• Korean Chemical Engineering Research
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• v.60 no.1
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• pp.62-69
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• 2022

Graphene has a large surface area to volume ratio and good mechanical and electrical property and biocompatibility. This study described the electrochemical deposition and reduction of graphene oxide on the surface of indium tin oxide (ITO) glass slide and electrochemical characterization of graphen-modified ITO. Cyclic voltammetry was used for the deposition and reduction of graphene oxide. The surface of graphen-coated ITO was characterized using scanning electron microscopy and energy dispesive X-ray spectroscopy. The electrodes were evaluated by performing cyclic voltammetry and electrochemical impedance spectroscopy. The number of cycles and scan rate greatly influenced on the coverage and the degree of reduction of graphene oxide, thus affecting the electrochemical properties of electrodes. Modification of ITO with graphene generated higher current with lower charge transfer resistance at the electrode-electrolyte interface. Glucose oxidase was immobilized on the graphene-modified ITO and has been found to successfully generate electrons by oxidizing glucose.

• Journal of the Korean Geotechnical Society
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• v.37 no.8
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• pp.5-13
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• 2021

Liquefaction behaviors of two natural silty samples containing fines including clay of 50% or more (Sample No.1 was silt 44.1% and clay 8.8%, sample No.2 was silt 57.2% and clay 12.4%) were examined by a cyclic triaxial test. According to the results on samples containing 50% or more of fine particles, an increase in the fine content decreases the liquefaction resistance of the sample. In other words, when the fine content increases, the liquefaction state of sample is reached with a small number of cyclic loads. In the relationship between the excess pore water pressure ratio and the number of cycles, the slope of the excess pore water pressure ratio increases more steeply as the fine content increases. As a result of analyzing the liquefaction behavior of the two silts with the content of clay contained in the fines, liquefaction occurred more easily in the No.2 silt with high clay content. This result shows that the clay contained in the fines affects the liquefaction behavior of the silt.

• Earthquakes and Structures
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• v.12 no.2
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• pp.201-211
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• 2017

This paper experimentally investigates the effect of yield strength of reinforcing bars and stirrups on the seismic performance of reinforced concrete (RC) circular piers. Reversed cyclic loading tests of nine-large scale specimens with longitudinal and transverse reinforcement of different yield strengths (varying between HRB335, HRB500E and HRB600 rebars) were conducted. The test parameters include the yield strength and amount of longitudinal and transverse reinforcement. The results indicate that the adoption of high-strength steel (HSS) reinforcement HRB500E and HRB600 (to replace HRB335) as longitudinal bars without reducing the steel area (i.e., equal volume replacement) is found to increase the moment resistance (as expected) and the total deformation capacity while reducing the residual displacement, ductility and energy dissipation capacity to some extent. Higher strength stirrups enhance the ductility and energy dissipation capacity of RC bridge piers. While the product of steel yield strength and reinforcement ratio ($f_y{\rho}_s$) is kept constant (i.e., equal strength replacement), the piers with higher yield strength longitudinal bars are found to achieve as good seismic performance as when lower strength bars are used. When higher yield strength transverse reinforcement is to be used to maintain equal strength, reducing bar diameter is found to be a better approach than increasing the tie spacing.

• Journal of the Korean Ceramic Society
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• v.45 no.6
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• pp.368-373
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• 2008

An electrode for supercapacitor using 3-dimensional porous nickel foam as a current collector and cobalt oxide as an active material was prepared and characterized in terms of morphology observation, crystalline property analysis, and the investigation of electrochemical property. The electrode surface showed that the cobalt oxide was homogeneously coated as the crystalline phase of $Co_3O_4$. Cyclic voltammetry for the $Co_3O_4$/nickel foam electrode exhibited higher specific capacitance values (445 F/g at 10 mV/s and 350 F/g at 200 mV/s) and excellent capacitance retention ratio (99% after $10^4$ cycles). It was proved that the nickel foam substrate played the roles in reducing the interfacial resistance with cobalt oxide and in improving the electrode density by embedding greater amount of cobalt oxide within it.

• Geomechanics and Engineering
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• v.2 no.3
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• pp.177-190
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• 2010

This paper presents the details of indigenous development of the piezovibrocone and calibration chamber. The developed cone has a cylindrical friction sleeve of $150cm^2$ surface area, capped with a $60^{\circ}$ apex angle conical tip of $15cm^2$ cross sectional area. It has a hydraulic shaker, coupled to the cone penetrometer with a linear displacement unit. The hydraulic shaker can produce cyclic load in different types of wave forms (sine, Hover sine, triangular, rectangular and external wave) at a range of frequency 1-10 Hz with maximum amplitude of 10 cm. The piezovibrocone can be driven at the standard rate of 2 cm/sec using a loading unit of 10 ton capacity. The calibration chamber is of size $2m{\times}2m{\times}2m$. The sides of the chamber and the top as well as the bottom portions are rigid. It has a provision to apply confining pressure (to a maximum value of $4kg/cm^2$) through the flexible rubber membrane inlined with the side walls of the calibration chamber. The preliminary static as well as dynamic cone penetration tests have been done sand in the calibration chamber. From the experimental results, an attempt has been made to classify the soil based on friction ratio ($f_R$) and the cone tip resistance ($q_c$).

• Bulletin of the Korean Chemical Society
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• v.31 no.12
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• pp.3697-3702
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• 2010

We demonstrate that vertically aligned carbon nanotubes can be synthesized directly on tantalum substrate via water-assisted chemical vapor deposition and evaluate their properties as electrochemical capacitors. The mean diameter of the carbon nanotubes was $7.1{\pm}1.5\;nm$, and 70% of them had double walls. The intensity ratio of G-band to D-band in Raman spectra was as high as 5, indicating good quality of the carbon nanotubes. Owing to the alignment and low equivalent series resistance, the carbon nanotube based supercapacitors showed good rate performance. Rectangular shape of cyclic voltammogram was maintained even at the scan rate of > 1 V/s in 1 M sulfuric acid aqueous solution. Specific capacitance was well-retained (~94%) even when the discharging current density dramatically increased up to 145 A/g. Consequently, specific power as high as 60 kW/kg was obtained from as-grown carbon nanotubes in aqueous solution. Maximum specific energy of ~20 Wh/kg was obtained when carbon nanotubes were electrochemically oxidized and operated in organic solution. Demonstration of direct synthesis of carbon nanotubes on tantalum current collectors and their applications as supercapacitors could be an invaluable basis for fabrication of high performance carbon nanotube supercapacitors.

• Journal of the Korean institute of surface engineering
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• v.52 no.3
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• pp.123-129
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• 2019

With recent demand for the renewable energy resources, we conducted a research on the energy conversion and storage device of supercapacitor. The hybrid graphene-zinc oxide(GZO) electrodes for the supercapacitors (SCs) were fabricated and investigated. To increase the electrical conductivity of the GZO electrode, the rapid thermal annealing(RTA) in $Ar/H_2$(10%) atmosphere was applied and the effect was examined by comparing it with RTA at Ar atmosphere. In Raman spectroscopy, the electrodes annealed at 400? in $Ar/H_2$ atmosphere showed a lower ratio of D/G peak than that of annealed at Ar atmosphere, and had a larger specific capacitance(Sc) in the cyclic voltammetry(CV), and a lower the equivalent series resistance(ESR) in the electrochemical impedance spectroscopy(EIS). The reason seems to come from the better mixing of the graphene and zinc oxide by the RTA in $Ar/H_2$(10%).

• Structural Engineering and Mechanics
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• v.83 no.6
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• pp.799-810
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• 2022

This study investigated the effect of the strengthening efficiency of unbonded steel-bar truss system on the out-of-plane behavior of perforated masonry walls. Four full-scale unreinforced masonry (URM) walls with two different planes were prepared using the unbonded steel-bar truss system and a URM walls without strengthening. All masonry walls were tested under constant axial and cyclic lateral loads. The obtained test results indicated that the pinching effect in the out-plane behavior of masonry walls tends to decrease in the in- and out-of-plane strengthened URM walls using the unbonded steel-bar truss system with the higher prestressing force ratio (R_p) of vertical reinforcing bars in the unbonded steel-bar truss system, regardless of the perforated type of the masonry wall. Consequently, the highest maximum shear resistance and cumulative dissipated energy at peak load in the post-peak behavior were observed in the in- and out-plane strengthened URM walls with the highest R_p values, which are 2.7 and 6.0 times higher than those of URM. In particular, the strengthening efficiency of the unbonded steel-bar truss system was primarily attributed to the vertical prestressed steel-bars rather than the diagonal steel-bars, which indicates that the strains in the vertical prestressed steel-bars at the peak load were approximately 1.6 times higher than those in the diagonal steel-bars.

• Journal of the Korean Geotechnical Society
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• v.21 no.4
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• pp.65-70
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• 2005

Many case histories of re-liquefaction phenomena seem to support the idea that sand deposits, if they once have been liquefied, could be reliquefied again by a subsequent earthquake even though the earthquake is smaller than the previous one. The magnitude of the strains induced in the initial liquefaction has a significant influence on the resistance of the sample to re-liquefaction. The deposits undergoing liquefaction experience large shear strain during liquefaction. And this previous strain changes the microstructure into highly anisotropic structure such as columnlike structure and connected voids. This type of anisotropy is so unstable that it can reduce re-liquefaction resistance. It is blown that the extent of anisotropic structural change depends on the gradation characteristics of ground. The purpose of this study is to estimate the correlation between the gradation characteristics of the sand and the ratio of re-liquefaction resistance to liquefaction resistance. In this study, 1-g shaking table tests were carried out on five different kinds of sands. During the tests the values of excess pore pressure at various depths and surface settlements were measured. Re-liquefaction resistances were not affected by the initial void ratio and the effective confining pressures, and the deposits of all test sands which had once been liquefied were reliquefied in the cyclic loading number below 1 to 1.5. The ratio of re-liquefaction resistance to liquefaction resistance linearly decreased as $D_{10}/C_u$ increased, and was constant as about 0.2 above the value of $D_{10}/C_u$, 0.15 mm.

• Clinical and Experimental Reproductive Medicine
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• v.31 no.2
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• pp.95-103
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• 2004

Objective: To compare COH characteristics and IVF outcomes among IVF-ET patients who were treated with various therapeutic modalities for ovarian endometriomas and to propose effective pre-cyclic therapeutic modalities to improve IVF-ET outcomes in the patients with ovarian endometriomas. Methods: All cases that had undergone IVF-ET after laparoscopy between January 1997 to August 2003 were reviewed. Forty-eight patients with tubal factor were assigned to Group I. Twenty seven, 22 and 38 patients diagnosed as severe pelvic adhesion with ovarian endometriomas by laparoscopy received only medical therapy (Group II), cyst aspiration (Group III), and sclerotherapy (Group IV), respectively. Laparoscopic cystectomy was performed in 20 patients (Group V). Resistance index was measured on day administering hCG. Results: As compared with Group I, in Group II resistance index increased (p<0.05) but number of oocytes, good-quality oocyte ratio (mature and intermediate oocytes/total retrieval oocytes), fertilization rate, and embryo development rate decreased (p<0.05). In Group III fertilization rate and embryo development rate decreased (p<0.05). There was no difference between Group IV and Group I in all parameters except basal FSH which increased (p<0.05). In Group V basal FSH, and resistance increased (p<0.05) and number of oocytes and good-quality oocytes ratio decreased (p<0.05). Conclusion: Sclerotherapy is an effective therapeutic option which can be done prior to IVF-ET cycles in the patients with ovarian endometriomas. Further studies on a large scale are necessary to confirm these data.