

The Effect of Fascial Distortion Model on Maximal Grip Strength, Force Sense and Range of Motion (근막변형모델이 최대악력, 힘 감각 그리고 관절가동범위에 미치는 효과)

  • Kim, Ji-Young;Kim, Seong-Yeol
    • Journal of The Korean Society of Integrative Medicine
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    • v.9 no.1
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    • pp.33-40
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    • 2021
  • Purpose : The fascia is the body's largest sensory organ affected by mechanical stimuli such as pressure. Fascial distortion model (FDM) is one of the fascia treatment techniques, and it is based that most musculoskeletal problems are caused by three-dimensional distortion of the fascia. Until now, some studies have been conducted to investigate the effect of FDM, but it is still not enough. In this study, among the six techniques of FDM, trigger band (TB) and cylinder distortion (CyD) were applied to the forearm to investigate the immediate effect on the maximal grip strength, force sense and range of motion. Methods : 22 healthy adults in their 20s and 30s participated. Before and after the application of FDM, maximal grip strength, force sense and range of motion were measured. For analysis, a paired t-test was performed, and the significance level was set to p<.05. Results : After FDM, there were a significant differences that increased the force sense and the range of motion (p<.05). But the maximal grip strength did not show a significant difference (p>.05). Conclusion : The results of this study, the FDM did not affect maximal grip strength, but it was shown to increase the sense of force and range of motion. We assumed that it is the result of the changes in the states of the fascia and changes in the activity of mechanical receptors induced by pressure and stretch from FDM application.

RC Snubber Analysis for Oscillation Reduction in Half-Bridge Configurations using Cascode GaN (Cascode GaN의 하프 브릿지 구성에서 오실레이션 저감을 위한 RC 스너버 분석)

  • Bongwoo, Kwak
    • Journal of IKEEE
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    • v.26 no.4
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    • pp.553-559
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    • 2022
  • In this paper, RC snubber circuit design technology for oscillation suppression in half-bridge configuration of cascode gallium nitride (GaN) field effect transistors (FETs) is analyzed. A typical wide band-gap (WBG) device, cascode GaN FET, has excellent high-speed switching characteristics. However, due to such high-speed switching characteristics, a false turn-off problem is caused, and an RC snubber circuit is essential to suppress this. In this paper, the commonly used experimental-based RC snubber design technique and the RC snubber design technique using the root locus method are compared and analyzed. In the general method, continuous circuit changes are required until the oscillation suppression performance requirement is met based on experimental experience . However, in root locus method, the initial value can be set based on the non-oscillation R-C map. To compare the performance of the two aforementioned design methods, a simulation experiment and a switching experiment using an actual double pulse circuit are performed.

Measurement and Analysis of Physical Environmental Load during Handling and Distribution of Domestic Fruits -Focused on Seongju Korean Melon

  • Jongmin Park;Donghyun Kim;Wontae Seo;Hyunmo Jung
    • KOREAN JOURNAL OF PACKAGING SCIENCE & TECHNOLOGY
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    • v.29 no.2
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    • pp.129-138
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    • 2023
  • The proportion of agricultural products handled through the Agricultural Products Processing Center (APC) is also steadily increasing every year, and in the case of Seongju Korean melon, a total of 10 APCs of Nonghyup and farming association corporations are in operation, and the distribution ratio is about 60% based on total production. In this study, Seongju Korean melon was selected as a target to analyze the environment load during carrying (production farm ~ APC) in the production area and the transport environment load during distribution of domestic fruits, and to analyze the environmental load for handling at APC. The vertical average vibration intensity (overall Grms of 1~250 Hz) of truck transport measured at three transport routes from Seongju Korean melon producer ~ APC, Seongju ~ Seoul and Seongju ~ Jeju was about three times larger than that in the lateral direction and 4.5 times larger than that in the longitudinal direction, respectively. The frequency of occurrence of high-amplitude events (G) in the vertical direction compared to the measuring time was deeply related to pavement conditions in the order of unpaved farm-roads, concretepaved farm-roads, and asphalt-paved main-roads, but overall Grms for the entire frequency band is believed to have a greater impact on vehicle traveling speed than road conditions. On the other hand, the difference in the size and direction of the vibration intensity measured by the forklift truck's main-body and the attachment (fork carrier) during handling at Seongju Korean melon APC was clear, and the vibration intensity of the forklift truck's main-body was largely affected by the stiffness of the fork and the mast according to the handling weight. Based on the field-data of the transport environment during domestic distribution measured through this study, it is believed that it is possible to develop a lab-based simulation protocol for appropriate packaging design.