• 제목/요약/키워드: Cycling Behavior

검색결과 140건 처리시간 0.032초

Synthesis and Performance of Li2MnSiO4 as an Electrode Material for Hybrid Supercapacitor Applications

  • Karthikeyan, K.;Amaresh, S.;Son, J.N.;Lee, Y.S.
    • Journal of Electrochemical Science and Technology
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    • 제3권2호
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    • pp.72-79
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    • 2012
  • $Li_2MnSiO_4$ was synthesized using the solid-state method under an Ar atmosphere at three different calcination temperatures (900, 950, and $1000^{\circ}C$). The optimization of the carbon coating was also carried out using various molar concentrations of adipic acid as the carbon source. The XRD pattern confirmed that the resulting $Li_2MnSiO_4$ particles exhibited an orthorhombic structure with a $Pmn2_1$ space group. Cyclic voltammetry was utilized to investigate the capacitive behavior of $Li_2MnSiO_4$ along with activated carbon (AC) in a hybrid supercapacitor with a two-electrode cell configuration. The $Li_2MnSiO_4$/AC cell exhibited a high discharge capacitance and energy density of $43.2Fg^{-1}$ and $54Whkg^{-1}$, respectively, at $1.0mAcm^{-2}$. The $Li_2MnSiO_4$/AC hybrid supercapacitor exhibited an excellent cycling stability over 1000 measured cycles with coulombic efficiency over > 99 %. Electrochemical impedance spectroscopy was conducted to corroborate the results that were obtained and described.

리튬이온이차전지용 LiCoO2-유기전해액의 충전상태에 따른 열적 안정성 (Thermal Stability of Delithiated LiCoO2-organic Electrolyte for Lithium-Ion Rechargeable Batteries)

  • 김동훈;이영호;신혜민;정영동;도칠훈;진봉수;김현수;문성인;오대희;김기원
    • 한국전기전자재료학회논문지
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    • 제20권5호
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    • pp.421-424
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    • 2007
  • Thermal behavior of $Li_{1-x}CoO_2$ has been investigated employing DSC (Differential Scanning calorimetry) and TGA (Thermogravimetry Analyzer), and the crystal parameters were calculated from XRD (X-ray diffraction).for the commercial rectangular pouch cell(1000 mAh).The cathode materials coated over aluminium foil current collector is made up of a blend consisting of active material $LiCoO_2$(size $20\;{\mu}m$, 94 wt%), conducting material super p black (SPB, 3 wt%) and binder polyvinylidene fluoride (PVDF, 3 wt%). The anode is a mix consisting of carbon (92 wt%) and PVDF(8 wt%) coated over copper foil. The cells for the experiments were first preconditioned by cycling three times and stabilized at OCV=3.0, 3.5, 4.2, 4.35 and 4.5 V. The stabilized cathode material was used for thermal and crystal parameter investigations.

Effectiveness of R/C jacketing of substandard R/C columns with short lap splices

  • Kalogeropoulos, George I.;Tsonos, Alexander G.
    • Structural Monitoring and Maintenance
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    • 제1권3호
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    • pp.273-292
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    • 2014
  • The effectiveness of a retrofitting method for concrete columns with particular weaknesses is experimentally evaluated and presented in this paper. Structural deficiencies namely the inadequacy of transverse reinforcement and short length of lap splices are very common in columns found in structures built prior to the 1960s and 1970s. Recent earthquakes worldwide have caused severe damages and collapses of these structures. Nevertheless, the importance of improving the load transfer capacity between the deficiently lap-spliced bars is usually underestimated during the strengthening procedures applied in old buildings, though critical for the safety of the residents' lives. Thus, the seismic performance of the enhanced columns is frequently overestimated. The retrofitting approach presented herein involves reinforced concrete jacketing of the column sub-assemblages and welding of the lap-spliced bars to prevent the splice failure and conform to the provisions of modern design Codes. The cyclic lateral loading response of poorly confined original column specimens with insufficient lap splices and the seismic behavior of the retrofitted columns are compared. Test results clearly demonstrate that the retrofitting procedure followed is an effective way of significantly improving the seismic performance of substandard columns found in old buildings.

Effects of PGF2 α and GnRH during Different Ovarian Status at Onset of Puberty in Murrah Buffalo Heifers (Bubalus bubalis)

  • Singh, c.;Madan, M.L.
    • Asian-Australasian Journal of Animal Sciences
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    • 제13권8호
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    • pp.1059-1062
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    • 2000
  • The objective of the investigation was to study the effect of intramuscular $PGF_2\;{\alpha}$ and GnRH on estrus behavior and ovarian response in Murrah buffalo heifers. Twelve Murrah buffalo heifers at 32 months of age that had not exhibited behavioral estrus symptom were included in the experiment. Out of 12,4 heifers were in follicular phase (plasma estradiol $57.05{\pm}12.52pg/ml$), another 4 heifers were in luteal phase (Plasma progesterone $2.24{\pm}0.25ng/ml$) while the ovaries of remaining four heifers were inactive (estradiol $23.70{\pm}1.66pg/ml$and progesterone $0.32{\pm}0.06ng/ml$). $PGF_2\;{\alpha}$ (25 mg, Lutalyse, im) and GnRH (200 ug, Fertagyl, iv) was administered to each heifer at interval of 10 days. The plasma progesterone concentration decreased within 48 hrs after $PGF_2\;{\alpha}$ injection and followed thereafter with follicular growth, estrus and ovulation. GnRH administration induced follicular growth, elevation of plasma estradiol concentration with subsequent exhibition of behavioral estrus in 2 out of 4 heifers having inactive ovary. The observation reveals that Murrah buffalo heifers at 32 months of age have developed receptors for $PGF_2\;{\alpha}$ and GnRH on ovarian and pituitary tissue respectively and response the single injection of $PGF_2\;{\alpha}$ and GnRH similar to the mature cycling animals.

Effects of Ubiquitin-conjugating Enzyme 2C on Invasion, Proliferation and Cell Cycling of Lung Cancer Cells

  • Tang, Xiao-Kui;Wang, Ke-Jian;Tang, Yu-Kui;Chen, Li
    • Asian Pacific Journal of Cancer Prevention
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    • 제15권7호
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    • pp.3005-3009
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    • 2014
  • The aims of this study were to investigate the influence of ubiquitin- conjugating enzyme E2C (UBE2C) on biological behavior of lung cancer cells. Using MTT, flow cytometry and invasion assays, we detected UBE2C expression and evaluated its biological properties in these cells, including effects on proliferation, the cell cycle profile and invasive capability. Compared with control cells, the UBE2C transfected cells demonstrated increased cellular proliferation (p<0.05). UBE2C transfected cells also had a lower percentage in G1 phase and a higher percentage in S phase (p<0.05). Importantly, the UBE2C transfected cells had a notable enhancement of cell numbers penetrating the basement membrane compared with the control group (p<0.05). Ectopic up-regulation UBE2C promoted the growth of lung cancer cells in vivo. Furthermore, we found UBE2C increased the expression of cyclin D1 and MMP-2. These results show UBE2C may represent a potential therapeutic target for lung cancer.

가스터빈 블레이드용 IN738LC의 열기계피로수명에 관한 연구 (Thermo-Mechancal Fatigue of the Nickel Base Superalloy IN738LC for Gas Turbine Blades)

  • 에릭 플러리;하정수;현중섭;장석원;정훈
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2000년도 춘계학술대회논문집A
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    • pp.188-193
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    • 2000
  • A more accurate life prediction for gas turbine blade takes into account the material behavior under the complex thermo-mechanical fatigue(TMF) cycles normally encountered in turbine operation. An experimental program has been carried out to address the thermo-mechanical fatigue life of the IN738LC nickel-base superalloy. In the first phase of the study, out-of-phase and in-phase TMF experiments have been performed on uncoated and coated materials. In the temperature range investigated. the deposition of NiCrAlY air plasma sprayed coating did not affect the fatigue resistance. In the second phase of the study, a physically-base life prediction model that takes into account of the contribution of different damage mechanisms has been applied. This model was able to reflect the temperature and strain rate dependences of isothermal cycling fatigue lives, and the strain-temperature history effect on the thermo-mechanical fatigue lives.

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NiCoCrAlY 및 NiAl bond coat를 사용한 Thermal Barrier Coating의 고온안정성에 미치는 Pt의 영향 (Effect of Pt on the High Temperature Stability of NiCoCrAlY or NiAl Bond Coat in the Thermal Barrier Coating System)

  • 구성모;김길무
    • 한국재료학회지
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    • 제15권6호
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    • pp.375-381
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    • 2005
  • High temperature oxidation behavior of thermal barrier coating (TBC) system (IN738 substrate + NiCoCrAlY or NiAl bond coat with or without Pt + yttria stabilized zirconia) prepared by air plasma spray (APS) process has been studied in order to understand the effect of Pt addition to bond coat on the stability of TBC system. Specimens were oxidized in thermal cycling and isothermal oxidation test at $1100^{\circ}C$. The Pt addition in TBC system with NiCoCrAlY bond coat showed a longer life time compared to that without addition of Pt. Pt addition to TBC system is believed to help the formation of more stable thermally grown oxide, $Al_2O_3$, at the TBC/bond coat interface, leading to a longer lifetime of TBC system.

새로운 합성법에 의한 LiV$_3$O$_8$ 의 초음파처리 특성 (The Ultrasonic Treatment Characteristics of LiV$_3$O$_8$ by New Synthesis)

  • 박수길;김종진;손원근;김상욱;류부형;이주성
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 1998년도 춘계학술대회 논문집
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    • pp.151-154
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    • 1998
  • The layered trivanadate, LiV$_3$O$_{8}$ has been investigated as a cathode material for secondary lithium batteries. Early in its development the preparation method of LiV$_3$O$_{8}$ strongly influenced its electrochemical properties, such as discharge capacity, rate capability and cycling efficiency. In the present experiment, a new synthesis route has been applied to obtain LiV$_3$O$_{8}$ . Instead of the conventional high temperature technique leading to the crystalline form, a solution technique producing the amorphous form has been used. This material, after dehydration, shows an electrochemical performance exeeding that of the crystalline one. The rationale for this behavior mainly lies in microscopic factors, i.e., in the possibility for the unit cell of amorphous LiV$_3$O$_{8}$ to insert up to 9 Li$^{+}$, instead of six for crystalline LiV$_3$O$_{8}$ . The ultrasonically treated products in water were characterized by XRD, TGA, DSC, and SEM. These measurements showed that the ultrasonic treatment process of crystalline LiV$_3$O$_{8}$ causes a decrease in crystallinity and considerable increases in specific surface area and interlayer spacing.g.

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솔더접합부에 대한 기계적 스트레스 평가 (Evaluation of Mechanical Stress for Solder Joints)

  • 김정관
    • 마이크로전자및패키징학회지
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    • 제9권4호
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    • pp.61-68
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    • 2002
  • 지금까지 전자 디바이스의 솔더접합부에 대한 신뢰성 평가에 있어서는 열충격시험에 의한 평가가 주류를 이루었다. 그러나 최근 모바일 제품이 소형화/다기능화되고 고밀도실장에 대한 요구가 증가함에 따라 BGA/CSP와 같은 솔더볼을 사용하는 패키지가 표면실장의 주류를 이루게 되었으며, 솔더접합부에 대한 메커니컬 스트레스 수명이 요구되어지고 있다. BGA/CSP의 솔더접합부에 대한 신뢰성 평가는 하중을 가한 상태에서 데이지체인 패턴의 전기적 저항변화와 스트레인 게이지에 의한 스트레스-스트레인 커브에 의해 행해진다. 본 연구에서는 자체 개발한 PCB만능시험장치의 응용과 솔더접합부에 대한 메커니컬 스트레스의 동적거동을 평가한 소니의 실험자료를 소개하도록 한다.

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리튬2차전지의 수명성능평가를 위한 충방전특성 모델링 (Charging/Discharging Modeling of Lithium Secondary Battery for Estimating Cycle Characteristic)

  • 김재언;노대석
    • 한국산학기술학회논문지
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    • 제8권6호
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    • pp.1343-1354
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    • 2007
  • 카메라, 휴대전화, 노트북 등과 같이 휴대 가능한 전기전자기기들은 대부분 2차 전지로부터 전원을 공급받고 있다. 2차 전지로서는 타 전지에 비하여 고 에너지 밀도와 고 전압의 특성을 갖고 있는 리튬2차전지가 가장 많이 활용되고 있으며, 이 특성 때문에 전기자동차, 우주왕복선, 분산전원의 한 형태인 전력 저장장치에까지 그 이용이 확대되고 있다. 그러나, 시스템의 최적성능을 보장하기 위해서는 용도별 싸이클 수명성능을 고려한 충방전 설계 및 이를 위한 전기적 등가모델의 정확성이 필수적이다. 따라서, 본 논문에서는 상용 리튬이차전지의 실제 실험 데이터에 근거하여 충/방전 심도 함수를 도출하고, 리튬이차전지의 수명성능평가를 위한 충/방전 특성 모델을 제안하고, 이의 타당성을 입증하였다.

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